High-pressure Raman spectroscopic study of Mn2GeO4, Ca2GeO4, Ca2SiO4, and CaMgGeO4 olivines

We present a Raman spectroscopic study of the structural modifications of several olivines at high pressures and ambient temperature. At high pressures, the following modifications in the Raman spectra are observed: 1)?in Mn₂GeO₄, between 6.7 and 8.6?GPa the appearance of weak bands at 560 and 860?cm^?1; between 10.6 and 23?GPa, the progressive replacement of the olivine spectrum by the spectrum of a crystalline high pressure phase; upon decompression, the inverse sequence of transformations is observed with some hysteresis in the transformation pressures; this sequence may be interpreted as the progressive transformation of the olivine to a spinelloid where Ge tetrahedra are polymerized, and then to a partially inverse spinel; 2)?in Ca₂SiO₄, the olivine transforms to larnite between 1.9 and 2.1?GPa; larnite is observed up to the maximum pressure of 24?GPa and it can partially back-transform to olivine during decompression; 3)?in Ca₂GeO₄, the olivine transforms to a new structure between 6.8 and 8?GPa; the vibrational frequencies of the new phase suggest that the phase transition involves an increase of the Ca coordination number and that Ge tetrahedra are isolated; this high pressure phase is observed up to the maximum pressure of 11?GPa; during decompression, it transforms to a disordered phase below 5?GPa; 4)?in CaMgGeO₄, no significant modification of the olivine spectrum is observed up to 15?GPa; between 16 and 26?GPa, broadening of some peaks and the appearance of a weak broad feature at 700–900?cm^?1 suggests a progressive amorphization of the structure; near 27?GPa, amorphization is complete and an amorphous phase is quenched down to ambient pressure; this unique behaviour is interpreted as the result of the incompatibilities in the high pressure behaviour of the Ca and Mg sublattices in the olivine structure.     

2. Dating Methods and Corresponding Chronometers in Astrobiology

This chapter concerns the tools with which time or durations are measured in the various disciplines contributing to the chronology of the solar system until the emergence of life. These disciplines and their tools are successively: astronomy (use of the Herzsprung–Russell diagram), geochemistry (radioactive dating), chemistry (no clocks!), and biology (molecular clocks, based on rates of molecular evolution over phylogenetic trees). A final section puts these tools in perspective, showing the impossibility of using a unique clock to describe the evolution of the solar system and of life until today.     

Reflectance spectra and chemical structure of Titan's tholins: Application to the analysis of Cassini-Huygens observations

Titan's tholins are used as analogs of Titan's aerosols and N-rich organic solids present on many icy surfaces. However, it is not clear whether or not they are relevant analogs, and which kind of tholins should be used among a wide set available in literature. This paper presents reflectance spectral data of two tholins selected as end-members of a series of samples covering a very wide range of continuous chemical and optical properties. These samples were formed under experimental conditions fairly consistent with Titan's stratosphere. A general framework for using these laboratory data to the analysis of spectral observation of Titan's surface or other objects is suggested. Furthermore, the study reports the first in situ unambiguous identification of aromatics compounds and evidences variations in the sp² carbon structure, which controls the absorption properties in the visible/NIR. These results also point out it is very unlikely to derive quantitative chemical information (e.g., N content, sp²/sp³ ratio) from remote sensing reflectance data.     

7. Ancient Fossil Record and Early Evolution (ca. 3.8 to 0.5 Ga)

Once life appeared, it evolved and diversified. From primitive living entities, an evolutionary path of unknown duration, likely paralleled by the extinction of unsuccessful attempts, led to a last common ancestor that was endowed with the basic properties of all cells. From it, cellular organisms derived in a relative order, chronology and manner that are not yet completely settled. Early life evolution was accompanied by metabolic diversification, i.e. by the development of carbon and energy metabolic pathways that differed from the first, not yet clearly identified, metabolic strategies used. When did the different evolutionary transitions take place? The answer is difficult, since hot controversies have been raised in recent years concerning the reliability of the oldest life traces, regardless of their morphological, isotopic or organic nature, and there are also many competing hypotheses for the evolution of the eukaryotic cell. As a result, there is a need to delimit hypotheses from solid facts and to apply a critical analysis of contrasting data. Hopefully, methodological improvement and the increase of data, including fossil signatures and genomic information, will help reconstructing a better picture of life evolution in early times as well as to, perhaps, date some of the major evolutionary transitions. There are already some certitudes. Modern eukaryotes evolved after bacteria, since their mitochondria derived from ancient bacterial endosymbionts. Once prokaryotes and unicellular eukaryotes had colonized terrestrial ecosystems for millions of years, the first pluricellular animals appeared and radiated, thus inaugurating the Cambrian. The following sections constitute a collection of independent articles providing a general overview of these aspects.     

Assessing agricultural and hydrological drought vulnerability in a savanna ecological zone of Sub-Saharan Africa

Natural Hazards - Despite measures to mitigate drought, study on the extent of agricultural and hydrological drought vulnerability is still neglected in the savanna ecological zone of Nigeria. This...     

