Rip current hazard assessment on a sandy beach in Liguria,NW Mediterranean

Natural Hazards - Rip currents are one of the most significant environmental hazards for beachgoers and are of interest to coastal scientists. Several studies have been conducted to understand rip...     

Na, Mg, Ni and Cs distribution and speciation after long-term alteration of a simulated nuclear waste glass: A micro-XAS/XRF/XRD and wet chemical study

Microscopic distribution and speciation of Na, Mg, Ni and Cs in a simulated (inactive) nuclear waste glass were studied using micro X-ray fluorescence (μ-XRF) and micro X-ray absorption spectroscopy (μ-XAS), after aqueous leaching during 12 years at 90 °C. Na and Mg are major constituents of the glass that can be used to determine the progress of the glass corrosion process and the nature of secondary alteration phases. Ni and Cs represent dose determining long-lived radionuclides (⁵⁹Ni, ¹³⁵Cs) in vitrified nuclear waste.The Na-Mg μ-XRF maps revealed that the core regions of the glass fragments are apparently unaltered and compositionally homogeneous, whereas rims and interstitial spaces are enriched with Mg-rich smectite formed during the leaching process. The micro X-ray absorption near edge structure (μ-XANES) spectra collected at the Mg K-edge in the altered zones show three sharp resonances typical for crystalline Mg-silicates. These resonances are distinctive of Mg occupying undistorted octahedral positions. In contrast, the μ-XANES spectra collected in the core zones of the glass fragments lack this resonance pattern and are identical to the spectra measured on the pristine (unleached) MW glass.Micro extended X-ray absorption fine structure (μ-EXAFS) and μ-XANES analyses at the Ni K-edge revealed three distinct Ni(II) species: (a) Ni uniformly distributed in the glass matrix, (b) micro-inclusions with high Ni concentrations and (c) Ni associated to the Mg-clay. The comparison with reference spectra of unleached MW and other Ni-bearing silicate glasses indicated that species (a) represents the original coordinative environment of Ni in the glass. The μ-EXAFS analyses revealed that species (b) is structural Ni in trevorite (NiFe₂O₄), which probably formed through unmixing processes during the cooling of the glass melt. The μ-EXAFS of species (c) could be successfully modeled assuming specific adsorption or incorporation of Ni into the lattice of trioctahedral Mg-clay minerals. Alternative models assuming other elements (Ni, Al, Fe) in addition to Mg in the second shell could not be fitted successfully.Aqueous concentration data were used to calculate the speciation of the leaching solutions. Saturation index (SI) calculations indicate undersaturation with respect to NiCO₃ and NiSO₄·7H₂O, but oversaturation with respect to β-Ni(OH)₂. The latter result is probably due to the omission of Ni borate and Ni silicate complexes in the speciation calculations, for which formation constants are not available. With the help of estimation techniques, we could infer that such complexes would dominate the Ni speciation and consequently reduce the SI below the saturation of β-Ni(OH)₂.The μ-XRF maps show that Cs is uniformly distributed in the MW glass, since no region with high Cs concentration could be detected. The Cs L_III-edge μ-XAS spectra were all very similar independently of the degree of alteration, indicating similar coordination environments of Cs in the core regions of the glass as well as in the secondary clays. These spectra largely differ from that measured for pollucite (a potential secondary Cs-phase in altered glasses) implying that the coordination environments of Cs in the MW glass and in pollucite are fundamentally different.The present study shows that μ-XRF and μ-XAS are essential tools in determining the fate and the retention mechanisms of radionuclides released from nuclear waste during aqueous alteration. Our spectroscopic analyses allowed us to exclude formation of specific Ni and Cs secondary solids (e.g. nepouite, β-Ni(OH)₂, pollucite) during the aqueous alteration. Ni and Cs are instead distributed as trace elements in the alteration phases formed by major elements during the leaching process. Our results imply that solid solution and/or adsorption equilibria, rather than pure phase solubility equilibria, are the adequate chemical models to determine Ni and Cs aqueous concentrations in performance assessments for radioactive waste repositories.     

Correction to: Rip current hazard assessment on a sandy beach in Liguria,NW Mediterranean

Natural Hazards - The article was published showing the first two author names in the wrong order.     

Variability of zinc and manganese concentrations in relation to sex and season in the bivalve Donax trunculus

Females of Donax trunculus L. show higher concentrations of Mn and Zn than males. Differences are very high for Mn which also shows very large monthly fluctuations. Both the metals present higher contents during the period of gonadic maturation. Some high values of manganese found in the period when gonads are resting suggest the influence of sharp environmental variations in the area where bivalves have been collected.     

