Role of the bedrock topography in the Quaternary filling of a giant estuarine basin: the Lower St. Lawrence Estuary,Eastern Canada

The geometry of estuarine and/or incised‐valley basins and their protected character compared with open sea basins are favourable for the preservation of sedimentary successions. The Lower St. Lawrence Estuary Basin (LSLEB, eastern Canada) is characterized by a thick (>400 m in certain areas) Quaternary succession. High‐ and very high‐resolution seismic reflection data, multibeam bathymetry coverage completed by core and chronostratigraphic data as well as a 3‐D seismic stratigraphic model are used to document the geometrical relationships between the bedrock and the Quaternary units of the LSLEB. The bedrock geometry of LSLEB is characterized by two large troughs that are interpreted as resulting mainly from repeated (?) periods of glacial overdeepening of a pre‐Quaternary drainage system. However, other mechanisms with complex feedback effects such as differential glacio‐isostatic uplift, erosion, sedimentary supply, and subsidence may have contributed to the formation of bedrock troughs. The two large bedrock troughs are mostly filled by ～200 m thick Wisconsinan (Marine Isotopic Stages 2–4) and possibly older sediments. Overlying units recorded the retreat of the Laurentian Ice Sheet during the Late Wisconsinan (Marine Isotopic Stage 2) and estuarine conditions during the Holocene. The strong correlation existing between the bedrock topography and the thickness of the Quaternary succession is indicative of the effectiveness of the LSLEB as a sediment trap.     

Modeling Dehalococcoides sp. Augmented Bioremediation in a Single Fracture System

A numerical reactive transport model was developed to simulate the bioremediation processes in a perchloroethene (PCE) contaminated single fracture system augmented with Dehalococcoides sp. (DHC). The model describes multispecies bioreactive transport processes that include bacterial growth and detachment dynamics, biodegradation of chlorinated species, competitive inhibition of various reactive species, and the loss of daughter products because of back‐partitioning effects. Two sets of experimental data, available in the study by Schaefer et al. (2010b) , were used to calibrate and test the model. The model was able to simulate both datasets. The simulation results indicated that the yield coefficient and the DHC maximum utilization rate coefficient were the two important process parameters. A detailed sensitivity study was completed to quantify the sensitivity of the model to variations in these two parameter values. The results show that an increase in yield coefficient increases bacterial growth and thus expedites the dechlorination process, whereas an increase in maximum utilization rate coefficient greatly increased dechlorination rates. The proposed model provides a mathematical framework for simulating remediation systems that employ DHC bioaugmentation for restoring chlorinated‐solvent contaminated groundwater aquifers.     

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

Regolith breccia Northwest Africa 7533: Mineralogy and petrology with implications for early Mars