Identification of groundwater potential in hard rock aquifer systems using Remote Sensing,GIS and Magnetic Survey in Veppanthattai,Perambalur, Tamilnadu

Water is an essential natural resource without which life wouldn’t exist. The study aims to identify groundwater potential areas in Vepapanthattai taluk of Perambalur district, Tamil Nadu, India, using analytic hierarchy process (AHP) model. Remote sensing and magnetic parameters have been used to determine the evaluation indicators for groundwater occurrence under the ArcGIS environment. Groundwater occurrence is linked to structural porosity and permeability over the predominantly hard rock terrain, making magnetic data more relevant for locating groundwater potential zones in the research area. NE-SW and NW-SE trending magnetic breaks derived from reduction to pole map are found to be more significant for groundwater exploration. The lineaments rose diagram indicates the general trend of the fracture to be in the NE-SW direction. Assigned normalised criteria weights acquired using the AHP model was used to reclassify the thematic layers. As a result, the taluk’s low, moderate, and high potential zones cover 25.08%, 25.68% and 49.24% of the study area, respectively. The high potential zones exhibit characteristics favourable for groundwater infiltration and storage, with factors as gentle slope of <3°, high lineament densities, magnetic breaks, magnetic low zones as indicative of dykes and cracks, lithology as colluvial deposits and land surface with dense vegetation. The depth of the fracture zones was estimated using power spectrum and Euler Deconvolution method. The groundwater potential mapping results were validated using groundwater level data measured from the wells, which indicated that the groundwater potential zoning results are consistent with the data derived from the real world.     

The difficult combination of renting and building a house in urban Ghana: analysing the perception of low and middle income earners in Accra

This study examines the experiences of low and middle income earners in urban Ghana in combining renting and self-building a house with their meagre income. Using a case study of 3 building sites in Accra, this study employs semi-structured interview guide to gather qualitative data from fifty respondents. The conclusion of this study is that improving housing career amidst other competing responsibilities in the life course pathways imposes stress and huge financial burden on households in a manner that they are compelled to forgo or cut down on non-housing consumption such as clothing, up-keep of in-laws, marriage, higher educational qualification and cars among others. This study recommends a revisit of the discussion on the enforcement of the provisions of the Rent Act, 1963 and consideration of the practice of rent deposit and monthly rent. Affordable housing finance options should be a priority of African governments and their development partners.     

Geochemistry and geochronology of the ~620 Ma gold-associated Batouri granitoids,Cameroon

The Batouri gold mining area in southeastern Cameroon is part of the Adamawa–Yadé Domain of the Central African Fold Belt (Pan-African). It is underlain by a variety of granitic rocks, including alkali-feldspar granite, syeno-monzogranite, granodiorite, and tonalite. Geochemical data suggest that these rocks formed by differentiation of I-type tonalitic magma under oxidizing conditions in a continental volcanic arc setting. U–Pb dating of zircons from gold-associated monzogranite-granodiorite at Kambélé gave concordant ages of 619 ± 2 and 624 ± 2 Ma, while Ar–Ar dating of alkali-feldspar granite yielded a non-plateau maximum age of 640–620 Ma. These ages imply that the Batouri granitoids were emplaced during the collision of the West African Craton and the Congo Craton.

The geochemical characteristics of the Batouri granitoids as well as their oxidized state (magnetite series) are typical of gold-associated felsic rocks in subduction settings elsewhere. The similarities in age, composition, and geochemical affinities of these granitoids with those reported from other localities in the Adamawa–Yadé Domain reinforce the earlier assumption that the granitic rocks of this domain represent parts of a regional-scale batholith, with commonly small-scale, high-grade auriferous quartz veins in structurally favourable sites. The spatial and temporal association of gold mineralization and the Batouri granitoids may suggest potential for regional-scale, high-tonnage, granite-related gold ore.     

Computation of the space and time evolution of equilibrium-line altitudes on Andean glaciers (10°N–55°S)

A previous study of Fox [Fox, A.N. 1993. Snowline altitude and climate at present and during the Last Pleistocene Glacial Maximum in the Central Andes (5°–28°S). Ph.D. Thesis. Cornell University.] showed that for a fixed 0 °C isotherm altitude, the equilibrium-line altitude (ELA) of the Peruvian and Bolivian glaciers from 5 to 20°S can be expressed based on a log–normal expression of local mid-annual rainfall amount (P). In order to extrapolate the function to the whole Andes (10°N to 55°S) a local 0 °C isotherm altitude is introduced. Two applications of this generalised function are presented. One concerns the space evolution of mean inter-annual ELA for three decades (1961–1990) over the whole South American continent. A high-resolution data set (grid data: 10′ for latitude/longitude) of mean monthly air surface temperature and precipitation is used. Mean annual values over the 1961–1990 period were calculated. On each grid element, the mean annual 0 °C isotherm altitude is determined from an altitudinal temperature gradient and mean annual temperature (T) at ground level. The 0 °C isotherm altitude is then associated with the annual precipitation amount to compute the ELA. Using computed ELA and the digital terrain elevation model GTOPO30, we determine the extent of the glacierised area in Andean regions under modern climatic conditions. The other application concerns the ELA time evolution on Zongo Glacier (Bolivia), where inter-annual ELA variations are computed from 1995 to 1999. For both applications, the computed values of ELA are in good agreement with those derived from glacier mass balance measurements.