Silicic magmas from the continental Cameroon Volcanic Line (Oku, Bambouto and Ngaoundere): 40Ar-39Ar dates, petrology, Sr-Nd-O isotopes and their petrogenetic significance

The intraplate Cameroon Volcanic Line (CVL) straddles the African-South Atlantic continent-ocean boundary and is composed mainly of alkaline basic volcanic rocks. Voluminous silicic volcanics characterize the continental sector of the CVL. We present here new geochemical, isotopic (Sr-Nd-O) and ⁴⁰Ar/³⁹Ar geochronological data on the main silicic volcanic centres of the Western (Mt. Oku, Sabga and Mt. Bambouto) and Eastern (Ngaoundere plateau) Cameroon Highlands. The silicic volcanism of Mt. Oku, Sabga and Mt. Bambouto occurred between 25 and 15 Ma and is represented by voluminous quartz-normative trachytes and minor rhyolitic ignimbrites. At Mt. Bambouto central volcano about 700 m of silicic volcanics erupted in less than 2.7 million years. These silicic volcanics are associated with slightly to moderately alkaline basalts and minor basanites. In general, onset of the silicic volcanism migrated from NE (Oku: 25 Ma) to SW (Sabga: 23 Ma; Bambouto: 18 Ma; and Mt. Manengouba: 12 Ma). The silicic volcanism of the Ngaoundere plateau (eastern branch of the CVL) is instead dominated by nepheline-normative trachytes which are associated with strongly alkaline basalts and basanitic rocks. These Ne-trachytes are younger (11-9 Ma) than the Q-trachytes of the Western Highlands. The least differentiated silicic volcanics are isotopically similar (⁸⁷Sr/⁸⁶Sr < 0.70380; ¹⁴³Nd/¹⁴⁴Nd > 0.51278) to the associated alkaline basalts suggesting differentiation processes without appreciable interaction with crustal materials. Such interactions may, however, have played some role in the genesis of the most evolved silicic volcanics which have ⁸⁷Sr/⁸⁶Sr as high as 0.705–0.714. Fractional crystallization is the preferred mechanism for genesis of the silicic melts of both Western and Eastern Highlands, as shown by modeling major and trace element variations. The genesis of the least evolved Q-trachytes from the Western Highlands, starting from slightly to moderately alkaline basalts, is compatible with fractionation of dominantly plagioclase, clinopyroxene and magnetite. Crystal fractionation may have occurred at low pressure and at QFM buffer f _O2conditions. Parental magmas of the Ngaoundere Ne-trachytes are likely instead to have been strongly alkaline basalts which evolved through crystal fractionation at higher P (6-2 kbar) and f _O2 (QFM + 2). The migration (25 to 12 Ma) of the silicic volcanism from NE to SW in the continental sector of the CVL is reminiscent of that (31-5 Ma) of the onset of the basic volcanism in the oceanic sector (Principe to Pagalu islands) of the CVL. These ages, and that (11-9 Ma) of the silicic volcanism of the Ngaoundere plateau, indicate that the Cameroon Volcanic Line as a whole may not be easily interpreted as the surface expression of hot-spot magmatism. Received: 24 February 1998 / Accepted: 22 September 1998     

The relation between Lyman α absorbers and gas-rich galaxies in the local Universe

We use high-resolution hydrodynamical simulations to investigate the spatial correlation between weak  ( N _{H  i} < 10¹⁵ cm⁻²)  Lyα absorbers and gas-rich galaxies in the local Universe. We confirm that Lyα absorbers are preferentially expected near gas-rich galaxies and that the degree of correlation increases with the column density of the absorber. The real-space galaxy auto-correlation is stronger than the cross-correlation (correlation lengths   r _0,gg= 3.1 ± 0.1 Mpc  h ⁻¹  and   r _0,ag= 1.4 ± 0.1 Mpc  h ⁻¹  , respectively), in contrast with the recent results of Ryan-Weber, and the auto-correlation of absorbers is very weak. These results are robust to the presence of strong galactic winds in the hydrodynamical simulations. In redshift space, a further mismatch arises since at small separations the distortion pattern of the simulated galaxy–absorber cross-correlation function is different from the one measured by Ryan-Weber. However, when sampling the intergalactic medium along a limited number of lines-of-sight, as in the real data, uncertainties in the cross-correlation estimates are large enough to account for these discrepancies. Our analysis suggests that the statistical significance of difference between the cross-correlation and auto-correlation signal in current data sets is ∼1σ only.     

The dynamical equations of polar wander and the global characteristics of the lithosphere as extracted from rotational data

The initial value problem describing the linear responses of the spin axis of a layered viscoelastic planet from surface loading is studied by means of Laplace transform techniques. A complete solution of polar motion requires the usage of two classes of eigenspectra: one arising from viscoelastic relaxation of the mantle due to surface forcing, the other involving the gradual readjustment of the spin axis as a consequence of mantle viscoelasticity. Our analytical 4-layer model comprising an elastic lithosphere, a two-layer, adiabatically stratified, viscoelastic mantle and an inviscid core has been incorporated into this formalism in which rotational deformation and isostatic relaxation are taken into account for all times. From employing both sets of rotational data, polar variations from the 70 years of data from the International Latitude Service (I.L.S.) and the non-tidal deceleration of the length of the day (l.o.d.) an estimate of the globally averaged lithosphere of between 130 and 200 km is obtained from the long wavelength flexural mode due to the degree-two harmonic. This range of values may have strong implications on the mode of continental evolution.