Spatio-temporal trends of heavy metals and source apportionment in Tolo Harbour,Hong Kong

This study provided a picture of the spatial and temporal distributions of Cr, Co, Ni Cu, Zn, As, Cd and Pb in bottom sediments of Tolo Harbour. The concentrations of the eight heavy metals differed significantly between sites due to the poor tidal flushing in Tolo Harbour. The levels of Cu, Zn, Cd and Pb were generally enriched in sediments from inner Tolo Harbour, while sediments from outer Tolo Harbour (Tolo Channel) had higher levels of Cr, Co and Ni. The redox sensitive element arsenic showed no distinct spatial pattern in Tolo Harbour. The decreasing levels of Cu, Zn, Pb and Cd in sediments with increasing distance from land demonstrated a typical diffusion pattern from land to the direction of sea. Two hot spots of Cu, Zn, Pb and Cd in sediments were located near Tai Po and Sha Tin new town, indicating that Cu, Zn, Pb and Zn were from land-derived sources. The sites with relatively high levels of Cr, Co and Ni in sediments were located in areas close to waste spoil in sea floor. The natural and anthropogenic inputs from Sha Tin and Tai Po to Tolo Harbour were mostly responsible for Cu, Zn, Cd and Pb enrichment in sediments from inner Tolo Harbour. The waste spoil in sea floor was believed to contribute to the Cr, Co and Ni in outer Tolo Harbour. The results of correlation coefficient between the eight heavy metals showed that Cu, Zn, Cd and Pb were strongly positively correlated, and Cr, Co and Ni were also significantly correlated with each other. The best explanation of strong correlation was their similar source. As, however, is not well correlated with the other seven heavy metals. The average concentrations of Cu and Zn displayed general increasing trends from 1978 to 2006 in Tolo Harbour, while the mean levels of Cr and Pb displayed a substantial decrease from 1978 to 1987, then a slight increase after 1987. No distinct temporal trends of the concentrations of Ni and As were observed from 1978 due to the inconsecutive data. On the other hand, the increasing trends of Cr, Cu, Zn, Cd and Pb were observed since 1996.     

Paragenesis of unusual Fe-cordierite (sekaninaite)-bearing paralava and clinker from the Kuznetsk coal basin,Siberia, Russia

Sekaninaite (X_Fe > 0.5)-bearing paralava and clinker are the products of ancient combustion metamorphism in the western part of the Kuznetsk coal basin, Siberia. The combustion metamorphic rocks typically occur as clinker beds and breccias consisting of vitrified sandstone–siltstone clinker fragments cemented by paralava, resulting from hanging-wall collapse above burning coal seams and quenching. Sekaninaite–Fe-cordierite (X_Fe = 95–45) is associated with tridymite, fayalite, magnetite, ± clinoferrosilite and ±mullite in paralava and with tridymite and mullite in clinker. Unmelted grains of detrital quartz occur in both rocks (<3 vol% in paralavas and up to 30 vol% in some clinkers). Compositionally variable siliceous, K-rich peraluminous glass is <30% in paralavas and up to 85% in clinkers. The paralavas resulted from extensive fusion of sandstone–siltstone (clinker), and sideritic/Fe-hydroxide material contained within them, with the proportion of clastic sediments ≫ ferruginous component. Calculated dry liquidus temperatures of the paralavas are 1,120–1,050°C and 920–1,050°C for clinkers, with calculated viscosities at liquidus temperatures of 10^1.6–7.0 and 10^7.0–9.8 Pa s, respectively. Dry liquidus temperatures of glass compositions range between 920 and 1,120°C (paralava) and 920–960°C (clinker), and viscosities at these temperatures are 10^9.7–5.5 and 10^8.8–9.7 Pa s, respectively. Compared with worldwide occurrences of cordierite–sekaninaite in pyrometamorphic rocks, sekaninaite occurs in rocks with X_Fe (mol% FeO/(FeO + MgO)) > 0.8; sekaninaite and Fe-cordierite occur in rocks with X_Fe 0.6–0.8, and cordierite (X_Fe < 0.5) is restricted to rocks with X_Fe < 0.6. The crystal-chemical formula of an anhydrous sekaninaite based on the refined structure is | \textK_0.02 |(\textFe_1.54^{2 +} \textMg_0.40 \textMn_0.06 )_{\Upsigma 2.00}^M [(\textAl_1.98 \textFe_0.02^{2 +} \textSi_1.00 )_{\Upsigma 3.00}^T1 (\textSi_3.94 \textAl_2.04 \textFe_0.02^{2 +} )_{\Upsigma 6.00}^T2 \textO₁₈ ]. \left| {{\text{K}}_{0.02} } \right|({\text{Fe}}_{1.54}^{2 + } {\text{Mg}}_{0.40} {\text{Mn}}_{0.06} )_{\Upsigma 2.00}^{M} [({\text{Al}}_{1.98} {\text{Fe}}_{0.02}^{2 + } {\text{Si}}_{1.00} )_{\Upsigma 3.00}^{T1} ({\text{Si}}_{3.94} {\text{Al}}_{2.04} {\text{Fe}}_{0.02}^{2 + } )_{\Upsigma 6.00}^{T2} {\text{O}}_{18} ].     

