Magnetic investigations of the West Hawk,Deep Bay and Clearwater impact structures,Canada

Abstract— Due to the effects of erosion, tectonism and burial, impact structures are often obscured or destroyed. Geophysical methods are increasingly being used in detecting the signatures of impact structures. While gravity lows associated with impact structures are well understood, associated magnetic anomaly lows are not. In this study, drill cores from three Canadian impact structures were analyzed for rock magnetic properties and mineralogy, in order to explain the magnetic anomaly lows associated with these structures. Samples from the drill cores were cut and measured for anisotropy of magnetic susceptibility (AMS) and natural remanent magnetization (NRM) parameters. Drill cores from the twin impact craters of the Clearwater structure exhibited different NRM characteristics, and samples from their respective drill cores were subject to demagnetization by alternating field and thermal techniques. The difference noted in their NRM characteristics was attributed to the acquisition of a viscous remanent magnetization (VRM) at depth in Clearwater East. At all three structures, both magnetic susceptibilities and remanent magnetizations are well below regional values in impact generated breccias, melt rocks, shocked crystalline rocks, and in postimpact sedimentary infill. The processes of brecciation, alteration, shock, and infill by nonmagnetic sediments contribute to the development of the magnetic lows. However, a significant contribution to the observed magnetic anomalies was found, by first-order forward modelling, to arise from basement rocks beneath the impact structures. This zone of reduced magnetization may be caused by the partial demagnetization of magnetite by the impact-induced transient stress wave traveling away from the point of impact.     

Estuarine phytoplankton group-specific responses to sublethal concentrations of the agricultural herbicide,atrazine

Atrazine is a common agricultural herbicide that is readily transported into estuaries through surface water runoff. In this study, we determined the short-term (24-48 h) sublethal effects of atrazine on estuarine phytoplankton biomass and community composition. Phytoplankton group-specific responses to atrazine exposure (25 microgh(-1)) were measured using natural water samples collected from two locations in Galveston Bay, Texas. Addition bioassays, coupled with HPLC pigment analysis, were used to quantify changes in the relative abundances of algal groups. For all algal groups except prasinophytes, the addition of atrazine in combination with nitrate was not significantly different from nitrate additions alone. These results suggest no significant negative effect of atrazine on phytoplankton under the specified environmental conditions for the bioassays. Although low concentrations of atrazine may have minimal impacts on phytoplankton, herbicide loadings need to be further characterized before generalizations can be applied to estuarine and coastal ecosystems.     

Oxyanion Concentrations in Eastern Sierra Nevada Rivers – 3. Boron, Molybdenum, Vanadium, and Tungsten

Water samples were collected from 10 locations along the Truckee River system, 14 locations along the Walker River system, and 12 locations along the Carson River, and analyzed for B, Mo, V, W, Na, Cl, and pH. Boron concentrations ranged from approximately 2 mol/kg in the upper reaches of the Truckee River to almost 1,200 mol/kg in Pyramid Lake. Molybdenum, V, and W had concentrations in the nanomolal range; Mo varied from a low of about 12 nmol/kg to a high of 3,200 nmol/kg (Walker Lake); V ranged from 9 nmol/kg to approximately 470 nmol/kg; and W varied from a low value around 0.8 nmol/kg (West Walker River) to 1,030 nmol/kg. The high concentrations of these oxyanion-forming trace elements in the rivers reflects (1) the relative stability of these oxyanions (e.g., MoO₄ ^2-, HVO₄ ^2-, WO₄ ^2-, B(OH)₃, and/or B(OH)₄ ^-) in the alkaline, well oxygenated river and lake waters, (2) contributions of hydrothermal waters (especially for B), and (3) weathering of rocks/regolith with high concentrations of these elements. In the case of Mo, V, and W, each exhibited relatively conservative behavior in the upper, oxygenated reaches of all three rivers. During the study period the region experienced a prolonged drought such that the lower reaches of each river were typified by no flow or stagnant waters and probably low oxygen and/or anoxic conditions (although not measured). Reductive processes occurring in the low flow to stagnant reaches of each river could have led to removal of Mo, V, and W from solution as coprecipitates with Fe monosulfides, or via sorption to Fe oxides/oxyhydroxides and/or organic matter. Boron, however, exhibited essentially no or minor removal from these rivers, and instead was added to each river via B-rich hydrothermal waters (e.g., Steamboat Creek from Steamboat Hot Springs), or by B-rich groundwaters via base-flow during the extensive drought.     

