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41.
Ellen Wohl 《地球表面变化过程与地形》2011,36(10):1378-1390
Historical range of variability (HRV) describes the range of temporal and spatial variations in river variables such as flow regime or channel planform prior to intensive human alteration of the ecosystem. In mountainous river networks, HRV is most usefully applied to spatially differentiated geomorphic process domains with distinctive form and process. Using the Colorado Front Range as an example, three examples of how knowledge of HRV can assist river management and restoration are discussed. The examples involve instream wood load and channel morphology, beaver colonies and valley‐bottom form and process, and flow thresholds in regulated rivers. The question of what a river should look like – that is, what range of process and form the river included prior to intensive human alteration – can be addressed by (i) placing the river within a process domain, (ii) establishing correlations between form parameters that can be remotely sensed and reach‐scale process and form, so that the spatial extent, connectivity, and rarity of process domains within a river network or a region can be quickly assessed, (iii) inferring characteristics of the river prior to intensive alteration by documenting characteristics of the least altered reference rivers and by using proxy indicators of pre‐alteration conditions, and (iv) establishing process thresholds that must be exceeded to maintain form (e.g. flow thresholds to mobilize bed sediment). Once this context has been established, resource managers can better evaluate the options for restoring altered riverine form and function. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
42.
Darci Rush Andrea Jaeschke Ellen C. Hopmans Stefan Schouten 《Geochimica et cosmochimica acta》2011,75(6):1662-1671
Anammox, the microbial anaerobic oxidation of ammonium by nitrite to produce dinitrogen gas, has been recognized as a key process in both the marine and freshwater nitrogen cycles, and found to be a major sink for fixed inorganic nitrogen in the oceans. Ladderane lipids are unique anammox bacterial membrane lipids that have been used as biomarkers for anammox bacteria in recent and past environmental settings. However, the fate of ladderane lipids during diagenesis is as of yet unknown. In this study, we performed oxic degradation experiments (at 20-100 °C) with anammox bacterial biomass to simulate early diagenetic processes occurring in the water column and at the sediment-water interface. Abundances of C18 and C20 ladderane lipids decreased with increasing temperatures, testifying to their labile nature. The most abundant products formed were ladderane lipids with a shorter alkyl side chain (C14 and C16 ladderane fatty acids), which was unambiguously established using two-dimensional NMR techniques on an isolated C14-[3]-ladderane fatty acid. The most pronounced production of these short-chain lipids was at 40 °C, suggesting that degradation of ladderane lipids was microbially mediated, likely through a β-oxidation pathway. An HPLC-MS/MS method was developed for the detection of these ladderane alteration products in environmental samples and positively tested on various sediments. This showed that the ladderanes formed during degradation experiments also naturally occur in the marine environment. Thus, short-chain ladderane lipids may complement the original longer-chain ladderane lipids as suitable biomarkers for the detection of anammox processes in past depositional environments. 相似文献
43.
Ellen M. Moon 《Geochimica et cosmochimica acta》2011,75(21):6705-6719
Bacteria are very efficient sorbents of trace metals, and their abundance in a wide variety of natural aqueous systems means biosorption plays an important role in the biogeochemical cycling of many elements. We measured the adsorption of Cu(II) to Bacillus subtilis as a function of pH and surface loading. Adsorption edge and XAS experiments were performed at high bacteria-to-metal ratio, analogous to Cu uptake in natural geologic and aqueous environments. We report significant Cu adsorption to B. subtilis across the entire pH range studied (pH ∼2-7), with adsorption increasing with pH to a maximum at pH ∼6. We determine directly for the first time that Cu adsorbs to B. subtilis as a (CuO5Hn)n−8 monodentate, inner-sphere surface complex involving carboxyl surface functional groups. This Cu-carboxyl complex is able to account for the observed Cu adsorption across the entire pH range studied. Having determined the molecular adsorption mechanism of Cu to B. subtilis, we have developed a new thermodynamic surface complexation model for Cu adsorption that is informed by and consistent with EXAFS results. We model the surface electrostatics using the 1pK basic Stern approximation. We fit our adsorption data to the formation of a monodentate, inner-sphere RCOOCu+ surface complex. In agreement with previous studies, this work indicates that in order to accurately predict the fate and mobility of Cu in complex biogeochemical systems, we must incorporate the formation of Cu-bacteria surface complexes in reactive transport models. To this end, this work recommends log K RCOOCu+ = 7.13 for geologic and aqueous systems with generally high B. subtilis-to-metal ratio. 相似文献
44.
