Effects of F,B2O3 and P2O5 on the solubility of water in haplogranite melts compared to natural silicate melts

The effects of F, B₂O₃ and P₂O₅ on the H₂O solubility in a haplogranite liquid (36 wt. % SiO₂, 39 wt. % NaAlSi₃O₈, 25 wt. % KAlSi₃O₈) have been determined at 0.5, 1, 2, and 3 kb and 800, 850, and 900°C. The H₂O solubility increases with increasing F and B content of the melt. The H₂O solubility increase in more important at high pressure (2 and 3 kb) than at low pressure (0.5 kb). At 2 kb and 800°C, the H₂O solubility increases from 5.94 to 8.22 wt. % H₂O with increasing F content in the melt from 0 to 4.55 wt. %, corresponding to a linear H₂O solubility increase of 0.53 mol H₂O/mol F. With addition of 4.35 wt. % B₂O₃, the H₂O solubility increases up to 6.86 wt. % H₂O at 2 kb and 800°C, corresponding to a linear increase of 1.05 mol H₂O/mol B₂O₃. The results allow to define the individual effects of fluorine and boron on H₂O solubility in haplogranitic melts with compositions close to that of H₂O-saturated thermal minima (at 0.5–3 kb). Although P has a dramatic effect on the phase relations in the haplogranite system, its effect on the H₂O solubility was found to be negligible in natural melt compositions. The concominant increase in H₂O solubility and F can not be interpreted on the basis of the available spectroscopic data (existence of hydrated aluminofluoride complexes or not). In contrast, hydrated borates or more probably boroxol complexes have been demonstrated in B-bearing hydrous melts.     

陕西凤县八方山-二里河（铜）铅锌矿床地质特征及成矿模式

在综合分析凤-太矿集区成矿构造特征的基础上，依据以往总结的凤．太矿田铅锌、金矿聚矿构造模式，通过对八方山-二里河铅锌矿床地质特征的分析，总结了找矿标志，初步认为八方山-二里河（铜）铅锌矿床的成矿模式为：“前泥盆纪海底热水喷流沉积一印支-燕山期构造改造型”铅锌矿床。认为成矿物质来源于基底，后期的构造-岩浆改造使基底成矿元素活化，沿同生断裂迁移、改造，最后在泥盆系中形成的扩容性构造部位富集成矿。提出了下一步扩大找矿的方向和建议。     

Closed Basin Brine Evolution and the Influence of Ca–Cl Inflow Waters: Death Valley and Bristol Dry Lake California, Qaidam Basin, China, and Salar de Atacama, Chile

Diagenetic-hydrothermal brines, here called “hydrothermal Ca–Cl brines,” have compositions that reflect interactions between groundwaters and rocks or sediments at elevated temperatures. Hydrothermal Ca–Cl brines reach the surface by convection-driven or topographically driven circulation, and discharge as springs or seeps along fault zones to become important inflow waters in many tectonically active closed basins. Case studies from (1) Qaidam Basin, China, (2) Death Valley, California, (3) Salar de Atacama, Chile, and (4) Bristol Dry Lake, California illustrate that hydrothermal Ca–Cl inflow waters have influenced brine evolution in terms of major ion chemistries and mineral precipitation sequences. All four basins are tectonically active; three (Death Valley, Salar de Atacama, and Qaidam Basin) have well-documented Ca–Cl spring inflow and Holocene faulting. Bristol Dry Lake has young volcanic deposits and Salar de Atacama has an active stratovolcano on its eastern margin, indicating subsurface magma bodies. A midcrustal magma chamber has been identified in southern Death Valley. Volcanism and faulting in these closed basins provides the heat source for hydrothermal-diagenetic processes and the energy and pathways to deliver these waters to the surface.     

The chemistry of bottled mineral and spring waters from Norway,Sweden, Finland and Iceland

Twenty-two bottled mineral and spring waters from Norway, Sweden, Finland and Iceland have been analysed for 71 inorganic chemical parameters with low detection limits as a subset of a large European survey of bottled groundwater chemistry (N = 884). The Nordic bottled groundwaters comprise mainly Ca–Na–HCO₃–Cl water types, but more distinct Ca–HCO₃, Na HCO₃ and Na–Cl water types are also offered. The distributions for most elements fall between groundwater from Fennoscandian Quaternary unconsolidated aquifers and groundwater from Norwegian crystalline bedrock boreholes. Treated tap waters have slightly lower median values for many parameters, but elements associated with plumbing have significantly higher concentrations in tap waters than in bottled waters. The small dataset is able to show that excessive fluoride and uranium contents are potential drinking water problems in Fennoscandia. Nitrate and arsenic displayed low to moderate concentrations, but the number of samples from Finland and Northern Sweden was too low to detect that elevated concentrations of arsenic occur in bedrock boreholes in some regions. The data shows clearly that water sold in plastic bottles is contaminated with antimony. Antimony is toxic and suspected to be carcinogenic, but the levels are well below the EU drinking water limit. The study does not provide any health-based arguments for buying bottled mineral and spring waters for those who are served with drinking water from public waterworks. Drinking water from crystalline bedrock aquifers should be analysed. In case of elevated concentrations of fluoride, uranium or arsenic, most bottled waters, but not all, will be better alternatives when treatment of the well water is not practicable.     

Cosmic structures, parameters & temperature anisotropies: Status and perspectives

After recalling the current understanding of the formation of the large scale structures of the Universe which the distribution of galaxies revealed, I review what the imprint on the Cosmic Microwave Background (CMB) of the seeds of these structures can tell us, has already told us, and what it should tell us within the next five years.     

Absolute abundances and distribution of material versus density and temperature in a coronal condensation

Data derived from coronal eclipse spectra in the visible range are analyzed in terms of electron density and temperature in a coronal condensation using the method recently developed by Jefferies, Orrall and Zirker. A mean density and a certain amount of material are associated to each temperature. Abundances relative to Fe are derived for Ni, Cr, Mn, S, Ca. The absolute abundance of Fe is found to be 2 × 10^?5. No absolute calibration is required. It appears that there must exist a non-negligible amount of ‘cold’ material (T _e < 10⁶K) in the corona, which cannot be observed in the visible spectral range.

     

Star formation in starburst galaxies from near-IR spectroscopy and evolutionary population synthesis

We show that the combined study of the near-IR Stellar Energy Distribution (SED) and emission lines in IR luminous starburst galaxies, using evolutionary population synthesis, gives constraints both on the star formation (SF) parameters and on the relative spatial distribution of the components (burst stars, evolved stars, H II regions, dust). We also note that the He I λ 2.06/Br _γ ratio, used to constrain the stellar upper mass limit, is sensitive to a variety of other factors that should be accounted for.