Evaluation of microwave-assisted acid extraction procedures for the determination of metal content and potential bioavailability in sediments

Acid extractions represent a simple and effective tool for the assessment of metal contamination, origin and bioavailability in the aquatic environment. Optimized microwave-assisted procedures utilizing two extractions (8 M HNO₃ and 1 M HCl) were developed. Particular attention was given to the evaluation of efficiency and selectivity of the developed procedures. This involved an examination of the sediment and the extraction residues by Mössbauer spectroscopy and X-ray diffractometry. These instrumental approaches were used to identify the geochemical phases associated with acid decomposition. Microwave digestion with 8 M HNO₃ produced an efficient solubilization of the most important metal-bearing phases and left unaffected only the minerals (quartz, feldspars, muscovite) with a negligible metal content, thus providing a good estimate of the total metal concentrations. The 1 M HCl extraction, despite the limitation due to the incomplete solubilization of pyrite and to the partial dissolution of sheet silicates, represents a simple and effective technique for providing an estimate of the bioavailable metal fraction in sediments. The combined use of the two microwave-assisted acid extractions can provide a rapid and simple approach for the risk assessment of metal-polluted sediments.     

2D numerical simulations of earthquake ground motion: examples from the Marche Region,Italy

A detailed numerical simulation of the ground motion and a site response analysis for two towns in the Marche Region (Treia and Cagli) is carried out on the basis of structural models deduced from available geological and geophysical data. In both cases, the reference event is an M = 5.7 earthquake associated with a normal fault located beneath each town. The ground motion is computed using the 2D spectral element method (SPEM 2D). The method solves the propagation of the seismic field through complex geological structures and enables an estimate of the effects of deep crustal structure, superficial geology, and topography on ground motion. Numerical simulations of the seismic field are performed along 2D vertical planes containing the seismic source. Strong ground motion has not been yet recorded in the two towns; therefore, the numerical simulation of ground motion represents a way to overcome the lack of instrumental data. The simulations carried out for Treia show that ground motion is influenced by both source mechanism and effects due to propagation through the geological structure, while ground motion in Cagli features strong local effects, caused by the presence of alluvial deposits under a large area of the town.     

Green‐Ampt Curve‐Number mixed procedure as an empirical tool for rainfall–runoff modelling in small and ungauged basins

The Soil Conservation Service Curve Number (SCS‐CN) method is a popular rainfall–runoff model that is widely used to estimate direct runoff from small and ungauged basins. The SCS‐CN is a simple and valuable approach to quantify the total streamflow volume generated by storm rainfall, but its use is not appropriate for estimating the sub‐daily incremental rainfall excess. To overcome this drawback, we propose to include the Green‐Ampt (GA) infiltration model into a mixed procedure, which is referred to as Curve Number for Green‐Ampt (CN4GA), aiming to distribute in time the information provided by the SCS‐CN method. For a given storm, the computed SCS‐CN total net rainfall amount is employed to calibrate the soil hydraulic conductivity parameter of the GA model. The proposed procedure is evaluated by analysing 100 rainfall–runoff events that were observed in four small catchments of varying size. CN4GA appears to provide encouraging results for predicting the net rainfall peak and duration values and has shown, at least for the test cases considered in this study, better agreement with the observed hydrographs than the classic SCS‐CN method. Copyright © 2012 John Wiley & Sons, Ltd.     

Open issues on the synthesis of evolved stellar populations at ultraviolet wavelengths

This paper deals with five-dimensional black hole solutions in (a) Einstein-Maxwell-Gauss-Bonnet theory with a cosmological constant and (b) Einstein-Yang-Mills-Gauss-Bonnet theory for spherically symmetric space time. In both the cases the possibility of phase transition is examined and it is analyzed whether the phase transition is a Hawking-Page type phase transition or not.     