Middle Terrace Deposits of the Tagus River in Alpiarça, Portugal, in Relation to Early Human Occupation

The stratigraphy and sedimentology of the Q3 middle terrace alluvial sequence in the lower Tagus river valley, Portugal, were studied near the village of Alpiarça, approximately 40 km upstream from the estuarine area. Two main stratigraphic units were recognized, separated by an important uncomformity. The Lower Gravels unit (LG) consists of intercalations of medium to coarse gravel deposits, mainly quartzitic, with coarse sandy matrix, organized in tabular bodies. The overlying Upper Sands unit (US) consists of tabular sandy channel deposits and overbank fines, the latter containing well-developed paleosols and backswamp deposits, showing a general aggrading trend, apparently with varying rates; available data indicate that deposition of the US took place under temperate climatic conditions. Within US deposits are several paleolithic archaeological sites, the lower ones in the alluvial stratigraphy being Middle Acheulian, whereas those embedded in overlying deposits are, from bottom to top, Upper Acheulian and Micoquian. Some of these sites have been recently excavated. The quartzite artifacts were apparently abandoned by early humans on the flood plain surface during deposition of the US unit and were subjected to limited reworking during their incorporation in the alluvium. TL/OSL dating of sandy-silty sediments, though imprecise, support archaeological evidence pointing to an age of 150,000 to 70,000 yr B.P. for the US unit.     

High-pressure blueschists and eclogites in Hong'an: a framework for addressing the evolution of high- and ultrahigh-pressure rocks in central China

The Hong'an region in the Qinling–Dabie collisional zone in eastern China hosts a series of metamorphic rocks exposing a south-to-north distribution from blueschist/blueschist–greenschist, amphibolite, eclogite (kyanite free) and kyanite–eclogite to coesite–eclogite facies rocks that represent progressively deeper levels of the Mesozoic subduction–collision complex. The Hong'an area is interesting for three reasons: (1) it escaped the thermal and structural overprint imparted on much of the Dabie Mountains during Early Cretaceous intrusion of voluminous granites and granodiorites; (2) the high-pressure (HP) Hong'an eclogites are widely distributed, often preserve prograde crystallization histories and can be directly linked in time and space to the blueschist/blueschist–greenschist rocks exposed to the south; (3) the blueschist/blueschist–greenschist facies rocks are generally better exposed than their equivalents in the southeastern Dabie Mountains and offer some opportunity for simultaneous structural and metamorphic analysis. The Hong'an area HP rocks offer perhaps the closest approximation to a preserved snapshot of Mesozoic pressure–temperature (P–T) conditions attending early subduction–exhumation in the region, and are thus essential to generating a coherent picture of the dynamics attending both metamorphism and exposure of the coeval ultrahigh-pressure (UHP) rocks. The purpose of this contribution is twofold: (1) to document previously unpublished metamorphic and structural data characterizing these HP sequences and their relative continuity in Hong'an; (2) to incorporate these data with recent geochronologic, structural and paleomagnetic information in the context of protracted, late Paleozoic through Mesozoic subduction, collision and exhumation. Metamorphism and exhumation of some of the southern Hong'an HP sequences appear to have occurred concomitant with oceanic subduction immediately to the west, and thus may have preceded widespread continental subduction/collision. Moreover, all of the HP–UHP sequences in the region were exhumed before the end of collision between the Sino-Korean and Yangtze cratons at ca. 160 Ma. Exhumation of HP–UHP rocks both before and during continental plate collision is neither novel for central China nor for other HP–UHP zones, but is important to take into account when reconstructing the evolution of such orogens.     

Stratigraphic investigations at Los Buchillones,a coastal Taino site in north‐central Cuba

The authors present stratigraphic data from Los Buchillones, a now submerged Taino village on the north coast of central Cuba that was occupied from some time prior to A.D. 1220 until 1640 or later. Los Buchillones is one of the best‐preserved sites in the Caribbean, with material culture remains that include palm thatch and wooden structural elements from some of the more than 40 collapsed structures. The purpose of this study was to investigate the environment and site‐formation processes of the Taino settlement. Sediment cores were sampled from the site and its vicinity to permit integration of the geological and archaeological stratigraphies. The cores were analyzed for color, texture, mollusk content, elemental geochemistry, and mineralogy. The results of the stratigraphic work are consistent with regional sealevel data that shows relative sea level has risen gradually during the late Holocene, but has remained relatively stable since the time the Taino first occupied Los Buchillones. Of the two structures partially cleared, at least one appears to have been built over the water, supported on pilings. Site selection is likely to have resulted from a consideration of environmental factors, such as access to marine, terrestrial, and lagoonal resources, and proximity to freshwater springs. © 2006 Wiley Periodicals, Inc.     

Fifty-eight years and counting of watershed science at the Caspar Creek Experimental Watersheds in northern California

The Caspar Creek Experimental Watersheds are the site of a long-term paired watershed study in the northern Coast Ranges of California. The watersheds are predominately forested with coast redwood and Douglas-fir. Old-growth forest was logged between 1860 and 1904. Two harvesting experiments have been completed since then and a third experiment is currently underway. Caspar Creek data are split into three phases corresponding to three experiments: Phase 1 (1962–1985) reports on a selection harvest (1971–1973) and initial recovery in the South Fork watershed; Phase 2 (1985–2017) includes clearcut harvesting of ~50% of the North Fork watershed (1985–1992) and recovery; and Phase 3 (2017 onward) corresponds to a second selection harvest in the South Fork watershed with a range of subwatershed harvest intensities (2017–2019) and recovery. All three experiments included harvest-related road-building and relied primarily on measurements of streamflow and sediment delivery from both treated and reference watersheds. Major findings include modest increases in post-harvest peak flows and cumulative flow volumes, post-harvest low flows that initially increased and then decreased 12 to 15 years after harvesting, and the consequences of different yarding techniques and road design on sediment yields. Some of the data for Phase 1 and Phase 2 are available in a USDA Forest Service online archive. The archived data include precipitation, streamflow, suspended sediment concentrations, turbidity, accumulated weir pond sediment volumes, bedload transport rates, water stable isotope data, and geospatial data. Archiving activities are ongoing. Phase 3 data are currently being collected and will be archived after a post-harvest monitoring period.     

