Uranium in submarine metalliferous deposits

Hydrothermal submarine metalliferous deposits, common in areas of the ocean floor with high heat flow, contain generally about 10 ppm U as an order of magnitude. The $\text{U}{}^{234}\text{U}{}^{238}$ ratio is in the majority of cases close to that of seawater; only in a few cases is it anomalously high. Anomalous $\text{U}{}^{234}\text{U}{}^{238}$ ratios are coupled with low U concentrations. These data are explained by a model where thermal water (essentially heated seawater) in its sub-bottom circulation often is unable to leach U from the basaltic oceanic crust; in fact, these thermal waters may in some cases lose U. When leaching of U from the basalt does take place, probably during shallow stages of the sub-bottom circulation, the resulting anomalous $\text{U}{}^{234}\text{U}{}^{238}$ ratio can be preserved in the hydrothermal deposit only if mixing with ‘seawater’ U is prevented.     

Formation of nitrite during the decomposition of aqueous ammonium niumate,under natural ultraviolet radiation

Summary The photodecomposition of ammonium nitrate at various concentrations, in ventilated, aqueous solutions, is investigated as a function of radiation intensity, both under sunlight illumination and under artificial ultraviolet light. The process of decomposition, to nitrogen and water, of ammonium nitrite formed, competes with the formation of NO ₂ ^– which is, otherwise, proportional to the radiation absorbed.     

Change of aqueous sodium nitrate under natural and artificial ultraviolet radiation

Summary The process of nitrite formation, by the action of the near-ultraviolet radiation on sodium nitrate solutions, is investigated both in the laboratory and at different elevations under sunlight. The release of NO _x , from solutions irradiated, is found to compete with the generation of nitrite which is proportional to the radiation absorbed by the solution.     

Palagonite,hyaloclastites and alteration of volcanic glass in the ocean

Palagonite is an hydrated and often altered glass usually associated with sub-aqueous basaltic volcanites. It is commonly considered as an alteration product of normal basaltic glass (sideromelane) with which it is associated in hyaloclastites. Existing information on the diffusion rates of water in natural glasses suggests, however, that the hydration which causes the formation of palagonite takes place at relatively high temperature, that is mainly during effusion and cooling of the lava under water. It is also suggested that generally palagonite is not formed in nature to any great extent from the alteration of sideromelane. Palagonite appears to devitrify much faster than normal unhydrated glass of the same composition. This fact may explain some previously unclear data on the occurrence of volcanic glasses on the floor of the oceans; namely, the existence of totally devitrified glasses in some recent sediments and the finding of unaltered glass in older deposits.     

Records of environmental and climatic changes during the late Holocene from Svalbard: palaeolimnology of Kongressvatnet

A multi-core, multidisciplinary palaeolimnological study of the partially varved sediment of a deep, meromictic, arctic lake, Kongressvatnet (Svalbard, Western Spitsbergen), provides a record of environmental and climatic changes during last ca. 1800 years. The chronology of sedimentation was established using several dating techniques (¹³⁷Cs, ²¹⁰Pb, varve counts, palaeomagnetic correlation). A multiproxy record of palaeolimnological variability was compiled based on sedimentation rates, magnetic properties, varve thickness, organic matter, geochemistry, pigments from algal and photosynthetic bacteria, mineralogy and biological assemblages (diatoms, Cladocera). The major features recognised in our master core K99-3 include a shift in sediment source and supply (magnetic measurements, geochemistry) probably caused by glaciological changes in the catchment around 38–32 cm core depth (AD 700–820). Additional environmental changes are inferred at 20–18, 8–4.5 and 3–2 cm (AD ca. 1160–1255; 1715–1880; 1940–1963, respectively). During the past ca. 120 years a prominent sedimentological change from brownish-grey, partly laminated silt-clay (varves) to black organic-rich deposits was observed. From AD 1350 to AD1880 the sediment is comprised of a continuous sequence of varves, whereas the earlier sediments are mostly homogeneous with only a few short intercalated laminated sections between AD 860 and 1350. Sedimentation and accumulation rates increased during the last 30 years (modern warming). Pigment concentrations are very low in the lower ca. 32 cm of the core (AD 820) probably because of the high turbidity high energy environment. The high sulphur content in the uppermost 32 cm of sediment has given rise to two horizontally stratified populations of sulphur anaerobic photosynthetic bacteria, as inferred from their specific carotenoids. These bacteria populations are much more abundant during the Little Ice Age (LIA) than during warmer periods (e.g., during the Medieval Warm Period and 20th century). Diatoms are lacking from the core base up to 18 cm (ca. AD 1255); at this level, species indicative of mesotrophic water are present, whereas from 17 cm to the top of the core, oligotrophic taxa such as Staurosira construens/S. pinnata complex dominate, indicating extended ice coverage and more oligotrophic waters during the LIA. The concentration of Cladocera subfossil remains (dominated by Chydorus) are relatively high in the deepest sections (54–32 cm), whereas the upper 32 cm are characterized by a very low concentration of remains, possibly because of the strongly anoxic conditions, and in this upper sediment section rotifer resting eggs become prevalent. We interpret these changes as responses to climate forcing through its impact on glacial melt water, lake ice cover duration and mainly redox conditions in deep water. The observed changes suggest that at least some of our recorded changes may parallel the Greenland Ice core, although our study added more details about the inferred climatic changes. Further aspects are discussed, such as catchment processes, glacial activity, duration of the Medieval Warm Period, the Little Ice Age, local human activity, and limnology.     

