Biogeochemical behavior of Ampelozizyphus amazonicus Ducke in the Pitinga mining district, Amazon, Brazil

The vegetal species Ampelozizyphus amazonicus Ducke (Rhamnaceae Family) was chosen as a sampling medium for the lateritic surfaces of the Pitinga Mine in the Amazon region, in order to study the biogeochemical behavior of this species and compare it with the chemical composition of a reference plant. The Pitinga mining district is one of the largest producers of tin in the world. This district contains unique deposits of cryolite and rare metals such as Zr, Nb, Ta, Y and REEs related to granitic bodies that intrude into the volcanic and acid pyroclastic rocks. The results showed that the species A. amazonicus predominantly concentrates significant levels of Zr, Nb, Ta, Th, Be, Sc over U, Hf, Ga and In. These elements are characteristic of the mineral paragenesis for the region, suggesting that this plant can provide a representative sampling medium future geochemical exploration programs in the region.     

Garnet growth at high- and ultra-high pressure conditions and the effect of element fractionation on mineral modes and composition

In this paper we show that thermodynamic forward modelling, using Gibbs energy minimisation with consideration of element fractionation into refractory phases and/or liberated fluids, is able to extract information about the complex physical and chemical evolution of a deeply subducted rock volume. By comparing complex compositional growth zonations in garnets from high-and ultra-high pressure samples with those derived from thermodynamic forward modelling, we yield an insight into the effects of element fractionation on composition and modes of the co-genetic metamorphic phase assemblage. Our results demonstrate that fractionation effects cause discontinuous growth and re-crystallisation of metamorphic minerals in high pressure rocks. Reduced or hindered mineral growth at UHP conditions can control the inclusion and preservation of minerals indicative for UHP metamorphism, such as coesite, thus masking peak pressure conditions reached in subducted rocks.Further, our results demonstrate that fractional garnet crystallisation leads to strong compositional gradients and step-like zonation patterns in garnet, a feature often observed in high-and ultra-high pressure rocks. Thermodynamic forward modelling allows the interpretation of commonly observed garnet growth zonation patterns in terms of garnet forming reactions and the relative timing of garnet growth with respect to the rock's pressure–temperature path. Such a correlation is essential for the determination of tectonic and metamorphic rates in subduction zones as well as for the understanding of trace element signatures in subduction related rocks. It therefore should be commonplace in the investigation of metamorphic processes in subduction zones.     

Origin of the Tongshankou porphyry–skarn Cu–Mo deposit,eastern Yangtze craton,Eastern China: geochronological,geochemical, and Sr–Nd–Hf isotopic constraints

The Tongshankou Cu–Mo deposit, located in the westernmost Daye district of the Late Mesozoic Metallogenic Belt along the Middle-Lower reaches of the Yangtze River, eastern China, consists mainly of porphyry and skarn ores hosted in the Tongshankou granodiorite and along the contact with the Lower Triassic marine carbonates, respectively. Sensitive high-resolution ion microprobe zircon U–Pb dating constrains the crystallization of the granodiorite at 140.6 ± 2.4 Ma (1σ). Six molybdenite samples from the porphyry ores yield Re–Os isochron age of 143.8 ± 2.6 Ma (2σ), while a phlogopite sample from the skarn ores yields an ⁴⁰Ar/³⁹Ar plateau age of 143.0 ± 0.3 Ma and an isochron age of 143.8 ± 0.8 Ma (2σ), indicating an earliest Cretaceous mineralization event. The Tongshankou granodiorite has geochemical features resembling slab-derived adakites, such as high Sr (740–1,300 ppm) and enrichment in light rare earth elements (REE), low Sc (<10 ppm), Y (<13.3 ppm), and depletion in heavy REE (<1.2 ppm Yb), and resultant high Sr/Y (60–92) and La/Yb (26–75) ratios. However, they differ from typical subduction-related adakites by high K, low MgO and Mg#, and radiogenic Sr–Nd–Hf isotopic compositions, with (⁸⁷Sr/⁸⁶Sr) _t  = 0.7062–0.7067, ɛ _Nd(t) = −4.37 to −4.63, (¹⁷⁶Hf/¹⁷⁷Hf) _t  = 0.282469–0.282590, and ɛ _Hf(t) = −3.3 to −7.6. The geochemical and isotopic data, coupled with geological analysis, indicate that the Tongshankou granodiorite was most likely generated by partial melting of enriched lithospheric mantle that was previously metasomitized by slab melts related to an ancient subduction system. Magmas derived from such a source could have acquired a high oxidation state, as indicated by the assemblage of quartz–magnetite–titanite–amphibole–Mg-rich biotite in the Tongshankou granodiorite and the compositions of magmatic biotite that fall in the field between the NiNiO and magnetite–hematite buffers in the Fe³⁺–Fe²⁺–Mg diagram. Sulfur would have been present as sulfates in such highly oxidized magmas, so that chalcophile elements Cu and Mo were retained as incompatible elements in the melt, contributing to subsequent mineralization. A compilation of existing data reveals that porphyry and porphyry-related Cu–Fe–Au–Mo mineralization from Daye and other districts of the Metallogenic Belt along the Middle-Lower reaches of the Yangtze River took place coevally in the Early Cretaceous and was related to an intracontinental extensional environment, distinctly different from the arc-compressive setting of the Cenozoic age that has been responsible for the emplacement of most porphyry Cu deposits of the Pacific Rim.     

