Interfacial geochemistry of barium in suspension and sediment from Zhujiang Estuary

Chemical forms of Ba are determined in samples of suspension and sediment from the Zhujiang Estuary. Their interfacial geochemical processes are discussed. Total suspended Ba content is between 2. 4 and 40. 4 μg/L, and mostly exists in the crystalline form (43. 5%), secondly in the Fe-Mn oxidative form (23.1%). Percentages of organic, carbonate and exchangeable forms are 14. 8%, 11. l%and 7.4%, respectively. Total content of Ba in the sediment is between 158. 6 and 48. 0 ug/g. Percentages of crystalline form, Fe-Mn oxidative form and carbonate form are 78. 4% ,13. 5%and 8. 2%, respectively. Organic and exchangeable forms are not detected. The study on the mechanism of interfacial movement suggests that the salinity range of 10 is the turning point for the varied distribution of Ba. The subsidence of crystalline form affects the decrease of Ba content in suspension. The decrease mostly takes place in the salinity range lower than 10, which corresponds to the high value of Ba content in the sediment. The     

A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

A note on the effects of a thin visco-elastic mud layer on small amplitude water-wave propagation

In this note we investigated the effects of a thin visco-elastic mud layer on wave propagation. Within the framework of linear water-wave theory, analytical solutions are obtained for damping rate, dispersion relation between wave frequency and wave number, and velocity components in the water column and mud layer. The wave attenuation rate reaches a maximum value when the mud layer thickness is about the same as the mud boundary layer thickness. Heavier mud has a weaker effect on the wave damping. However, the wave attenuation rate does not always decrease as the elastic shear modulus increases. In the range of small values for elastic shear modulus, the wave attenuation can be amplified quite significantly. The current solutions are compared with experimental data with different wave conditions and mud properties. In general, good agreements are observed.     

Atmospheric forcing of the eastern tropical Pacific: A review

The increase in marine, land surface, atmospheric and satellite data during recent decades has led to an improved understanding of the air–sea interaction processes in the eastern tropical Pacific. This is also thanks to extensive diagnoses from conceptual and coupled ocean–atmosphere numerical models. In this paper, mean fields of atmospheric variables, such as incoming solar radiation, sea level pressure, winds, wind stress curl, precipitation, evaporation, and surface energy fluxes, are derived from global atmospheric data sets in order to examine the dominant features of the low level atmospheric circulations of the region. The seasonal march of the atmospheric circulations is presented to depict the role of radiative forcing on atmospheric perturbations, especially those dominating the atmosphere at low levels.In the tropics, the trade winds constitute an important north–south energy and moisture exchange mechanism (as part of the low level branch of the Hadley circulation), that determines to a large extent the precipitation distribution in the region, i.e., that associated with the Inter-Tropical Convergence Zone (ITCZ). Monsoonal circulations also play an important role in determining the warm season precipitation distribution over the eastern tropical Pacific through a large variety of air–sea–land interaction mechanisms. Westward traveling waves, tropical cyclones, low latitude cold air intrusions, and other synoptic and mesoscale perturbations associated with the ITCZ are also important elements that modulate the annual rainfall cycle. The low-level jets of the Gulf of California, the Intra-Americas Sea (Gulf of Mexico and Caribbean Sea) and Chocó, Colombia are prominent features of the eastern tropical Pacific low-level circulations related to sub-regional and regional scale precipitation patterns. Observations show that the Intra-Americas Low-Level Jet intensity varies with El Niño/Southern Oscillation (ENSO) phases, however its origin and role in the westward propagation and development of disturbances that may hit the eastern tropical Pacific, such as easterly waves and tropical cyclones, are still unclear. Changes in the intensity of the trade winds in the Caribbean Sea and the Gulf of Mexico (associated with eastern tropical Pacific wind jets) exert an important control on precipitation by means of wind–topography interactions. Gaps in the mountains of southern Mexico and Central America allow strong wind jets to pass over the continent imprinting a unique signal in sea surface temperatures and ocean dynamics of the eastern tropical Pacific.The warm pools of the Americas constitute an important source of moisture for the North American Monsoon System. The northeastern tropical Pacific is a region of intense cyclogenetic activity, just west of the coast of Mesoamerica. Over the oceanic regions, large-scale properties of key variables such as precipitation, moisture, surface energy fluxes and wind stress curl are still uncertain, which inhibits a more comprehensive view of the region and stresses the importance of regional field experiments. Progress has been substantial in the understanding of the ocean and atmospheric dynamics of the eastern tropical Pacific, however, recent observational evidence such as that of a shallow meridional circulation cell in that region, in contrast to the classic concept of the Hadley-type deep meridional circulation, suggests that more in situ observations to validate theories are still necessary.This paper is part of a comprehensive review of the oceanography of the eastern tropical Pacific Ocean.     

