Shoshonitic lamprophyre dykes and their relation to mesothermal Au---Sb veins at Hillgrove, New South Wales, Australia

The Hillgrove mineral field, in the southern part of the New England Orogen of northeastern New South Wales, Australia, contains numerous mesothermal Au---Sb vein systems. Calc-alkaline (shoshonitic) lamprophyre (CAL) dykes are also associated with mineralisation with dilational lode structures acting as conduits for dyke intrusion, which has occurred before and after major quartz-stibnite veining. Dykes include minette and vogesite compositions and were emplaced in the late Permian (247–255 Ma), at the same time as regionally extensive I-type magmatism in the New England Orogen. Least-altered dykes are enriched in Mg, K, Ba, Rb, Sr, Zr, Th, Cr and Ni relative to I-type intrusives although chemical affinities are evident between lamprophyres and the more mafic members of the high-K Moonbi Plutonic Suite.

Hillgrove lamprophyres are commonly enriched in Sb, As, Hg, Au, W and Bi with respect to average CAL compositions. Evidence indicates this is most likely due to contamination of magma during intrusion through mineralised structures, rather than a primary magmatic feature. Partially resorbed xenocrystic stibnite occurs in dykes which have intruded lode structures, probably facilitated by the low melting point of stibnite (550°C) and its incorporation into the magma. Carbon and oxygen isotopic data from carbonates in least-altered, post-lode lamprophyres are indistinguishable from carbonate in altered dykes and veins, implying that hydrothermal interaction continued after dyke intrusion. Although it is unlikely that lamprophyre dykes have been a direct source for mineralisation at Hillgrove, the close temporal and spatial relation of dykes, mesothermal Au---Sb veins and I-type intrusions are interpreted to be manifestations of the post-collisional setting and influx of mantle-derived heat and partial melts into the New England Orogen during the late Permian.     

Origin of Archean migmatites from the Gwenoro Dam area,Zimbabwe-Rhodesia

Archean migmatites in the vicinity of Gwenoro Dam in Zimbabwe-Rhodesia are composed chiefly of trondhjemite gneiss (TR), mafic tonalite (MT), amphibolite (AM), leuco-trondhjemite veins (LTR), and pegmatites. The gneiss is intruded in nearby areas with small tonalite plutons (TN). Geochemical model studies together with field relationships are consistent with the following model for migmatite production: AM is produced by partial melting of a partly depleted ultramafic parent in which neither garnet nor amphibole remain in the residue; TR and TN are produced by partial melting of undepleted to variably depleted amphibolite in which garnet does not remain in the residue; MT is produced by mixing of plagioclase-rich TR with AM; and LTR represents the solid residue after fractional crystallization of TR.     

Mineral/melt partitioning of trace elements during hydrous peridotite partial melting

This experimental study examines the mineral/melt partitioning of incompatible trace elements among high-Ca clinopyroxene, garnet, and hydrous silicate melt at upper mantle pressure and temperature conditions. Experiments were performed at pressures of 1.2 and 1.6 GPa and temperatures of 1,185 to 1,370 °C. Experimentally produced silicate melts contain up to 6.3 wt% dissolved H ₂O, and are saturated with an upper mantle peridotite mineral assemblage of olivine+orthopyroxene+clinopyroxene+spinel or garnet. Clinopyroxene/melt and garnet/melt partition coefficients were measured for Li, B, K, Sr, Y, Zr, Nb, and select rare earth elements by secondary ion mass spectrometry. A comparison of our experimental results for trivalent cations (REEs and Y) with the results from calculations carried out using the Wood-Blundy partitioning model indicates that H ₂O dissolved in the silicate melt has a discernible effect on trace element partitioning. Experiments carried out at 1.2 GPa, 1,315 °C and 1.6 GPa, 1,370 °C produced clinopyroxene containing 15.0 and 13.9 wt% CaO, respectively, coexisting with silicate melts containing ~1–2 wt% H ₂O. Partition coefficients measured in these experiments are consistent with the Wood-Blundy model. However, partition coefficients determined in an experiment carried out at 1.2 GPa and 1,185 °C, which produced clinopyroxene containing 19.3 wt% CaO coexisting with a high-H ₂O (6.26±0.10 wt%) silicate melt, are significantly smaller than predicted by the Wood-Blundy model. Accounting for the depolymerized structure of the H ₂O-rich melt eliminates the mismatch between experimental result and model prediction. Therefore, the increased Ca ²⁺ content of clinopyroxene at low-temperature, hydrous conditions does not enhance compatibility to the extent indicated by results from anhydrous experiments, and models used to predict mineral/melt partition coefficients during hydrous peridotite partial melting in the sub-arc mantle must take into account the effects of H ₂O on the structure of silicate melts.     