Late Mesoproterozoic rifting in Arctic Canada during Rodinia assembly: impactogens,trans‐continental far‐field stress and zinc mineralisation

This paper challenges the conventional interpretation of a major, economically important Mesoproterozoic intracratonic rift system as a group of aulacogens, proposing instead that they are rifts that developed in response to far‐field stress caused by continent–continent collision (impactogens) during supercontinent assembly. The tectonostratigraphic evolution of the Bylot basins (Arctic Canada) records dramatic alternations between extensional and compressional stress regimes, precluding an aulacogen interpretation and favouring an impactogen interpretation. New geochronological data (U–Th–Pb whole‐rock depositional age; detrital zircon signatures) provide a record of impactogens that developed in Laurentia's interior as a result of Grenvillian (~1.1 Ga) far‐field stress during assembly of the supercontinent Rodinia. Formation of the world‐class Nanisivik zinc deposit in one of the rifts is temporally associated with the Grenvillian orogeny, and consequently represents both (i) a rare exception to the global pattern of few ore deposits forming during supercontinent episodes, and (ii) a hitherto unrecognised tectonic setting for carbonate‐hosted zinc deposits.     

CHOSEN: A synthesis of hydrometeorological data from intensively monitored catchments and comparative analysis of hydrologic extremes

Comparative hydrology has been hampered by limited availability of geographically extensive, intercompatible monitoring data on comprehensive water balance stores and fluxes. These limitations have, for example, restricted comprehensive assessment of multiple dimensions of wetting and drying related to climate change and hampered understanding of why widespread changes in precipitation extremes are uncorrelated with changes in streamflow extremes. Here, we address this knowledge gap and underlying data gap by developing a new data synthesis product and using that product to detect trends in the frequencies and magnitudes of a comprehensive set of hydroclimatic and hydrologic extremes. CHOSEN (Comprehensive Hydrologic Observatory Sensor Network) is a database of streamflow, soil moisture, and other hydroclimatic and hydrologic variables from 30 study areas across the United States. An accompanying data pipeline provides a reproducible, semi-automated approach for assimilating data from multiple sources, performing quality assurance and control, gap-filling and writing to a standard format. Based on the analysis of extreme events in the CHOSEN dataset, we detected hotspots, characterized by unusually large proportions of monitored variables exhibiting trends, in the Pacific Northwest, New England, Florida and Alaska. Extreme streamflow wetting and drying trends exhibited regional coherence. Drying trends in the Pacific Northwest and Southeast were often associated with trends in soil moisture and precipitation (Pacific Northwest) and evapotranspiration-related variables (Southeast). In contrast, wetting trends in the upper Midwest and the Rocky Mountains showed few univariate associations with other hydroclimatic extremes, but their latitudes and elevations suggested the importance of changing snowmelt characteristics. On the whole, observed trends are incompatible with a ‘drying-in-dry, wetting-in-wet’ paradigm for climate-induced hydrologic changes over land. Our analysis underscores the need for more extensive, longer-term observational data for soil moisture, snow and evapotranspiration.     

Variability of dissolved organic carbon in precipitation during storms at the Shale Hills Critical Zone Observatory

Organic compounds are removed from the atmosphere and deposited to the Earth's surface via precipitation. In this study, we quantified variations of dissolved organic carbon (DOC) in precipitation during storm events at the Shale Hills Critical Zone Observatory, a forested watershed in central Pennsylvania (USA). Precipitation samples were collected consecutively throughout the storm during 13 events, which spanned a range of seasons and synoptic meteorological conditions, including a hurricane. Further, we explored factors that affect the temporal variability by considering relationships of DOC in precipitation with atmospheric and storm characteristics. Concentrations and chemical composition of DOC changed considerably during storms, with the magnitude of change within individual events being comparable or higher than the range of variation in average event composition among events. Although some previous studies observed that concentrations of other elements in precipitation typically decrease over the course of individual storm events, results of this study show that DOC concentrations in precipitation are highly variable. During most storm events, concentrations decreased over time, possibly as a result of washing out of the below‐cloud atmosphere. However, increasing concentrations that were observed in the later stages of some storm events highlight that DOC removal with precipitation is not merely a dilution response. Increases in DOC during events could result from advection of air masses, local emissions during breaks in precipitation, or chemical transformations in the atmosphere that enhance solubility of organic carbon compounds. This work advances understanding of processes occurring during storms that are relevant to studies of atmospheric chemistry, carbon cycling, and ecosystem responses.