Surface energy balance of Bayi Ice Cap in the middle of Qilian Mountains,China

Energy balance at the glacier surface is important for understanding the impacts of climate change on glaciers. Here, we analyzed the characteristics of the glacier surface energy fluxes along with their contributions to glacier melt on Bayi Ice Cap in Qilian Mountains by using a point-scale energy balance model. The half-hourly meteorological data from an automatic weather station (AWS) located on the glacier was used to drive the energy balance model. The model simulated results could accurately represent the mass-balance observations from the stake near the weather station during summer 2016. Our results showed the net radiation (86%) played an important role in the surface energy balance, and the contribution of the turbulent heat fluxes (14%) to the energy budget was relatively less important. A distinct behavior of energy balance, as compared to other continental glaciers in China (e.g., two adjacent glaciers Laohugou No. 12 Glacier and Qiyi Glacier), is the fact that a sustained period of positive turbulent latent flux exists on Bayi Ice Cap during August, causing faster melt rate in the month of August. Our study also presented the effect of frequent summer snowfall in slowing down surface melt by changing the surface albedo during the beginning of the melting season.     

Spatial and temporal constraints on regional-scale groundwater flow in the Pampa del Tamarugal Basin,Atacama Desert,Chile

Aquifers within the Pampa del Tamarugal Basin (Atacama Desert, northern Chile) are the sole source of water for the coastal city of Iquique and the economically important mining industry. Despite this, the regional groundwater system remains poorly understood. Although it is widely accepted that aquifer recharge originates as precipitation in the Altiplano and Andean Cordillera to the east, there remains debate on whether recharge is driven primarily by near-surface groundwater flow in response to periodic flood events or by basal groundwater flux through deep-seated basin fractures. In addressing this debate, the present study quantifies spatial and temporal variability in regional-scale groundwater flow paths at 20.5°S latitude by combining a two-dimensional model of groundwater and heat flow with field observations and δ¹⁸O isotope values in surface water and groundwater. Results suggest that both previously proposed aquifer recharge mechanisms are likely influencing aquifers within the Pampa del Tamarugal Basin; however, each mechanism is operating on different spatial and temporal scales. Storm-driven flood events in the Altiplano readily transmit groundwater to the eastern Pampa del Tamarugal Basin through near-surface groundwater flow on short time scales, e.g., 10⁰–10¹ years, but these effects are likely isolated to aquifers in the eastern third of the basin. In addition, this study illustrates a physical mechanism for groundwater originating in the eastern highlands to recharge aquifers and salars in the western Pampa del Tamarugal Basin over timescales of 10⁴–10⁵ years.     