Distribution and transport of organic matter along a filament-eddy system in the Canaries – NW Africa coastal transition zone region

The distribution and transport of chlorophyll a (Chla), particulate (POC) and dissolved (DOC) organic carbon, and the respiratory ETS activity of the microplankton community were studied along a filament-eddy system located in the transition zone between the NW Africa upwelling and Canary Islands waters. Two independent filaments (F1 and F2) stemming from the coastal jet, between Cape Juby and Cape Bojador, merged about 100 km offshore, turning southward and onshore forced by the circulation of a recurrent oceanic cyclonic eddy. In general, the coastal upwelling waters presented higher Chla, but lower POC, DOC and ETS activity than filament waters. However, differences in organic carbon distribution and respiratory activity were observed among stations from the two filaments. The bio-chemical fields were strongly influenced by a complex sub-mesoscale hydrography resulting from the interaction of cyclonic and anticyclonic island eddies with the filaments. The combined F1 + F2 filament system transported 97.1 kg s⁻¹ of excess (non-refractory) total organic carbon (e-TOC), a value comparable to other published estimates from upwelling filaments in the NE Atlantic. About 90% of e-TOC was exported as DOC, since eddy re-circulation precluded the offshore transport of POC. Assuming that the calculated transport of e-TOC is representative of the annual average, the yearly offshore transport (3.1 x 10⁹ kg C) would represent about 25% of the upwelling primary production of the region of study.     

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.     

A low level supplementary heating system for free divers

A simple and effective method of heating divers in extreme cold water has been developed. The local heating concept utilizes a uniformly distributed granular mixture of magnesium and iron particles packed in small sachets. Upon activation by sea water, the two metal mixture behaves as a multitude of short-circuited electrolytic cells, producing thermal energy rather than electrical energy. The 45 mm-square sachets may be placed where heating is required on the diver's body, thus giving rise to the term “local heating”, obviously, the heating system requires no pumping device, or distribution network. Heating rate and duration of output of the sachets are controlled by particle size, and mixture ratio of the constituent Mg and Fe particles.This paper described the development, testing and performance of the heating sachets. Results of live tests in different dive situations are also presented and discussed.     

Undular tidal bore dynamics in the Daly Estuary, Northern Australia

Measurements in the macro-tidal Daly Estuary show that the presence of an undular tidal bore contributed negligibly to the dissipation of tidal energy. No recirculation bubble was observed between a trough and the following wave crest in the lee waves following the undular bore. This differs to stationary undular bores in laboratory experiments at larger Froude numbers where a recirculation bubble exists. Secondary motions and the turbulence generated by the undular bore had no measurable influence on the sediment transport. This situation contrasts with the intense sediment resuspension observed in breaking tidal bores. The tidally averaged sediment budget in the Daly Estuary was controlled by the asymmetry of tidal currents. The undular bore may widen the river by breaking along the banks that it undercuts, leading to bank slippage. A patch of river-wide macro-turbulence of 3-min duration occurred about 20 min after the passage of the bore during accelerating tidal currents.     

Toward a generic method for studying water renewal, with application to the epilimnion of Lake Tanganyika

We present a method, based on the concept of age and residence time, to study the water renewal in a semi-enclosed domain. We split the water of this domain into different water types. The initial water is the water initially present in the semi-enclosed domain. The renewing water is defined as the water entering the domain of interest. Several renewing water types may be considered depending on their origin. We present the equations for computing the age and the residence time of a certain water type. These timescales are of use to understand the rate at which the water renewal takes place. Computing these timescales can be achieved at an acceptable extra computer cost.The above-mentioned method is applied to study the renewal of epilimnion (i.e. the surface layer) water in Lake Tanganyika. We have built a finite element reduced-gravity model modified to take into account the water exchange between the epilimnion and the hypolimnion (i.e. the bottom layer), the water supply from precipitation and incoming rivers, and the water loss from evaporation and the only outgoing river. With our water renewal diagnoses, we show that the only significant process in the renewal of epilimnion water in Lake Tanganyika is the water exchange between the epilimnion and the hypolimnion, other phenomena being negligible.