On ionospheric disturbances caused by the solar activity of November 1960

Summary On November 1960 a special solar activity occured, producing characteristic disturbances in the ionosphere. Athens center followed this activity by vertical sounding and by Riometer recordings. They are evidences for proton events producing deep absorption in the ionosphere and aurora extending till 38° latitude. Some observations concerning July 1961 solar activity are reported. World wide decrease of the maximum electron density reported during the November period was observed also in Athens. Ionospheric disturbances following vertical sounding observations are of «negative» type.     

Potential of Argo Drifters for Estimating Biological Production within the Water Column

Argo drifters provide information of the vertical structure in the water column and have a potential for the improvement of understanding phytoplankton primary production and biogeochemical cycles in combination with ocean color satellite data, which can obtain the horizontal distribution of phytoplankton biomass in the surface layer. Our examples show that using Argo drifters with satellite-measured horizontal distribution of phytoplankton biomass at the sea surface allow an improved understanding of the development of the spring bloom. The other possible uses of Argo drifter are discussed.     

Controls on mineral deposit occurrence inferred from analysis of their spatial pattern and spatial association with geological features

In this paper, point pattern analysis, fractal analysis and Fry analysis were employed to study the spatial pattern of known occurrences of mineral deposits of the type sought, whereas distance distribution method was applied to study the spatial associations between various geological features and known occurrences of mineral deposits of the type sought. In the Aroroy district (Philippines), the results of the applications of these spatial analytical techniques support a conceptual model of district-scale mechanism of geologic controls on low-sulphidation epithermal Au mineralization, which involves a more-or-less regular mesh of interlinked zones of extension faults/fractures at and/or around intersections of NNW- and NW-trending strike-slip faults/fractures. Integration of spatial evidential data layers representing these structural controls and surficial geochemical anomalies, via knowledge-guided application of data-driven evidential belief functions, results in delineation of prospective areas occupying about 25% of the district, in which there is about 70% likelihood of undiscovered occurrences of low-sulphidation epithermal Au deposits.     

A trigger-tube tracer dilution technique for determining Darcy and apparent velocities of groundwater in dug wells: A case study on phreatic aquiferous formation in Bamenda-Cameroon

The need to understand flow within aquiferous formations for a complete evaluation of groundwater resource and quality control prompts the determination of groundwater velocities through well dilution technique. Well dilution techniques utilize tracer solutions after establishing an initial homogenous condition to monitor the flow rate of ambient groundwater into the wells. Application of dilution techniques in wells makes it feasible to determine the velocities of groundwater in the aquiferous formation surrounding the well. In this study, a simple trigger-tube tracer dilution technique was employed to determine the Darcy and apparent velocities of groundwater in the phreatic aquiferous formation in Bamenda, Cameroon. Eighteen(18) hand dug-wells at different locations within Bamenda were sampled by utilizing sodium chloride(NaCl) as the conservative tracer. Field estimates of groundwater flow velocities in the phreatic aquiferous formation in Bamenda reveal Darcy's groundwater velocity in the range of 0.39 m/d at Nacho to 130.64 m/d at Foncha Street and apparent velocity in the range of 0.78 m/d at Nacho to 277.86 m/d at Foncha Street. The immense variations in the velocities of groundwater indicate that the groundwater flows at different rates and directions within the aquiferous formation in Bamenda, possibly due to variations in their hydraulic conductivities. Moreover, the spatial variations in the formation types, facies changes, thickness, and layering of the aquiferous formation also contribute to the variation of velocities. Areas with low groundwater velocities are associated with a lower contaminant transport rate when compared to areas with high groundwater velocities. The findings of this study are important for assessing the rates of pollutant movement in the subsurface, as well as the effectiveness and efficacy of the trigger-tube technique in evaluating the hydraulic properties of aquiferous formations.     

Modeling vertical stratification of CO2 injected into a deep layered aquifer

The vertical stratification of carbon dioxide (CO₂) injected into a deep layered aquifer made up of high-permeability and low-permeability layers, such as Utsira aquifer at Sleipner site in Norway, is investigated with a Buckley–Leverett equation including gravity effects. In a first step, we study both by theory and simulation the application of this equation to the vertical migration of a light phase (CO₂), in a denser phase (water), in 1D vertical columns filled with different types of porous media: homogeneous, piecewise homogeneous, layered periodic and finally heterogeneous. For each case, we solve the associated Riemann problems and propose semi-analytical solutions describing the spatial and temporal evolution of the light phase saturation. These solutions agree well with simulation results. We show that the flux continuity condition at interfaces between high-permeability and low-permeability layers leads to CO₂ saturation discontinuities at these interfaces and, in particular, to a saturation increase beneath low-permeability layers. In a second step, we analyze the vertical migration of a CO₂ plume injected into a 2D layered aquifer. We show that the CO₂ vertical stratification under each low-permeability layer is induced, as in 1D columns, by the flux continuity condition at interfaces. As the injection takes place at the bottom of the aquifer the velocity and the flux function decrease with elevation and this phenomenon is proposed to explain the stratification under each mudstone layer as observed at Sleipner site.     

