Book reviews

THE IMPACT OF VOLCANIC HAZARDS AT RABAUL, PAPUA NEW GUINEA (Discussion Paper No. 33) by R. J. Blong and C. Aislabie. 17 × 25 cm, xiv and 207 pages. Institute of National Affairs: Port Morseby 1988 (ISBN 9980 77 086 4).

A PRACTICAL APPROACH TO SEDIMENTOLOGY by R. C. Lindholm. 15 × 23 cm, xviii and 279 pages. Allen & Unwin: London 1987 (ISBN 0 04 551132 2) $A45.00 (soft).

THE ATMOSPHERE AND WEATHER OF SOUTHERN AFRICA by R. A. Preston‐Whyte and P. D. Tyson. 18 × 24 cm, xiii and 375 pages. Oxford University Press: Cape Town 1988 (ISBN 0 19 570 514 9) R56.00 (hard); (ISBN 0 19 570 496 7) R39.14 (soft).

QUATERNARY PALEOCLIMATOLOGY: Methods of Paleoclimatic Reconstruction by R. S. Bradley. 15 × 23 cm, xvii and 472 pages. Allen & Unwin: Boston 1985 (ISBN 0 04 551067 9) $A69.95 (hard); (ISBN 0 04 551068 7) $A39.95 (soft).

PROCESSES IN PHYSICAL GEOGRAPHY by R. D. Thompson, A. M. Mannion, C. W. Mitchell, M. Parry and J. R. Townsend. 24 × 19 cm, xii and 380 pages. Longman: London 1986 (ISBN 0 582 30136) $A44.95.

PERSPECTIVES ON A DYNAMIC EARTH by T. R. Paton. 16 × 24 cm, 142 pages. Allen & Unwin: London 1986 (ISBN 0 04 55 0043 6) $A23.95 (soft).

LAND DEGRADATION AND SOCIETY edited by P. Blaikie and H. Brookfield. 15 × 23 cm. xxiv and 296 pages. Methuen: London 1987 (ISBN 0 416 40150 3) $A32.95 (soft).

THE PENGUIN DICTIONARY OF HUMAN GEOGRAPHY by B. Goodall. 13 × 20 cm, 509 pages. Penguin: Harmondsworth 1987 (ISBN 0 14 051095 8) $A19.95 (soft).

MAKING SENSE OF DEVELOPMENT: An Introduction to Classical and Contemporary Theories of Development and Their Application to South‐east Asia by P. W. Preston. 14 × 22 cm, xxi and 318 pages. Routledge & Kegan Paul: London 1986 (ISBN 0 7102 0813 8) $A87.95 (hard).

THE DEMOGRAPHIC DIMENSION IN INDONESIAN DEVELOPMENT by G. J. Hugo, T. H. Hull, V. J. Hull and G. W. Jones. 16 × 25 cm, xxv and 417 pages. Oxford University Press: Singapore 1987 (ISBN 0 19 582699 X) $A49.95 (hard).

GLOBAL ISSUES AND OUTLOOK IN PULP AND PAPER edited by G. F. Schreuder, 18 × 26 cm, ix and 302 pages. University of Washington Press: Seattle 1988 (ISBN 0 295 96642 4) $US40.00 (hard).

AN HISTORICAL GEOGRAPHY OF MODERN AUSTRALIA: The Restive Fringe (Cambridge Studies in Historical Geography No. 11) by J. M. Powell. 16 × 33 cm, xx and 400 pages. Cambridge University Press: Cambridge 1988 (ISBN 0 521 25619 4) $A39.95 (hard).

HISTORICAL GEOGRAPHY: Progress and Prospect edited by M. Pacione. 14 × 22 cm, 306 pages. Croom Helm: London 1987 (ISBN 0 7099 40467) $A27.50 (hard).

THE ROLE OF THEORY IN URBAN PLANNING: A Study of Metropolitan Planning in Perth, Western Australia (Geowest No. 24) by O. Yiftachel. 21 × 29 cm, 102 pages. Department of Geography, University of Western Australia: Nedlands 1987 (ISBN 0 86422 063 4).

SYDNEY INTO ITS THIRD CENTURY: Metropolitan Strategy for the Sydney Region by NSW Department of Environment and Planning. 21 × 29 cm, 72 pages. NSW department of Environment and Planning: Sydney 1988 (ISBN 0 7305 4312 9).

