where k is a constant equal to 6.5 × 10−16 mol/cm2/s and Ω is the saturation index with respect to magnesite. This equation is consistent with spiral growth step generation controlling magnesite precipitation rates. Corresponding magnesite precipitation rates measured using mixed-flow reactors are shown to be consistent with both the rates measured by HAFM and the spiral growth theory, confirming the rate limiting mechanism. Step advancement, however, is observed to slow far faster than step generation with decreasing temperature; the activation energy for step advancement is 159 kJ/mol whereas step generation rates have an estimated activation energy of 60 kJ/mol. As such, it seems likely that at ambient temperatures magnesite growth is limited by very slow step advancement rates.  相似文献   
298.
Numerical simulations of the Mediterranean sea outflow: impact of the entrainment parameterization in an isopycnic coordinate ocean model   总被引:1,自引:0,他引:1  
Matheos P. Papadakis  Eric P. Chassignet  Robert W. Hallberg 《Ocean Modelling》2003,5(4):325-356
Gravity current entrainment is essential in determining the properties of the interior ocean water masses that result from marginal sea overflows. Although the individual entraining billows will be unresolvable in large-scale ocean models for the foreseeable future, some large-scale simulations are now being carried out that do resolve the intermediate scale environment which may control the rate of entrainment. Hallberg [Mon. Wea. Rev. 128 (2000) 1402] has recently developed an implicit diapycnal mixing scheme for isopycnic coordinate ocean models that includes the Richardson number dependent entrainment parameterization of Turner [J. Fluid Mech. 173 (1986) 431], and which may be capable of representing the gravity current evolution in large-scale ocean models. The present work uses realistic regional simulations with the Miami Isopycnic Coordinate Ocean Model (MICOM) to evaluate ability of this scheme to simulate the entrainment that is observed to occur in the bottom boundary currents downstream of the Mediterranean outflow. These simulations are strikingly similar to the observations, indicating that this scheme does produce realistic mixing between the Mediterranean outflow and the North Atlantic Central Water. Sensitivity studies identify the critical Richardson number below which vigorous entrainment occurs as a particularly important parameter. Some of these experiments also show meddies detaching from the Mediterranean undercurrent at locations that appear to be highly influenced by topographic features.  相似文献   
299.
Channel response to a dam-removal sediment pulse captured at high-temporal resolution using routine gage data     
Matthew J. Cashman  Allen C. Gellis  Eric Boyd  Mathias J. Collins  Scott W. Anderson  Brett D. McFarland  Ashley M. Ryan 《地球表面变化过程与地形》2021,46(6):1145-1159
In this study, we captured how a river channel responds to a sediment pulse originating from a dam removal using multiple lines of evidence derived from streamflow gages along the Patapsco River, Maryland, USA. Gages captured characteristics of the sediment pulse, including travel times of its leading edge (~7.8 km yr−1) and peak (~2.6 km yr−1) and suggest both translation and increasing dispersion. The pulse also changed local hydraulics and energy conditions, increasing flow velocities and Froude number, due to bed fining, homogenization and/or slope adjustment. Immediately downstream of the dam, recovery to pre-pulse conditions occurred within the year, but farther downstream recovery was slower, with the tail of the sediment pulse working through the lower river by the end of the study 7 years later. The patterns and timing of channel change associated with the sediment pulse were not driven by large flow or suspended sediment-transporting events, with change mostly occurring during lower flows. This suggests pulse mobility was controlled by process-factors largely independent of high flow. In contrast, persistent changes occurred to out-of-channel flooding dynamics. Stage associated with flooding increased during the arrival of the sediment pulse, 1 to 2 years after dam removal, suggesting persistent sediment deposition at the channel margins and nearby floodplain. This resulted in National Weather Service-indicated flood stages being attained by 3–43% smaller discharges compared to earlier in the study period. This study captured a two-signal response from the sediment pulse: (1) short- to medium-term (weeks to months) translation and dispersion within the channel, resulting in aggradation and recovery of bed elevations and changing local hydraulics; and (2) dispersion and persistent longer-term (years) effects of sediment deposition on overbank surfaces. This study further demonstrated the utility of US Geological Survey gage data to quantify geomorphic change, increase temporal resolution, and provide insights into trajectories of change over varying spatial and temporal scales.  相似文献   
300.