Effects of vegetation restoration on soil physical properties of abandoned farmland on the Loess Plateau,China

To improve the ecological environment in China, the Chinese government implemented a country-wide ecological protection and reforestation project (namely the “Grain for Green Project”) in 1999 to return cultivated land with slopes of 25° or more to perennial vegetation. Vegetation restoration reduces soil erosion mainly by changing the soil physical properties. Different vegetation restoration methods might produce different impacts on soil physical properties. In this study, two vegetation restoration methods (i.e., natural restoration and artificial restoration) were compared on abandoned farmland in the typically hilly and gullied areas of the Loess Plateau of Northwest China. In the natural restoration method, the farmland was abandoned to natural vegetation succession without irrigation, fertilization or other artificial disturbances. In the artificial restoration method, the farmland was planted with black locust (Robinia pseudoacacia L.) and watered and cultivated for the first two years. Three soil physical properties (i.e., soil moisture, bulk density and aggregation) were investigated under the two vegetation restoration methods. The results showed that the soil moisture and soil bulk density were higher under artificial restoration than under natural restoration within the first three years of vegetation restoration. By the fourth year, the soil moisture and soil bulk density were higher under natural restoration than under artificial restoration. For the stability of soil aggregates?>?0.25 mm, the soil aggregates in the 0-20 cm soil layer were more stable under artificial restoration than under natural restoration, while the results were the opposite for the 40-60 cm soil layer. Overall, the soil physical properties were continuously improved during the restoration of vegetation on abandoned farmland. In choosing between vegetation restoration methods, natural restoration is preferable to artificial restoration, but artificial intervention is needed during the first three years.     

Magnetic activity inside the auroral zones and field-aligned currents

Big perturbations of the magnetic field (amplitudes larger than 250 nT) are simply detected by subtracting the values of a model from the measurements of CHAMP satellite. Taking a full year of CHAMP data and organizing them in four subsets of three months length (spring, summer, autumn, winter), it is found that: (a) the two domains where such big perturbations mainly exist are limited, in both hemispheres, by a parallel of high latitude of the corrected geomagnetic coordinates system; (b) a conspicuous seasonal (annual) variation affects the density of the perturbations and is opposite in the two hemispheres. We hold that these perturbations are linked to the midday magnetic activity within the auroral zone, long ago described by one of us (Mayaud, 1956). The source of the perturbations observed at the satellite altitude would be field-aligned currents resulting from the penetration of the solar wind into the magnetospheric cusps. To cite this article: J.-L. Le Mouël et al., C. R. Geoscience 335 (2003).     

Recovery of groundwater in the Sanriku region contaminated by the tsunami inundation from the 2011 Tohoku earthquake

Many wells in the Sanriku region used as sources for water supply systems were heavily contaminated by the tsunami of the 2011 great Tohoku earthquake on March 11 in 2011. To better understand the nature of the groundwater contamination by the tsunami inundation and to clarify the recovery process of contaminated groundwater at the study wells, groundwater monitoring has been conducted once or twice yearly since early summer in 2011. High and abnormal values of electric conductivity (EC), chloride ion concentration (CIC), Na⁺, Ca⁺, heavy metal ions, and heavier isotopes of the contaminated groundwater were also obtained in April and June 2011. The chemical elements have rapidly and exponentially decreased as a result of effective pumping of the contaminated groundwater from the study wells and because of abundant rainfall in 2011. In April 2015 (about 4 years after the tsunami inundation), the CIC and EC of the contaminated groundwater of two study wells in Minamisanriku town had reached pre-inundation values. The estimated residence times of groundwater of the two study wells were 105–118 days in the full-day pumping stage and 910–1000 days in the daytime-only pumping stage.     