BUS SERVICES IN WESTERN SYDNEY: Private Bus Operators and Government Transport Departments (Monograph Series No. 3) by P. Tranter. 21 × 29 cm, v and 98 pages. Department of Geography and Oceanography, University College, Australian Defence Force Academy: Campbell, ACT 1988 (ISBN 0 7317 0036 8).

AGEING IN VICTORIA: An Electronic Social Atlas by A. L. Howe, P. Newton and P. Sharwood. 30 × 21 cm, 105 pages. National Research Institute for Gerontology and Geriatric Medicine, Mt. Royal Hospital and University of Melbourne: Melbourne 1987 (ISBN 0 958326 6 2) $A10.00 (soft).

READINGS IN AUSTRALIAN GEOGRAPHY: Proceedings of the 21st Institute of Australian Geographers’ Conference, Perth 10–18 May 1986, edited by A. Conacher. 21 × 29 cm, vi and 493 pages. Institute of Australian Geographers (WA Branch) and Department of Geography, University of Western Australia: Perth 1987 (ISBN 0 909678 30 B) $A25.00 (soft).

GEOGRAPHY RESEARCH PROJECTS: A Senior Student's Handbook by H. Binden and H. Williams. 18 × 26 cm, 149 pages. Edward Arnold Australia: Caulfield East 1988 (ISBN 0 7131 8311 X) $A 14.95 (soft).

OUR AMERICAN LAND: 1987 Yearbook of Agriculture, ix and 323 pages. US Government Printing Office, Washington, DC: 1987 $US9.50.

THE ENCYCLOPAEDIC DICTIONARY OF PHYSICAL GEOGRAPHY edited by A. Goudie et al. 17 × 24 cm, xvi and 528 pages. Basil Black‐well: Oxford 1988 (ISBN 0 631 15581 3) $A34.95 (soft).

THE CONSERVATION OF ECOSYSTEMS AND SPECIES by Gareth E. Jones, 14 × 22 cm, 277 pages. Croom Helm: London 1987 (ISBN 0 7099 1463 6) $A87.95 (hard).

SO CAME THEY SOUTH by R. Clancy and A. Richardson. 35 × 35 cm, 176 pages. Shakespeare Head: Sydney 1988 (ISBN 0 7302 0864 8) $A34.95.     

Using GPS multipath to measure soil moisture fluctuations: initial results

Measurements of soil moisture are important for studies of climate and weather forecasting, flood prediction, and aquifer recharge studies. Although soil moisture measurement networks exist, most are sparsely distributed and lack standardized instrumentation. Measurements of soil moisture from satellites have extremely large spatial footprints (40–60 km). A methodology is described here that uses existing networks of continuously-operating GPS receivers to measure soil moisture fluctuations. In this technique, incoming signals are reflected off and attenuated by the ground before reception by the GPS receiver. These multipath reflections directly affect signal-to-noise ratio (SNR) data routinely collected by GPS receivers, creating amplitude variations that are a function of ground reflectivity and therefore soil moisture content. After describing this technique, multipath reflection amplitudes at a GPS site in Tashkent, Uzbekistan are compared to estimates of soil moisture from the Noah land surface model. Although the GPS multipath amplitudes and the land surface model are uncalibrated, over the 70-day period studied, they both rise sharply following each rainfall event and slowly decrease over a period of ∼10 days.     

Integrated chronostratigraphy of Proterozoic-Cambrian boundary beds in the western Anabar region, northern Siberia

Carbonate-rich sedimentary rocks of the western Anabar region, northern Siberia, preserve an exceptional record of evolutionary and biogeochemical events near the Proterozoic/Cambrian boundary. Sedimentologically, the boundary succession can be divided into three sequences representing successive episodes of late transgressive to early highstand deposition; four parasequences are recognized in the sequence corresponding lithostratigraphically to the Manykal Formation. Small shelly fossils are abundant and include many taxa that also occur in standard sections of southeastern Siberia. Despite this coincidence of faunal elements, biostratigraphic correlations between the two regions have been controversial because numerous species that first appear at or immediately above the basal Tommotian boundary in southeastern sections have first appearances scattered through more than thirty metres of section in the western Anabar. Carbon- and Sr-isotopic data on petrographically and geochemically screened samples collected at one- to two-metre intervals in a section along the Kotuikan River, favour correlation of the Staraya Reckha Formation and most of the overlying Manykai Formation with sub-Tommotian carbonates in southeastern Siberia. In contrast, isotopic data suggest that the uppermost Manykai Formation and the basal 26 m of the unconformably overlying Medvezhya Formation may have no equivalent in the southeast; they appear to provide a sedimentary and palaeontological record of an evolutionarily significant time interval represented in southeastern Siberia only by the sub-Tommotian unconformity. Correlations with radiometrically dated horizons in the Olenek and Kharaulakh regions of northern Siberia suggest that this interval lasted approximately three to six million years, during which essentially all 'basal Tommotian' small shelly fossils evolved.     

