The Grader layered intrusion (Havre-Saint-Pierre Anorthosite, Quebec) and genesis of nelsonite and other Fe–Ti–P ores

The Grader layered intrusion is part of the Havre-Saint-Pierre anorthosite in the Grenville Province (Quebec, Canada). This intrusion has a basin-like morphology and contains significant resources of Fe–Ti–P in ilmenite and apatite. Outcropping lithologies are massive oxide alternating with anorthosite layers, banded ilmenite–apatite–plagioclase rocks and layered oxide apatite (gabbro-)norites. Drill cores provide evidence for stratigraphic variations of mineral and whole rock compositions controlled by fractional crystallization with the successive appearance of liquidus phases: plagioclase and ilmenite followed by apatite, then orthopyroxene together with magnetite, and finally clinopyroxene. This atypical sequence of crystallization resulted in the formation of plagioclase–ilmenite–apatite cumulates or “nelsonites” in plagioclase-free layers. Fine-grained ferrodiorites that cross-cut the cumulates are shown to be in equilibrium with the noritic rocks. The high TiO₂ and P₂O₅ contents of these assumed liquids explains the early saturation of ilmenite and apatite before Fe–Mg silicates, thus the nelsonites represent cumulates rather than crystallized Fe–Ti–P-rich immiscible melts. The location of the most evolved mineral and whole rock compositions several tens of meters below the top of the intrusion, forming a sandwich horizon, is consistent with crystallization both from the base and top of the intrusion. The concentrations of V and Cr in ilmenite display a single fractionation path for the different cumulus assemblages and define the cotectic proportion of ilmenite to 21 wt.%. This corresponds to bulk cotectic cumulates with ca. 8 wt.% TiO₂, which is significantly lower than what is commonly observed in the explored portion of the Grader intrusion. The proposed mechanism of ilmenite-enrichment is the lateral removal of plagioclase due to its relative buoyancy in the dense ferrodiorite melt. This plagioclase has probably accumulated in other portions of the intrusion or has not been distinguished from the host anorthosite.     

Geochemical Mineral Exploration: Should We Use Enrichment Factors or Log-Ratios?

According to previous studies, the use of enrichment factors in environmental studies is inconsistent with its original concept and that such indiscriminate use of enrichment factors should be stopped. In this contribution, it is shown through spatial correlation analysis that using enrichment factors is no better than using log-ratios of geochemical data for mapping of deposit-related anomalies.     

Natural Resources Research Publications on Geochemical Anomaly and Mineral Potential Mapping,and Introduction to the Special Issue of Papers in These Fields

In its 26 years of existence, the journal of Natural Resources Research (NRR) has published and continues to publish papers on geochemical anomaly and mineral potential mapping. This is consistent with its aims and scope to publish quantitative studies of natural (mainly but not limited to mineral) resources exploration, evaluation and exploitation, including environmental and risk-related aspects. Over the years, NRR has contributed significantly more to the publication of developments in mineral potential mapping and notably less to the publication of developments in geochemical anomaly mapping. In more detail, NRR has contributed significantly more to the publication of research on development of robust quantitative methods for analysis and synthesis of spatial evidence of mineral potential but notably less to the publication of research on development of geologically focused models of mineral potential. The editorship of NRR recognizes the latter as a challenge to promote further research on development of numerically robust as well as geologically focused mineral potential models, and this special issue is a major initiative in response to that challenge. The recent inclusion of Natural Resources Research for coverage by the Clarivate Analytics (formerly the Institute for Scientific Information) in the Science Citation Index Expanded? and Journal Citation Reports^® (JCR) Science Edition will help make Natural Resources Research meet that challenge.     

Dispersive Fluxes Within and Over a Real Urban Canopy: A Large-Eddy Simulation Study

Boundary-Layer Meteorology - Large-eddy simulations (LES) are conducted to study the transport of momentum and passive scalar within and over a real urban canopy in the City of Boston, USA. This...     

Fluid-induced high-temperature metasomatism at Rundv?gshetta in the Lützow-Holm Complex,East Antarctica: Implications for the role of brine during granulite formation