Subarctic catchment water storage and carbon cycling – Leading the way for future studies using integrated datasets at Pallas,Finland     
Hannu Marttila  Annalea Lohila  Pertti Ala-Aho  Kashif Noor  Jeffrey M. Welker  Danny Croghan  Kaisa Mustonen  Leo-Juhani Meriö  Anna Autio  Filip Muhic  Hannah Bailey  Mika Aurela  Jussi Vuorenmaa  Timo Penttilä  Valtteri Hyöky  Eric Klein  Anton Kuzmin  Pasi Korpelainen  Timo Kumpula  Anssi Rauhala  Bjørn Kløve 《水文研究》2021,35(9):e14350
Subarctic ecohydrological processes are changing rapidly, but detailed and integrated ecohydrological investigations are not as widespread as necessary. We introduce an integrated research catchment site (Pallas) for atmosphere, ecosystems, and ecohydrology studies in subarctic conditions in Finland that can be used for a new set of comparative catchment investigations. The Pallas site provides unique observational data and high-intensity field measurement datasets over long periods. The infrastructure for atmosphere- to landscape-scale research in ecosystem processes in a subarctic landscape has recently been complemented with detailed ecohydrological measurements. We identify three dominant processes in subarctic ecohydrology: (a) strong seasonality drives ecohydrological regimes, (b) limited dynamic storage causes rapid stream response to water inputs (snowmelt and intensive storms), and (c) hydrological state of the system regulates catchment-scale dissolved carbon dynamics and greenhouse (GHG) fluxes. Surface water and groundwater interactions play an important role in regulating catchment-scale carbon balances and ecosystem respiration within subarctic peatlands, particularly their spatial variability in the landscape. Based on our observations from Pallas, we highlight key research gaps in subarctic ecohydrology and propose several ways forward. We also demonstrate that the Pallas catchment meets the need for sustaining and pushing the boundaries of critical long-term integrated ecohydrological research in high-latitude environments.  相似文献   
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291.
As part of the 2000 Texas Air Quality Study (TexAQS), we studied the isoprene oxidation process under ambient conditions to discern the presence of chlorine atom (Cl) chemistry in the Houston, Texas urban area. By measuring chloromethylbutenone (CMBO) and an isomer of chloromethylbutenal (CMBA), we clearly observed sixteen episodes of active Cl chemistry during the 24-day experiment. Estimated median Cl concentration during each of these episodes was between the detection limit of ~102 atoms cm−3 and 50 - 30 + 70 ×104 50_{ - 30}^{ + 70} \times {10^4} atoms cm−3. Cl concentration during all the episodes averaged 7.6 - 2.0 + 4.7 ×104 7.6_{ - 2.0}^{ + 4.7} \times {10^4} atoms cm−3 and thus amounted to less than 3% of the OH concentration during the same periods. During the episodes, the fraction of oxidation chemistry initiated by Cl ranged from 3–43% and was strongly dependent on the quantity and type of hydrocarbons present in the atmosphere. Because of its intermittent presence and low concentration, Cl is not a broadly influential oxidant in the Houston, Texas urban area.  相似文献   
292.
293.
We investigate the properties of optically passive spirals and dusty red galaxies in the A901/2 cluster complex at redshift ∼0.17 using rest-frame near-ultraviolet–optical spectral energy distributions, 24-μm infrared data and Hubble Space Telescope morphologies from the STAGES data set. The cluster sample is based on COMBO-17 redshifts with an rms precision of  σ cz ≈ 2000 km s−1  . We find that 'dusty red galaxies' and 'optically passive spirals' in A901/2 are largely the same phenomenon, and that they form stars at a substantial rate, which is only four times lower than that in blue spirals at fixed mass. This star formation is more obscured than in blue galaxies and its optical signatures are weak. They appear predominantly in the stellar mass range of  log  M */M=[10, 11]  where they constitute over half of the star-forming galaxies in the cluster; they are thus a vital ingredient for understanding the overall picture of star formation quenching in clusters. We find that the mean specific star formation rate (SFR) of star-forming galaxies in the cluster is clearly lower than in the field, in contrast to the specific SFR properties of blue galaxies alone, which appear similar in cluster and field. Such a rich red spiral population is best explained if quenching is a slow process and morphological transformation is delayed even more. At  log  M */M < 10  , such galaxies are rare, suggesting that their quenching is fast and accompanied by morphological change. We note that edge-on spirals play a minor role; despite being dust reddened they form only a small fraction of spirals independent of environment.  相似文献   
294.