Kinematic and geochronological constraints on shear deformation in the Ferriere-Mollières shear zone (Argentera-Mercantour Massif,Western Alps): implications for the evolution of the Southern European Variscan Belt

International Journal of Earth Sciences - In the Western Alps, a steeply dipping km-scale shear zone (the Ferriere-Mollières shear zone) cross-cuts Variscan migmatites in the...     

A soft computing approach to tunnel face stability in a probabilistic framework

Acta Geotechnica - Tunnel face is important for shallow tunnels to avoid collapses. In this study, tunnel face stability is studied with soft computing techniques. A database is created based on...     

Shear and dilatational wave velocities for unsaturated soils

The primary objective of this study is for presenting some simple-to-use expressions relating the shear and dilatational wave velocities (V_S and V_P) to some physical and constitutive parameters of unsaturated soils. To this purpose, a simplified formulation is developed using the theory of linear poroelasticity in conjunction with some constitutive parameters widely used in geotechnical engineering. The derived expressions are of practical interest in view of the fact that they could be employed for evaluating the involved soil parameters from V_S and V_P measurements by in-situ or laboratory geophysical tests.     

Including root reinforcement variability in a probabilistic 3D stability model

Forests play a significant role in protecting people, settlements in mountainous terrains from hydrogeomorphic hazards, including shallow landslides. Although several studies have investigated the interactions between forests and slope instabilities, a full understanding of them has not yet been obtained. Additionally, models that incorporate forest stand properties into slope failure probability analyses have not been developed. In principle, physical‐based models, which are powerful tools for landslide hazard analyses, represent an appropriate approach to linking stand properties and slope stability. However, the reliability of these models depends on numerous parameters that describe highly complex geotechnical and hydrological processes (e.g. potential failure depth, saturation ratio, root reinforcement, etc.) that are difficult to measure and model. In particular, the spatial heterogeneity of root reinforcement remains a problem, and the use of physically based models from a forest management perspective has been limited. This paper presents a procedure for assessing slope stability in terms of the Factor of Safety that accounts for forest stand characteristics such as tree density, average diameter at breast height and minimum distance between trees. The procedure combines a three‐dimensional (3D) slope stability model with an evaluation of the variability of root reinforcement in terms of a probability distribution, according to forest characteristics. Monte Carlo simulation is used to account for the residual uncertainties in both stand characteristics and 3D stability model parameters. The proposed method was applied in a subalpine catchment in the Italian Alps, mainly covered by coniferous forest and characterized by steep slopes and high landslide risk. The results suggest that the procedure is highly reliable, according to landslide inventory maps [area under the ROC curve (AUC) is 0.82 and modified success rate (MSR) is 0.70]. Thus, it represents a promising tool for studying the role of root reinforcement in landslide hazard mapping and guiding forest management from a slope stability perspective. Copyright © 2017 John Wiley & Sons, Ltd.