Northwest Africa 7533, a polymict Martian breccia, consists of fine‐grained clast‐laden melt particles and microcrystalline matrix. While both melt and matrix contain medium‐grained noritic‐monzonitic material and crystal clasts, the matrix also contains lithic clasts with zoned pigeonite and augite plus two feldspars, microbasaltic clasts, vitrophyric and microcrystalline spherules, and shards. The clast‐laden melt rocks contain clump‐like aggregates of orthopyroxene surrounded by aureoles of plagioclase. Some shards of vesicular melt rocks resemble the pyroxene‐plagioclase clump‐aureole structures. Submicron size matrix grains show some triple junctions, but most are irregular with high intergranular porosity. The noritic‐monzonitic rocks contain exsolved pyroxenes and perthitic intergrowths, and cooled more slowly than rocks with zoned‐pyroxene or fine grain size. Noritic material contains orthopyroxene or inverted pigeonite, augite, calcic to intermediate plagioclase, and chromite to Cr‐bearing magnetite; monzonitic clasts contain augite, sodic plagioclase, K feldspar, Ti‐bearing magnetite, ilmenite, chlorapatite, and zircon. These feldspathic rocks show similarities to some rocks at Gale Crater like Black Trout, Mara, and Jake M. The most magnesian orthopyroxene clasts are close to ALH 84001 orthopyroxene in composition. All these materials are enriched in siderophile elements, indicating impact melting and incorporation of a projectile component, except for Ni‐poor pyroxene clasts which are from pristine rocks. Clast‐laden melt rocks, spherules, shards, and siderophile element contents indicate formation of NWA 7533 as a regolith breccia. The zircons, mainly derived from monzonitic (melt) rocks, crystallized at 4.43 ± 0.03 Ga (Humayun et al. 2013 ) and a ¹⁴⁷Sm‐¹⁴³Nd isochron for NWA 7034 yielding 4.42 ± 0.07 Ga (Nyquist et al. 2016 ) defines the crystallization age of all its igneous portions. The zircon from the monzonitic rocks has a higher Δ¹⁷O than other Martian meteorites explained in part by assimilation of regolith materials enriched during surface alteration (Nemchin et al. 2014 ). This record of protolith interaction with atmosphere‐hydrosphere during regolith formation before melting demonstrates a thin atmosphere, a wet early surface environment on Mars, and an evolved crust likely to have contaminated younger extrusive rocks. The latest events recorded when the breccia was on Mars are resetting of apatite, much feldspar and some zircons at 1.35–1.4 Ga (Bellucci et al. 2015 ), and formation of Ni‐bearing pyrite veins during or shortly after this disturbance (Lorand et al. 2015 ).     

Fault‐controlled fluid flow inferred from hydrothermal vents imaged in 3D seismic reflection data,offshore NW Australia

Fluid migration pathways in the subsurface are heavily influenced by pre‐existing faults. Although studies of active fluid‐escape structures can provide insights into the relationships between faults and fluid flow, they cannot fully constrain the geometry of and controls on the contemporaneous subsurface fluid flow pathways. We use 3D seismic reflection data from offshore NW Australia to map 121 ancient hydrothermal vents, likely related to magmatic activity, and a normal fault array considered to form fluid pathways. The buried vents consist of craters up to 264 m deep, which host a mound of disaggregated sedimentary material up to 518 m thick. There is a correlation between vent alignment and underlying fault traces. Seismic‐stratigraphic observations and fault kinematic analyses reveal that the vents were emplaced on an intra‐Tithonian seabed in response to the explosive release of fluids hosted within the fault array. We speculate that during the Late Jurassic the convex‐upwards morphology of the upper tip‐lines of individual faults acted to channelize ascending fluids and control where fluid expulsion and vent formation occurred. This contribution highlights the usefulness of 3D seismic reflection data to constraining normal fault‐controlled subsurface fluid flow.     

Evidence of high‐energy events in shelly layers interbedded in coastal Holocene sands in Cadiz Bay (south‐west Spain)

In some present‐day coastal areas, recent inactive deposits now outside the reach of sea agents can be observed. These deposits, although formed under different climatic and sea level conditions, often show similar facies to current littoral deposits. They are frequently interpreted as old dunes and beach ridges, or as abandoned spit bars, representative of previous dynamic stages. Nevertheless, in coastal areas which have been subjected to highly‐energetic events similar deposits can also be found. When a dynamic event acts on several adjacent environments, the transported and re‐deposited sediments can create homogeneous deposits with similar facies, that are easily confused. In this work, shelly layers interbedded in relict littoral sands located in the La Algaida pinewood, on the edge of the Rio San Pedro tidal channel, in Cadiz Bay (south‐west Spain) have been studied. The main constituents of the shelly beds are Glycimeris valves, organisms which are no longer found as live specimens in the present‐day sea bed of Cadiz Bay. From their appearance, the origin of these shelly beds could be related to sea washovers generated by tidal or storm action, but their disposition and height over the present sea level implies that even higher energy agents were involved in their formation, such as major storms or tsunami waves. The most significant process was the mobilization of the sub‐tidal and littoral sediments and their dispersal and re‐sedimentation, both lengthways and widthways of the coast, giving way to homogeneous sandy deposits in all littoral environments some of which are now outside the reach of current sea agents. The exception is the present‐day shore of the San Pedro tidal channel, where the sediments are being reworked by tidal and small wave action. If the proximity of the study zone to the limit of the African and Iberian plates is considered, where several historical earthquakes and tsunamis have taken place, it is possible to think that these deposits could be a consequence of sporadic and successive washovers, generated by tsunamis occurring between ad 800 and ad 1200. Sedimentological and historical data indicate an increase in seismic and tsunami activity during this period of time, while the shelly layers would be the consequence of the most intense pulses occurring during these high‐energy events. Copyright © 2009 John Wiley & Sons, Ltd.     