Models of accretion discs and their associated outflows often incorporate assumptions of axisymmetry and symmetry across the disc plane. However, for turbulent discs these symmetries only apply to averaged quantities and do not apply locally. The local asymmetries can induce local imbalances in outflow power across the disc mid-plane, which can in turn induce local tilting torques. Here we calculate the effect of the resulting stochastic torques on disc annuli that are a consequence of standard mean field accretion disc models. The torques induce a random walk of the vector perpendicular to the plane of each averaged annulus. This random walk is characterized by a radially dependent diffusion coefficient which we calculate for small angle tilt. We use the coefficient to calculate a radially dependent time-scale for annular tilt and associated jet wobble. The wobble time depends on the square of the wander angle so the age of a given system determines the maximum wobble angle. We apply this to examples of blazars, young stellar objects and binary engines of pre-planetary nebulae and microquasars. It is noteworthy that for an averaging time   t w∼ 3 d  , we estimate a wobble angle for jets in SS 433 of  θ∼ 0.8°  , not inconsistent with observational data. In general the non-periodic nature of the stochastic wobble could distinguish it from faster periodic jet precession.  相似文献   
295.
296.
We correlate Upper Pleistocene glacial and fluvial deposits of the Cinca and Gállego River valleys (south central Pyrenees and Ebro basin, Spain) using geomorphic position, luminescence dates, and time-related trends in soil development. The ages obtained from glacial deposits indicate glacial periods at 85 ± 5 ka, 64 ± 11 ka, and 36 ± 3 ka (from glacial till) and 20 ± 3 ka (from loess). The fluvial drainage system, fed by glaciers in the headwaters, developed extensive terrace systems in the Cinca River valley at 178 ± 21 ka, 97 ± 16 ka, 61 ± 4 ka, 47 ± 4 ka, and 11 ± 1 ka, and in the Gállego River valley at 151 ± 11 ka, 68 ± 7 ka, and 45 ± 3 ka. The times of maximum geomorphic activity related to cold phases coincide with Late Pleistocene marine isotope stages and Heinrich events. The maximum extent of glaciers during the last glacial occurred at 64 ± 11 ka, and the terraces correlated with this glacial phase are the most extensive in both the Cinca (61 ± 4 ka) and Gállego (68 ± 7 ka) valleys, indicating a strong increase in fluvial discharge and availability of sediments related to the transition to deglaciation. The global Last Glacial Maximum is scarcely represented in the south central Pyrenees owing to dominantly dry conditions at that time. Precipitation must be controlled by the position of the Iberian Peninsula with respect to the North Atlantic atmospheric circulation system. The glacial systems and the associated fluvial dynamic seem sensitive to 1) global climate changes controlled by insolation, 2) North Atlantic thermohaline circulation influenced by freshwater pulses into the North Atlantic, and 3) anomalies in atmospheric circulation in the North Atlantic controlling precipitation on the Iberian Peninsula. Our scenario of glacial and fluvial evolution during the Late Pleistocene in northern Spain could be extrapolated to other glaciated mountainous areas in southern Europe.  相似文献   
297.
Magnesite growth rates as a function of temperature and saturation state   总被引:1,自引:1,他引:0  
Magnesite growth rates and step velocities have been measured systematically as a function of temperature from 80 to 105 °C and saturation state in 0.1 M NaCl solutions using hydrothermal atomic force microscopy (HAFM). The observations indicate that at these conditions magnesite precipitation is dominated by the coupling of step generation via spiral growth at screw dislocations and step advancement away from these dislocations. As these two processes occur in series the slowest of these dominates precipitation rates. At 100 °C magnesite growth rates (r) determined by HAFM are consistent with
r=k(Ω-1)2,
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