Identification and distribution of intact polar branched tetraether lipids in peat and soil 总被引:1,自引:0,他引:1
Francien Peterse Ellen C. Hopmans Stefan Schouten Anchélique Mets W. Irene C. Rijpstra Jaap S. Sinninghe Damsté 《Organic Geochemistry》2011,42(9):1007-1015
Branched glycerol dialkyl glycerol tetraether lipids (GDGTs) are membrane lipids of soil bacteria that occur ubiquitously in soil, but their occurrence as intact polar lipids (IPLs) has not been well studied. Here, we report the identification and distribution of IPL-branched GDGTs throughout a depth profile of a Swedish peat bog. In addition to two reported glycosidic IPL branched GDGTs, we identified IPL branched GDGTs with a hexose-glycuronic acid, phospho-hexose, or hexose-phosphoglycerol head group, based on mass spectrometry. A selected reaction monitoring (SRM) assay was developed to monitor changes in head group distribution with depth. The abundance of the IPL branched GDGTs increased below the water table, suggesting that they were primarily produced in this part of the peat. This was supported by the concentrations of core lipid and IPL-derived branched GDGTs, which also substantially increased below the water table. However, individual IPL trends differed, which may be due to changes in the microbial community composition with depth or to different degradation rates for the different IPL branched GDGTs. The SRM method was also applied to two different soil types, which showed that similar IPL branched GDGTs as those in peat were present, albeit with different distributions. 相似文献
45.
Female and male individuals of the same species often differ with respect to their susceptibility to toxicant stress. In the present study, sea urchins (Psammechinus miliaris) of both sexes were exposed to high (150 μg L?1) and environmentally relevant (5 μg L?1) concentrations of phenanthrene over 10 days. While food intake was significantly decreased following exposure to 150 μg L?1 phenanthrene, histological indices (lipofuscin accumulation, fibrosis, oocyte atresia), energetic status (energy charge, sum adenylates, AMP/ATP ratio) as well as ascorbate levels in the gonads showed either little or no effect upon phenanthrene exposure. However, most parameters (vitamin C, energy charge, sum adenylates, AMP/ATP ratio, ATP and ADP concentrations, lipofuscin content, fibrosis) significantly differed between male and female animals. This study illustrates the difficulties to identify toxic injury in reproductive tissue as it may be superimposed by gametogenesis and spawning of gametes. 相似文献
46.
The incorporation of fullerenes and carbon nanotubes into electronic, optical and consumer products will inevitably lead to the presence of these anthropogenic compounds in the environment. To date, there have been few studies isolating these materials from environmental matrices. Here we report a method commonly used to quantify black carbon (BC) in soils, the benzene polycarboxylic acid (BPCA) method, for measurement of two types of single walled carbon nanotubes (SWCNTs), two types of fullerenes and two forms of soot. The distribution of BC products (BPCAs) from the high pressure and high temperature oxidation illustrates the condensed nature of these compounds because they form predominantly fully substituted mellitic acid (B6CA). The conversion of carbon nanoparticles to BPCAs was highest for fullerenes (average of 23.2 ± 4.0% C recovered for both C60 and C70) and lowest for non-functionalized SWCNTs (0.5 ± 0.1% C). The recovery of SWCNTs was 10 times higher when processed through a cation-exchange column, indicating the presence of metals in SWCNTs compromises the oxidation chemistry. While mixtures of SWCNTs, soot and sediment revealed small losses of black carbon during sample processing, the method is suitable for quantifying total BC. The BPCA distribution of mixtures did not agree with theoretical mixtures using model polyaromatic hydrocarbons, suggesting the presence of a matrix effect. Future work is required to quantify different types of black carbon within the same sample. 相似文献
47.