Time dependent structural architecture of subsidiary fracturing and stress pattern in the tip region of an extensional growth fault system, Tarquinia basin, Italy

Fault tip regions, relay ramps and accommodation zones in between major segments of extensional fault systems provide zones of additional structural and stratigraphic complexities and also significantly affect their hydraulic behaviour. The great interest for both academic and industrial purposes encouraged specific studies of fault tip regions that, in some cases, produced controversial results. We approached the study of fault tip regions by integrating structural, AMS and stratigraphic analyses of the tip of an extensional growth fault system in the Tarquinia basin, on the Tyrrhenian side of the Northern Apennines. Detailed structural mapping indicates the occurrence of systematic relationships between the orientation of the main subsidiary fault zones, the orientation and position of the two main joint sets developed in the fault damage zones, and the overprinting relationships between the two main joint sets themselves. Microstructural analysis of fault core rocks indicates a progression of deformation from soft-sediment to brittle conditions. The AMS study supports the evolution of deformation under a constantly oriented stress field. By combining this multidisciplinary information we propose an evolutionary model for the tip of the extensional growth fault system that accounts for the progressively changing sediment rheological properties, and for the time dependent subsidiary deformation pattern by invoking the interplay between the regional stress field and the local, kinematically-derived one by fault activity. We also speculate on the overall implications for fluid flow of the proposed evolutionary model.     

Crowdsourcing a cyclist perspective on suggested recreational paths in real-world networks

ABSTRACT

Routing and navigation services for leisure activities are conditioned by special needs and trade-offs. The advent of online communities and large crowdsourced datasets offers opportunities to improve the adoption of a user’s perspective in these suggested paths. This paper focuses on achieving two goals. First, the presented methodology analyses a dataset of 190,610 historical GPS traces to gain insights into the appreciation or attractiveness of each edge in a real-world network for a specific leisure activity (i.e. road cycling). Second, as literature on these leisure activities is still sparse, we want to create a thorough understanding of the activities at hand for future work. An appreciation model is proposed and the spread of this score is analyzed in shortest-path alternatives of popular routing engines for this activity. This analysis successfully discriminates these shortest paths based on the scoring value and three morphological parameters of the path. However, the robustness of the model should be improved to ensure the viability of the proposed approach in future work. More specifically, further research on the local optimality of the route choices will be imperative.     

Recent trends in annual snowline variations in the northern wet outer tropics: case studies from southern Cordillera Blanca,Peru

TL-moments approach has been used in an analysis to identify the best-fitting distributions to represent the annual series of maximum streamflow data over seven stations in Johor, Malaysia. The TL-moments with different trimming values are used to estimate the parameter of the selected distributions namely: Three-parameter lognormal (LN3) and Pearson Type III (P3) distribution. The main objective of this study is to derive the TL-moments (t ₁,0), t ₁?=?1,2,3,4 methods for LN3 and P3 distributions. The performance of TL-moments (t ₁,0), t ₁?=?1,2,3,4 was compared with L-moments through Monte Carlo simulation and streamflow data over a station in Johor, Malaysia. The absolute error is used to test the influence of TL-moments methods on estimated probability distribution functions. From the cases in this study, the results show that TL-moments with four trimmed smallest values from the conceptual sample (TL-moments [4, 0]) of LN3 distribution was the most appropriate in most of the stations of the annual maximum streamflow series in Johor, Malaysia.     

Actor-Based Design of a Management System for the Elephant Marsh Fishery in Malawi

In Malawi, fishing community user groups known as beach village committees, traditional chiefs, government officers, and fishers are the key players in fisheries management. Fish catch trends at the Elephant Marsh Fishery in southern Malawi are declining. Based on interviews and participant observation, this article uses an actor-based framework (known as Action-in-Context) to unveil the issues that are crucial in devising a sustainable governance system for the fishery. We establish and propose that the key social variables for the design of a three-pillared (locally based, weak, and amorphous) resilient institution for sustainability of the Elephant Marsh Fishery are (i) the social reputation of the leaders of local fishery institutions (beach village committee leaders), and (ii) the power dynamics between traditional chiefs and these local fishery leaders. We end the article by exploring the implications of the findings on the sustainability of the fishery under rising resource pressure.     

A record of the Messinian salinity crisis in the eastern Ionian tectonically active domain (Greece,eastern Mediterranean)

This integrated study (field observations, micropalaeontology, magnetostratigraphy, geochemistry, borehole data and seismic profiles) of the Messinian–Zanclean deposits on Zakynthos Island (Ionian Sea) focuses on the sedimentary succession recording the pre‐evaporitic phase of the Messinian salinity crisis (MSC) through the re‐establishment of the marine conditions in a transitional area between the eastern and the western Mediterranean. Two intervals are distinguished through the palaeoenvironmental reconstruction of the pre‐evaporitic Messinian in Kalamaki: (a) 6.45–6.122 Ma and (b) 6.122–5.97 Ma. Both the planktonic foraminifer and the fish assemblages indicate a cooling phase punctuated by hypersalinity episodes at around 6.05 Ma. Two evaporite units are recognized and associated with the tectonic evolution of the Kalamaki–Argassi area. The Primary Lower Gypsum (PLG) unit was deposited during the first MSC stage (5.971–5.60 Ma) in late‐Messinian marginal basins within the pre‐Apulian foreland basin and in the wedge‐top (<300 m) developed over the Ionian zone. During the second MSC stage (5.60–5.55 Ma), the PLG evaporites were deeply eroded in the forebulge–backbulge and the wedge‐top areas, and supplied the foreland basin's depocentre with gypsum turbidites assigned to the Resedimented Lower Gypsum (RLG) unit. In this study, we propose a simple model for the Neogene–Pliocene continental foreland‐directed migration of the Hellenide thrusting, which explains the palaeogeography of the Zakynthos basin. The diapiric movements of the Ionian Triassic evaporites regulated the configuration and the overall subsidence of the foreland basin and, therefore, the MSC expression in this area.