Numerical models and ductile ultimate deformation response of post‐tensioned self‐centering moment connections

New steel moment‐resisting connections that incorporate post‐tensioning elements to provide a self‐centering capacity and devices to dissipate seismic input energy have recently been proposed and experimentally validated. Experimental studies have confirmed that these connections are capable of undergoing large lateral deformations with negligible residual drifts. To facilitate their implementation, accurate modeling of the behavior of systems incorporating post‐tensioned connections must be readily available to designers and researchers. A number of simplified models have been suggested in the literature by researchers trying to capture experimental results at the beam–column connections and thereby to predict the global response of structures incorporating such connections. To provide a clear set of guidelines for the modeling of post‐tensioned steel frames, for practicing engineers as well as researchers, in this paper three types of numerical models of increasing complexity are presented: (i) a sectional analysis procedure, (ii) a lumped plasticity spring frame leveled approach and (iii) a non‐linear solid finite element analysis to predict the response at ultimate deformation levels. The analytical results obtained from the numerical models predict well the structural behavior of these connections when compared with available experimental data. Even at the ultimate deformation level, analytical results are in good agreement with test results. Furthermore, detailing requirements are proposed to assure that flexural hinges form in the beams in order to improve the cyclic response of steel self‐centering connections when drifts exceeding the design drifts are imposed to the system. Experimental and analytical studies demonstrate that steel post‐tensioned self‐centering connections incorporating the proposed detailing in the beams develop an increased deformation capacity and thereby exhibit a ductile response while avoiding a sudden loss of their strength and stiffness. Copyright © 2008 John Wiley & Sons, Ltd.     

Geology and tectonics of the basin of Mexico and their relationship with the damage caused by the earthquakes of September 1985

Summary The earthquakes of 19 September 1985 (18.2° N, 102.7° W and a magnitude of 8.1 Richter scale) and of 20 (17.6° N, 101.8° W and a magnitude of 7.5 Richter scale) September 1985, caused the total or partial destruction of more than 2000 structures in Mexico City. The most affected areas are located along the fringes of and bordering old roadways, earthworks (dikes), aquaducts and pre-hispanic population centres. Ancient construction artificially modified the sedimentation in the basin of the Mexico Valley Lakes making the sub-soil of Mexico City more rigid near to the surface, and producing deviations of the surface seismic waves (Rayleigh waves and Love waves). Also, when earthquakes occur on the Pacific coast, seismic waves travel quickly through plutonic, metamorphics and continental and marine rocks of different ages, having high seismic velocities. When the seismic waves enter the poorly consolidated lake sediments having low seismic velocities in the Mexico City Basin, they produce an energy buildup that causes the phenomenon called magnification.There exists a direct relation between the amplification mentioned above and the presence of rigid bodies that are buried in the sub-soil. The length of these bodies is of the order of tens of kilometres horizontally with thicknesses less than 50 metres. These Rigid Barriers produce reflections and refractions of the surface waves along their borders with destructive consequences for the buildings. A correlation between the buildings and the houses damaged and destroyed and the location of the prehispanic construction on the sub-soil has been made which shows that the most damage happened in the borders of old roadways (i.e. Tlalpan road), perimeter walls (i.e. San Lazaro), aqueducts (i.e. Chapultepec Avenue), pyramids (i.e. Templo Mayor) and population centres (i.e. Tlaltelolco).