We report new petrological, phase equilibria modeling, and fluid inclusion data for pelitic and mafic granulites from Rundv?gshetta in the highest-grade region of the Neoproterozoic Lützow-Holm Complex(LHC),East Antarctica, and provide unequivocal evidence for fluid-rock interaction and high-temperature metasomatism in the presence of brine fluid. The studied locality is composed dominantly of well-foliated pelitic granulite(K-feldspar+quartz+sillimanite+garnet+ilmenite) with foliation-parallel bands and/or layers of mafic granulite(plagioclase+orthopyroxene+garnet+ilmenite+quartz+biotite). The boundary between the two lithologies is defined by thin(about 1 -20 cm in thick) garnet-rich layers with a common mineral assemblage of garnet+plagioclase+quartz+ilmenite+biotite ? orthopyroxene. Systematic increase of grossular and decrease of pyrope contents in garnet as well as decreasing Mg/(Fe+Mg) ratio of biotite from the pelitic granulite to garnet-rich rock and mafic granulite suggest that the garnet-rich layer was formed by metasomatic interaction between the two granulite lithologies. Phase equilibria modeling in the system NCKFMASHTO demonstrates that the metasomatism took place at 850 -860℃, which is slightly lower than the peak metamorphism of this region, and the modal abundance of garnet is the highest along the metapeliteemetabasite boundary(up to 40%), which is consistent with the field and thin section observations. The occurrence of brine(7.0 -10.9 wt.% Na Cleqfor ice melting or 25.1 -25.5 wt.% NaC leqfor hydrohalite melting) fluid inclusions as a primary phase trapped within plagioclase in the garnet-rich layer and the occurrence of Cl-rich biotite(Cl = 0.22 -0.60 wt.%) in the metasomatic rock compared to that in pelitic(0.15 -0.24 wt.%) and mafic(0.06-0.13 wt.%) granulites suggest infiltration of brine fluid could have given rise to the high-temperature metasomatism. The fluid might have been derived from external sources possibly related to the formation of major suture zones formed during the Gondwana amalgamation.     

Empirical Estimation of Uniaxial Compressive Strength of Rock: Database of Simple,Multiple, and Artificial Intelligence-Based Regressions

Geotechnical and Geological Engineering - Empirical relationships for estimating Uniaxial Compressive Strength (UCS) of rock from other rock properties are numerous in literature. This is because...     

Calcium isotope ratios in animal and human bone

Calcium isotopes in tissues are thought to be influenced by an individual’s diet, reflecting parameters such as trophic level and dairy consumption, but this has not been carefully assessed. We report the calcium isotope ratios (δ^44/42Ca) of modern and archaeological animal and human bone (n = 216). Modern sheep raised at the same location show 0.14 ± 0.08‰ higher δ^44/42Ca in females than in males, which we attribute to lactation by the ewes. In the archaeological bone samples the calcium isotope ratios of the herbivorous fauna vary by location. At a single site, the archaeological fauna do not show a trophic level effect. Humans have lower δ^44/42Ca than the mean site fauna by 0.22 ± 0.22‰, and the humans have a greater δ^44/42Ca range than the animals. No effect of sex or age on the calcium isotope ratios was found, and intra-individual skeletal δ^44/42Ca variability is negligible. We rule out dairy consumption as the main cause of the lower human δ^44/42Ca, based on results from sites pre-dating animal domestication and dairy availability, and suggest instead that individual physiology and calcium intake may be important in determining bone calcium isotope ratios.     

Development of a User-Centred Web-Mapping Application for Ocean Modellers

Abstract

This paper reports on the User-Centred Design and development of a web-mapping application from the Ocean Mapping Group (OMG) at the University of New Brunswick (UNB), to deliver ocean mapping data to ocean modellers. First, a work domain analysis was conducted to determine the required application functionality and content, consisting of an ocean modeller informal interview, a competitive analysis, and an online survey. Taking insight from the work domain analysis, a requirements document was prepared to support the development of the first application prototype. This prototype was then evaluated by eight target users, using a cognitive walkthrough and an online survey. The results from this evaluation led to a series of revisions to the functionality, content, and interface of the web-mapping application, establishing the revised prototype. The results showed a useful tool, end-user satisfaction, and stated a wide range of recommendations to enhance functionality for the next steps of the development.     

Physical studies of Centaurs and Trans-Neptunian Objects with the Atacama Large Millimeter Array

Once completed, the Atacama Large Millimeter Array (ALMA) will be the most powerful (sub)millimeter interferometer in terms of sensitivity, spatial resolution and imaging. This paper presents the capabilities of ALMA applied to the observation of Centaurs and Trans-Neptunian Objects, and their possible output in terms of physical properties. Realistic simulations were performed to explore the performances of the different frequency bands and array configurations, and several projects are detailed along with their feasibility, their limitations and their possible targets. Determination of diameters and albedos via the radiometric method appears to be possible on ∼500 objects, while sampling of the thermal lightcurve to derive the bodies’ ellipticity could be performed at least 30 bodies that display a significant optical lightcurve. On a limited number of objects, the spatial resolution allows for direct measurement of the size or even surface mapping with a resolution down to 13 milliarcsec. Finally, ALMA could separate members of multiple systems with a separation power comparable to that of the HST. The overall performance of ALMA will make it an invaluable instrument to explore the outer Solar System, complementary to space-based telescopes and spacecrafts.