Carbonyl products of the gas phase reaction of ozone with 1,1-disubstituted alkenes

Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O₃+R₁R₂C=CH₂ (HCHO+R₁R₂COO)+(1–)(R₁COR₂+H₂COO) where formaldehyde and the ketone R₁ COR₂ are the primary carbonyls and R₁R₂COO and H₂COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H₂COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R₁R₂COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined.     

A model of an exploding,radiating star in general relativity

In a previous paper Adams, Cary and Cohen (1994) presented a model of a supernova. In that paper the equations of General Relativity describing the evolution of a spherically symmetric, radiating star were solved analytically. The evolution of the star was determined by the application of boundary conditions at the center and at the edge. Due to lmitations in the presupernova model, only the very slow inward motion of an unstable, degenerate core could be considered. The solution was also limited by the need to exclude a runaway term, one that increased exponentially with time. Without the exclusion of the runaway, the luminosity would have increased without bound and the mass would have become negative.This paper presents a completely analytic solution to the equations of General Relativity describing the evolution of a Type II supernova. Professor S.E. Woosley kindly gave us data on the physical variables of a 12M ₀ presupernova star. In our model the core collapses within 1 s, leaving a 1.3M ₀ remnant. Shortly afterward 10.6M ₀ is ejected to infinity, and 0.17M ₀ is radiated away in the form of neutrinos. The distance of the edge from the center increases proportionally to the two-thirds power of the time. The luminosity decreases proportionally to the inverse four-thirds power.Although the runaway solution was modified by the exploding rather than a static envelope, it must still be excluded by adjusting initial conditions. Its character is changed from an exponential to a very large power (55) of time. The removal of a degree of freedom by this exclusion leads to physically non-sensical results such as negative luminosity. The inclusion of a term describing motion of the mantle due to neutrino interactions provides the additional degree of freedom necessary for physically reasonable results.     

On the pH-dependent formation constants of iron(III)-sulfur(IV) transient complexes

An experimental study is described of Fe(III)-S(IV) formation constants measured as a function of pH (1–3), ionic strength (0.2–0.5 M) and [Fe(III)] _T (2.5–5.0×10^–4 M) using a continuous-flow spectrophotometric technique to make observations 160 ms after mixing. Preliminary experiments using pulse-accelerated-flow (PAF) spectrophotometry to measure rate constants on a microsecond timescale are also described. The conditional formation constant at 25 °C can be modeled with the following equation: {ie307-1} where {ie307-2}K ₇ andK ₈ can be interpreted as intrinsic constants for the coordination of HSO ₃ ^– by FeOH²⁺ and Fe³⁺, respectively, but until further evidence is obtained they should be regarded as fitting constants. PAF spectrophotometry showed that the initial reaction of Fe(III) with S(IV) (pH 2.0) is characterized by a second-order rate constant of 4×10⁶ M^–1 s^–1 which is comparable to rate of reaction of FeOH²⁺ with SO ₄ ^2– . However, the PAF results should be regarded as preliminary since unexpected features in the initial data indicate that the reaction may be more complex than expected.     

Experimental investigation and application of the equilibrium rutile + orthopyroxene = quartz + ilmenite