Carbon Monoxide on Jupiter: Evidence for Both Internal and External Sources

Thirteen lines of the CO band near 4.7 μm have been observed on a jovian hot spot at a resolution of 0.045 cm⁻¹. The measured line profiles indicate that the CO mole fraction is 1.0±0.2 ppb around the 6-bar level and is larger in the upper troposphere and/or stratosphere. An external source of CO providing an abundance of 4⁺³₋₂×10¹⁶ molecules cm⁻² is implied by the observations in addition to the amount deposited at high altitude by the Shoemaker-Levy 9 collision. From a simple diffusion model, we estimate that the CO production rate is (1.5-10)×10⁶ molecules cm⁻² s⁻¹ assuming an eddy diffusion coefficient around the tropopause between 300 and 1500 cm² s⁻¹. Precipitation of oxygen atoms from the jovian magnetosphere or photochemistry of water vapor from meteoroidal material can only provide a negligible contribution to this amount. A significant fraction of the CO in Jupiter's upper atmosphere may be formed by shock chemistry due to the infall of kilometer- to subkilometer-size Jupiter family comets. Using the impact rate from Levison et al. (2000, Icarus143, 415-420) rescaled by Bottke et al. (2002, Icarus156, 399-433), this source can provide the observed stratospheric CO only if the eddy diffusion coefficient around the tropopause is 100-300 cm² s⁻¹. Higher values, ∼700 cm² s⁻¹, would require an impact rate larger by a factor of 5-10, which cannot be excluded considering uncertainties in the distribution of Jupiter family comets. Such a large rate is indeed consistent with the observed cratering record of the Galilean satellites (Zahnle et al. 1998, Icarus136, 202-222). On the other hand, the ∼1 ppb concentration in the lower troposphere requires an internal source. Revisiting the disequilibrium chemistry of CO in Jupiter, we conclude that rapid vertical mixing can provide the required amount of CO at ∼6 bar for a global oxygen abundance of 0.2-9 times the solar value considering the uncertainties in the convective mixing rate and in the chemical constants.     

Periodic orbits in a dynamical system with three degrees of freedom

We use the analytical method of Lindstedt to make an inventory of the regular families of periodic orbits and to obtain approximate analytical solutions in a three-dimensional harmonic oscillator with perturbing cubic terms. We compare these solutions to the results of numerical computations at a specific orbital resonance.     

Boron isotopic fractionation related to boron sorption on humic acid and the structure of surface complexes formed

Boron isotopic fractionation during adsorption onto Ca-flocculated Aldrich humic acid (HA) has been investigated experimentally as a function of solution pH at 25°C and I = 0.15 M. Boron aqueous concentration and isotopic composition were determined by Cs₂BO₂⁺ Positive Thermal Ionization Mass Spectrometry analysis, while the structure of B surface complexes on HA was characterized using ¹¹B Magic Angle Spinning Nuclear Magnetic Resonance (MAS NMR). Significant B sorption on HA was observed at 6 < pH < 12 with a maximum value of Kd, the partition coefficient between adsorbed and aqueous boron, equal to 40 at pH = 9.5-10. Combined ¹¹B MAS NMR analysis and FITEQL modeling of B sorption on HA showed that this element forms tetrahedrally coordinated five- or six-membered ring chelates, most likely 1,2-diol and 1,3-diol complexes at alkaline pH (8 < pH < 11) and dicarboxylic complexes at near neutral conditions (6 < pH < 9). Results of this study demonstrate for the first time that boron sorption on HA induces a strong pH-dependent isotope fractionation—with ¹¹B depleted at the surface of HA—that reaches a maximum at 5 < pH < 9 (α = 0.975, Δ = −25‰) and decreases sharply at pH >9. The measured isotope fractionation cannot be modeled assuming that the isotopic composition of the sorbed borate species is identical to that of B(OH)₄^- species in the parent solution. It is shown that the extent of isotopic fractionation depends not only on B aqueous speciation but also on the distribution and structure of the borate surface complexes formed. In agreement with energetic constrains, calculation of the isotope fractionation factors between aqueous boric acid and boron surface complexes suggests that the formation of the strained six-membered ring 1,3-diol complex yields a much higher fractionation (α_BLP1−III = 0.954-0.960, Δ = −41/-47‰) than that of the very stable five-membered ring 1,2-diol (α_BLP2−III = 0.983, Δ = −18‰). The results of this study open new perspectives to understand and model boron biogeochemical cycle. It is predicted that boron sorption onto organic matter can have important consequences for the boron isotopic composition of surface water reservoirs (seawater, groundwater, soil waters) in which either abundant organic surfaces or significant boron concentrations are available. In addition, the large isotope fractionation between aqueous boric acid and surface boron-organic complexes found in the present work makes boron a promising tracer of biologic activity.