Incorporation of 14C-depleted (old) dissolved organic carbon (DOC) on/into particulate organic carbon (POC) has been suggested as a possible mechanism to explain the low Δ14C-POC values observed in the deep ocean [Druffel, E.R.M., Williams, P.M., 1990. Identification of a deep marine source of particulate organic carbon using bomb 14C. Nature, 347, 172–174.]. A shipboard incubation experiment was performed in the Sargasso Sea to test this hypothesis. Finely ground dried plankton was incubated in seawater samples from the deep Sargasso Sea, both with and without a biological poison (HgCl2). Changes in parameters such as biochemical composition and carbon isotopic signatures of bulk POC and its organic compound classes were examined to study the roles of sorptive processes and biotic activity on POC character. Following a 13-day incubation, the relative abundance of the acid-insoluble organic fraction increased. Abundances of extractable lipids and total hydrolyzable amino acids decreased for both treatments, but by a greater extent in the non-poisoned treatment. The Δ14C values of POC recovered from the non-poisoned treatment were significantly lower than the value of the unaltered plankton material used for the incubation, indicating incorporation of 14C-depleted carbon, most likely DOC. The old carbon was present only in the lipid and acid-insoluble fractions. These results are consistent with previous findings of old carbon dominating the same organic fractions of sinking POC from the deep Northeast Pacific [Hwang, J., Druffel, E.R.M., 2003. Lipid-like material as the source of the uncharacterized organic carbon in the ocean? Science, 299, 881–884.]. However, the Δ14C values of POC recovered from the poisoned treatment did not change as much as those from the non-poisoned treatment suggesting that biological processes were involved in the incorporation of DOC on/into POC. 相似文献
48.
Martina Flörke Ellen Kynast Ilona Bärlund Stephanie Eisner Florian Wimmer Joseph Alcamo 《Global Environmental Change》2013,23(1):144-156
To enhance global water use assessment, the WaterGAP3 model was improved for back-calculating domestic, manufacturing and thermoelectric water uses until 1950 for 177 countries. Model simulations were carried-out on a national scale to estimate water withdrawals and consumption as well as cooling water required for industrial processes and electricity production. Additionally, the amount of treated and untreated wastewater as generated by the domestic and manufacturing sectors was modeled. In the view of data availability, model simulations are based on key socio-economic driving forces and thermal electricity production. Technological change rates were derived from statistical records in order to consider developments in water use efficiency, which turned out to have a crucial role in water use dynamics. Simulated domestic and industrial water uses increased from ca. 300 km3 in 1950 to 1345 km3 in 2010, 12% of which were consumed and 88% of which were discharged back into freshwater bodies. The amount of domestic and manufacturing wastewater increased considerably over the last decade, but only half of it was untreated. The downscaling of the untreated wastewater volume to river basin scale indicates a matter of concern in East and Southeast Asia, Northern Africa, and Eastern and Southern Europe. In order to reach the Millennium Development Goals, securing water supply and the reduction of untreated wastewater discharges should be amongst the priority actions to be undertaken. Population growth and increased prosperity have led to increasing water demands. However, societal and political transformation processes as well as policy regulations resulting in new water-saving technologies and improvements counteract this development by slowing down and even reducing global domestic and industrial water uses. 相似文献
49.
50.
We observed 18-cm OH emission in Comet 9P/Tempel 1 before and after Deep Impact. Observations using the Arecibo Observatory 305 m telescope took place between 8 April and 9 June, 2005, followed by post-impact observations using the National Radio Astronomy Observatory 100 m Green Bank Telescope 4-12 July, 2005. The resulting spectra were analyzed with a kinematic Monte Carlo model which allows estimation of the OH production rate, neutral gas outflow velocity, and distribution of the out-gassing from the nucleus. We detected typically 24% variability from the overall OH production rate trend in the two months leading up to the impact, and no dramatic increase in OH production in the days post-impact. Generally, the coma is well-described, within uncertainties, by a symmetric model with OH production rates from 1.6 to , and mean water outflow velocity of . At these low production rates, collisional quenching is expected to occur only within 20,000 km of the nucleus. However, our best-fit average quenching radius is 64,200 ± 22,000 km in April and May. 相似文献