Regional modelling of rainfall-induced runoff using hydrological model by incorporating plant cover effects: case study in Kelantan,Malaysia

The objective of this paper is to develop a spatial temporal runoff modelling of local rainfall patterns effect on the plant cover hilly lands in Kelantan River Basin. Rainfall interception loss based on leaf area index, loss/infiltration on the ground surface, and runoff calculation were considered as the main plant cover effects on the runoff volume. In this regard, a hydrological and geotechnical grid-based regional model (integrated model) was performed using Microsoft Excel^® and GIS framework system for deterministic modelling of rainfall-induced runoff by incorporating plant cover effects. The infiltration process of the current model was integrated with the precipitation distribution method and rainfall interception approach while the runoff analysis of integrated model was employed based on loss/infiltration water on the ground surface with consideration of water interception loss by canopy and the remaining surface water. In the following, the spatial temporal analysis of rainfall-induced runoff was performed using 10 days of hourly rainfall events at the end of December 2014 in Kelantan River Basin. The corresponding changes in pressure head and consequent rate of infiltration were calculated during rainfall events. Subsequently, flood volume is computed using local rainfall patterns, along with water interception loss and the remaining surface water in the study area. The results showed the land cover changes caused significant differences in hydrological response to surface water. The increase in runoff volume of the Kelantan River Basin is as a function of deforestation and urbanization, especially converting the forest area to agricultural land (i.e. rubber and mixed agriculture).     

Oil geochemistry derived from the Qinjiatun–Qikeshu oilfields: insight from light hydrocarbons

A suite of 27 oils from the Qinjiatun–Qikeshu oilfields in the Lishu Fault Depression of the Songliao Basin was analyzed using whole oil gas chromatography. In combination with the relative distribution of C₂₇, C₂₈, and C₂₉ regular steranes, detailed geochemical analyses of light hydrocarbons in oil samples revealed crude oils characterized by the dual input of lower aquatic organisms and higher terrestrial plants. Several light hydrocarbon indicators suggest that the liquid hydrocarbons have maturities equivalent to vitrinite reflectances of around 0.78%–0.93%. This is consistent with the maturity determination of steranes C₂₉ 20S/(20S + 20R) and C₂₉ ααβ/(ααα + αββ). Crude oils derived from the two distinct oilfields likely both have source rocks deposited in a lacustrine environment based on light hydrocarbon parameters and on higher molecular weight hydrocarbon parameters. The results show that light hydrocarbon data in crude oils can provide important information for understanding the geochemical characteristics of the Qinjiatun–Qikeshu oils during geologic evolution.     

Stream Restoration Performance and Its Contribution to the Chesapeake Bay TMDL: Challenges Posed by Climate Change in Urban Areas

In large part driven by total maximum daily load (TMDL) mandates, the restoration community in the Chesapeake Bay region has been implementing novel best management practices (BMPs) and stream restoration designs in urban areas, such as regenerative stream/stormwater conveyance (RSC) structures and stream-wetland complexes (SWCs). However, the nutrient and sediment reduction efficiencies of these novel designs are virtually unknown, and the possibility of increasing riverine flow in the Chesapeake Bay watershed associated with climate change this century necessitates an evaluation of their performance to develop and utilize those that optimize reductions in nutrient and sediment fluxes. We compare pre- and post-construction loads (total nitrogen (TN), total phosphorus (TP), and total suspended solids (TSS)) from RSCs (i.e., upland BMPs) and a SWC (i.e., stream restoration) constructed at the outflow of a highly developed watershed in the Coastal Plain physiographic province of Maryland. The largest of the two RSCs performed best in relation to expected nutrient and sediment reductions because of superior water retention capability. By the length of river reach restored, the SWC attained from 79 to 88% of its N reduction TMDL goal, but only 19 to 23 and 2.7 to 3.1% for TP and TSS, respectively; by watershed area, % attainments of TMDL goals were much lower. Results indicate that SWCs have the potential to curtail N loading from developed catchments, but additional water quality benefits may be limited. Climate change projections indicate that there will be an increased frequency of larger-volume storms that will result in an increase in stormflow runoff from urban areas, and increased pollutant loads will likely curtail potential gains made by efforts to achieve TMDL goals. Given the large-scale implementation of BMPs currently underway to accommodate the Chesapeake Bay TMDL, the restoration community needs to adopt a concerted strategy of building climate resilience into many types of urban BMPs to help attain and maintain loads at TMDL levels in anticipation of a progressively wetter climate throughout this century.