Statistical properties of the <Emphasis Type="Italic">GALEX</Emphasis> spectroscopic stellar sample

The GALEX General Data Release 4/5 includes 174 spectroscopic tiles, obtained from slitless grism observations, for a total of more than 60 000 ultraviolet spectra. We have determined statistical properties of the sample of GALEX stars. We have defined a suitable system of spectroscopic indices, which measure the main mid-UV features at the GALEX low spectral resolution and we have employed it to determine the atmospheric parameters of stars in the range 4500≲T _eff≲9000 K. Our preliminary results indicate that the majority of the sample is formed by main sequence F- and G-type stars, with metallicity [M/H]≳−1 dex.     

Multiple spacecraft rendezvous maneuvers by differential drag and low thrust engines

A novel two-phase hybrid controller is proposed to optimize propellant consumption during multiple spacecraft rendezvous maneuvers in Low Earth Orbit. This controller exploits generated differentials in aerodynamic drag on each involved chaser spacecraft to effect a propellant-free trajectory near to the target spacecraft during the first phase of the maneuver, and then uses a fuel optimal control strategy via continuous low-thrust engines to effect a precision dock during the second phase. In particular, by varying the imparted aerodynamic drag force on each of the chaser spacecraft, relative differential accelerations are generated between each chaser and the target spacecraft along two of the three translational degrees of freedom. In order to generate this required differential, each chaser spacecraft is assumed to include a system of rotating flat panels. Additionally, each chaser spacecraft is assumed to have continuous low-thrust capability along the three translational degrees of freedom and full-axis attitude control. Sample simulations are presented to support the validity and robustness of the proposed hybrid controller to variations in the atmospheric density along with different spacecraft masses and ballistic coefficients. Furthermore, the proposed hybrid controller is validated against a complete nonlinear orbital model to include relative navigation errors typical of carrier-phase differential GPS (CDGPS). Limitations of the proposed controller appear relative to the target spacecraft’s orbit eccentricity and a general characterization of the atmospheric density. Bounds on these variables are included to provide a framework within which the proposed hybrid controller can effect an extremely low propellant rendezvous of multiple chaser spacecraft to a desired target spacecraft.     

Fractal and Multifractal Properties of Active Regions as Flare Precursors: A Case Study Based on SOHO/MDI and SDO/HMI Observations

Several studies indicate that fractal and multifractal parameters inferred from solar photospheric magnetic field measurements may help assessing the eruptive potential of Active Regions (ARs) and also predicting their flare activity. We further investigate this topic, by exploring the sensitivity of some parameters already used in the literature on data and methods employed for their estimation. In particular, we measured the generalized fractal dimensions D ₀ and D ₈, and the multifractal parameters C _div and D _div, on the time series of photospheric magnetograms of the flaring AR NOAA 11158 obtained with the SOHO/MDI and SDO/HMI. The observations by the latter instrument are characterized by a higher spatial and temporal resolution, as well as higher flux sensitivity, than the ones obtained from SOHO/MDI, which were widely employed in earlier studies. We found that the average and peak values of complexity parameters measured on the two data sets agree within measurement uncertainties. The temporal evolution of the parameters measured on the two data sets show rather similar trends, but the ones derived from the SOHO/MDI observations show larger and spurious variations over time than those deduced from analysis of the corresponding SDO/HMI data. We also found a larger sensitivity of these measurements to characteristics of the data analyzed than reported by earlier studies. In particular, analysis of the higher resolution and higher cadence SDO/HMI data allows us also to detect slight variations of the complexity indicators that cannot be derived from the analysis of the SOHO/MDI data. These variations occur right after the major events in the analyzed AR. They may be the signature of photospheric effects of coronal magnetic field re-arrangement.     

Interacting Winds in Eclipsing Symbiotic Systems – The Case Study of EG Andromedae

We report the mathematical representation of the so called eccentric eclipse model, whose numerical solutions can be used to obtain the physical parameters of a quiescent eclipsing symbiotic system. Indeed the nebular region produced by the collision of the stellar winds should be shifted to the orbital axis because of the orbital motion of the system. This mechanism is not negligible, and it led us to modify the classical concept of an eclipse. The orbital elements obtained from spectroscopy and photometry of the symbiotic EG Andromedae were used to test the eccentric eclipse model. Consistent values for the unknown orbital elements of this symbiotic were obtained. The physical parameters are in agreement with those obtained by means of other simulations for this system.