Equilibria in the Sirf (Silica-Ilmenite-Rutile-Ferrosilite) system: $${\text{SiO}}_{\text{2}} + ({\text{Mg,Fe}}){\text{TiO}}_{\text{3}} {\text{ + (Mg,Fe)SiO}}_{\text{3}} $$ have been calibrated in the range 800–1100° C and 12–26 kbar using a piston-cylinder apparatus to assess the potential of the equilibria for geobarometry in granulite facies assemblages that lack garnet. Thermodynamic calculations indicate that the two end-member equilibria involving quartz + geikielite = rutile + enstatite, and quartz + ilmenite = rutile + ferrosilite, are metastable. We therefore reversed equilibria over the compositional range Fs_40–70, using Ag₈₀Pd₂₀ capsules with \(f_{{\text{O}}_{\text{2}} } \) buffered at or near iron-wüstite. Ilmenite compositions coexisting with orthopyroxene are \(X_{{\text{MgTiO}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.06 to 0.15 and \(X_{{\text{Fe}}_{\text{2}} {\text{O}}_{\text{3}} }^{{\text{Ilm}}} \) of 0.00 to 0.01, corresponding toK _D values of 13.3, 10.2, 9.0 and 8.0 (±0.5) at 800, 900, 1000 and 1100° C, respectively, whereK _D =(XMg/XFe)^Opx/(XMg/XFe)^Ilm. Pressures have been calculated using equilibria in the Sirf system for granulites from the Grenville Province of Ontario and for granulite facies xenoliths from central Mexico. Pressures are consistent with other well-calibrated geobarometers for orthopyroxeneilmenite pairs from two Mexican samples in which oxide textures appear to represent equilibrium. Geologically unreasonable pressures are obtained, however, where oxide textures are complex. Application of data from this study on the equilibrium distribution of iron and magnesium between ilmenite and orthopyroxene suggests that some ilmenite in deep crustal xenoliths is not equilibrated with coexisting pyroxene, while assemblages from exposed granulite terranes have reequilibrated during retrogression. The Sirf equilibria are sensitive to small changes in composition and may be used for determination of activity/composition (a/X) relations of orthopyroxene if an ilmenite model is specified. A symmetric regular solution model has been used for orthopyroxene in conjunction with activity models for ilmenite available from the literature to calculatea/X relations in orthopyroxene of intermediate composition. Data from this study indicate that FeSiO₃?MgSiO₃ orthopyroxene exhibits small, positive deviations from ideality over the range 800–1100°C.     

Diamondiferous eclogites from Yakutia,Siberia: evidence for a diversity of protoliths

Major-element and REE compositions of 14 diamondiferous eclogites from the Udachnaya kimberlite in Yakutia, Siberia have been determined by electron microprobe and secondary ion mass spectrometer (SIMS). Based on previous clinopyroxene classification schemes (e.g., Taylor and Neal 1989), all of these eclogite xenoliths belong to Group B/C, although some of the garnet compositions and mineral REE abundances are inconsistent with the indicated groups. This demonstrates the inadequacy of the classification scheme based on African eclogites for application to Siberian samples. Because of the coarse grain size of the Udachnaya nodules, meaningful modal abundances could not be obtained. However, reconstructed REE compositions using various garnet: clinopyroxene ratios demonstrate relative insensitivity to changes in mode for common eclogitic assemblages. Many of these reconstructed REE compositions show LREE depletions. Some depletions are consistent with an origin (either directly or through partial melting) as normal or Type-I ocean floor basalt. Others, however, require material of eclogitic or pyroxenitic affinities to undergo partial melting; this facilitates the depletion of LREE while leaving the HREE at nearly original levels. Many of the eclogites of South Africa are consistent with a protolith of anomalous or Type II ocean floor basalt. This fundamental difference between the two regions is the likely cause of the inconsistencies with the chemicallybased classification.     

Confirmation of radio absorption by the intergalactic medium

The conventional interpretation of the cosmic background radiation (CBR) as a relic of the Big Bang assumes that the intergalactic medium is highly transparent to radio frequency radiation. Previous work (Lerner, 1990) used the well-known correlation of IR and radio luminosities of spiral galaxies to test this assumption. That analysis, using 237 Shapley-Ames galaxies showed that radio luminosity (L _R ) for a given IR-luminosity, declines with distance, implying that the IGM strongly absorbs radio frequency radiation. That absorption has now been confirmed using a sample of 301 IR-bright galaxies. Using two independent methods of determining the correlation of IR and radio luminosities of spiral and interacting galaxies, the sample shows that for a givenL _IR ,L _R D ^{–0.32±0.04} over a range of distances from 0.7-300 Mpc. (H ₀ = 75 km s^–1 Mpc^–1). The correlation is significant at the 8 or 10^–14 level. Absorption by the IGM is the only reasonable explanation for this correlation. The existence of such absorption implies that neither the isotropy nor the spectrum of the CBR are primordial and that neither is evidence for a Big Bang.