The relative stabilities of the reverse and normal polarity states of the earth's magnetic field

Recent analyses of the geomagnetic reversal sequence have led to different conclusions regarding the important question of whether there is a discernible difference between the properties of the two polarity states. The main differences between the two most recent studies are the statistical analyses and the possibility of an additional 57 reversal events in the Cenozoic. These additional events occur predominantly during reverse polarity time, but it is unlikely that all of them represent true reversal events. Nevertheless the question of the relative stabilities of the polarity states is examined in detail, both for the case when all 57 “events” are included in the reversal chronology and when they are all excluded. It is found that there is not a discernible difference between the stabilities of the two polarity states in either case. Inclusion of these short events does, however, change the structure of the non-stationarity in reversal rate, but still allows a smooth non-stationarity. Only 7 of the 57 short events are pre-38 Ma, but the evidence suggests that this is a real geomagnetic phenomenon rather than degradation of the magnetic recording or a bias in observation. This could be tested by detailed magnetostratigraphic and oceanic magnetic surveys of the Paleogene and Late Cretaceous. Overall it would appear that the present geomagnetic polarity timescale for 0–160 Ma is probably a very good representation of the actual history, and that different timescales and additional events now represent only changes in detail.     

SAMPLING METHODS AND APPROACHES USING RADIONUCLIDE TRACERS IN THE STUDY OF SEDIMENT RESUSPENSION AND CROSS MARGIN TRANSPORT IN NEARSHORE OF THE LAURENTIAN GREAT LAKES

1 INTRODUCTION Sediment resuspension, particularly in response to episodic storm events, is a common characteristic of coastal and nearshore environments. The resulting 揵enthic storms?may play a significant role in the dynamics of benthic systems, including structuring the physical characteristics of the bottom, providing a mechanism for the recycling of biogeochemically important materials to the water column, and driving horizontal and cross margin transport of suspended particulates …     

Effect of mining and related activities on the sediment trace element geochemistry of lake coeur D'Alene,idaho, USA. Part I: Surface sediments

During the summer of 1989 surface sediment samples were collected in Lake Coeur d'Alene, the Coeur d'Alene River and the St Joe River, Idaho, at a density of approximately one sample per square kilometre. Additional samples were collected from the banks of the South Fork of the Coeur d'Alene and the Coeur d'Alene Rivers in 1991. All the samples were collected to determine trace element concentrations, partitioning and distribution patterns, and to relate them to mining, mining related and discharge operations that have occurred in the Coeur d'Alene district since the 1880s, some of which are ongoing. Most of the surface sediments in Lake Coeur d'Alene north of Conkling Point and Carey Bay are substantially enriched in Ag, As, Cu, Cd, Hg, Pb, Sb and Zn relative to unaffected sediments in the southern portion of the lake near the St Joe River. All the trace element enriched sediments are extremely fine grained (mean grain sizes « 63 μm). Most of the enriched trace elements, based on both the chemical analyses of separated heavy and light mineral fractions and a two step sequential extraction procedure, are associated with an operationally defined Fe oxide phase; much smaller percentages are associated either with operationally defined organics/sulphides or refractory phases. The presence, concentration and distribution of the Fe oxides and heavy minerals indicates that a substantial portion of the enriched trace elements are probably coming from the Coeur d'Alene River, which is serving as a point source. Within the lake, this relatively simple point source pattern is complicated by a combination of (1) the formation of trace element rich authigenic Fe oxides that appear to have reprecipitated from material solubilized from anoxic bed sediments and (2) physical remobilization by currents and wind driven waves. The processes that have caused the trace element enrichment in the surface sediments of Lake Coeur d'Alene are likely to continue for the foreseeable future.