Spatial and temporal distribution of cadmium and copper in water and zooplankton in the Bahía Blanca estuary,Argentina

Cadmium and copper in the dissolved and particulate phase and in zooplankton were determined in the Bahía Blanca estuary during six surveys from March to December 2005. Temperature, pH, salinity, dissolved oxygen, suspended particulate matter, particulate organic matter and chlorophyll-a were also considered. Dissolved Cd was below the detection limit (0.2 μg L⁻¹) for almost the entire study period whereas Cu concentrations (0.5–2.4 μg L⁻¹) indicated a continuous dissolved Cu input. Particulate Cd concentrations ranged from below the detection limit (<0.01) to 28.6 μg g⁻¹ d.w. while particulate Cu ranged from below the detection limit (<0.04) to 53.5 μg g⁻¹ d.w. Cd in mesozooplankton ranged from below the detection limit (<0.01) to 37.4 μg g⁻¹ d.w. Some of the Cd levels were higher than those reported for other aquatic ecosystems. Cu in the mesozooplankton ranged from 1.3 to 89.3 μg g⁻¹ d.w., values which were within the reported values or higher than other studies. The log of the partition coefficients (log (K_d)) of Cd was 0.04, while log (K_d) for Cu ranged from −0.39 to 2.79. These values were lower than both those calculated for other estuaries and the typical coefficients for marine environments. The log of the bioconcentration factor (log BCF) of Cd was 1.78, indicating that Cd concentration was higher in the zooplankton than in the dissolved phase. Log BCF of Cu ranged from 1.15 to 3. The logs of the biomagnification factors (log BMF) of Cd were low, with a range between −3.45 and 2.21 and those for Cu ranged from −0.1 to 3.35. Positive values indicate biomagnification while negative values indicate biodiminution. In general, no significant dissolved Cd concentration appeared to be present in the Bahía Blanca estuary and Cu values did not indicate a critical environmental status. The particulate phase seemed to be the major carrier for Cd and Cu and TPCu values were within the normal values for an anthropogenically stressed estuary but not for a strongly polluted system. This fraction was the most important metal source for the mesozooplankton. Moreover, the highest metal concentrations were in the mesozooplankton since most of the bioconcentration and biomagnification factors were positive, especially for Cu.     

Marsh expansion at Calaveras Point Marsh, South San Francisco Bay, California

Studies of shoreline progradation along low-energy vegetated shorelines have been limited, as these environments are generally experiencing erosion rather than deposition, with extreme erosion rates frequently found. This study examined yearly changes along a vegetated shoreline at Calaveras Point Marsh, South San Francisco Bay, California, using aerial photography, to determine the roles of climatic, watershed, and coastal process in driving shoreline changes. In addition, sediment accumulation was monitored on a yearly basis at 48 locations across the marsh to determine the role of geomorphic factors in promoting accumulation. Calaveras Point Marsh was found to have expanded from 49.26 ± 5.2 to 165.7 ± 4.7 ha between 1975 and 2005. Although the rate of marsh expansion was not positively correlated with yearly variability in precipitation, local streamflow, delta outflow, water level observations, population growth, or ENSO indices, marsh growth was greater during years of higher than average temperatures. Warmer temperatures may have promoted the recruitment and growth of Spartina foliosa, a C₄ grass known to be highly responsive to temperature. Other factors, such as the formation of a coastal barrier, a recent change in the location of the mouth of the Guadalupe River, and channel readjustment in response to diking are credited with driving the bulk of the marsh expansion. Sediment accumulation was found to be high closest to channels and to the shoreline, at low elevations and in recently vegetated marsh. Globally, the pace of sea level rise exerts the primary control on wetland development and persistence. However, at local geographic scales, factors such as tectonic events, modifications to natural sediment transport pathways or land use changes may overwhelm the effects of regional sea level rise, and allow for wetlands to develop, expand and persist despite rapid sea level rise.     

Potential source and diagenetic signatures of oceanic dissolved and particulate organic matter as distinguished by lipid biomarker distributions

Potential biogenic sources of ultrafiltered dissolved and suspended particulate organic matter (UDOM and POM, respectively) from the Sargasso Sea (SS) and North Central Pacific (NCP) Ocean were investigated using lipid biomarker compounds. Organic carbon (OC) concentrations were ~ 20–40 times greater in UDOM than POM and decreased with depth. However, total OC-normalized lipid concentrations were 2–3 orders of magnitude higher in POM than in UDOM. Particulate total lipids decreased 3–10-fold with depth, compared to 10–20% for dissolved total lipids. Total fatty acids (FA), the most abundant lipids, showed similar patterns as total lipids, comprising ~ 62–88% of the total lipids analyzed in UDOM and ~ 57–84% in POM.FA were dominated by straight-chain saturated compounds followed by monounsaturated, polyunsaturated, and branched FA. Polyunsaturated FA were enriched in POM vs. UDOM and in surface vs. deep waters for both UDOM and POM, likely reflecting the algal origins and greater reactivity of surface-derived materials. In both UDOM and POM, sterols of planktonic origin dominated, including cholest-5-en-3β-ol (C₂₇Δ⁵), 24-methylcholesta-5,24(28)E-dien-3β-ol (C₂₈Δ^5,24(28)) and 24-ethylcholest-5-3β-ol (C₂₉Δ⁵), with varying contributions from cholesta-5,22E-3β-ol (C₂₇Δ^5,22), 24-methylcholesta-5,22E-3β-ol (C₂₈Δ^5,22) and 24-ethylcholesta-5,22E-3β-ol (C₂₉Δ^5,22).Factor analysis of lipid biomarkers showed major differences between the UDOM and POM pools and for each pool as a function of depth, but not between the SS and NCP. While UDOM and POM biomarkers were both dominated by autochthonous sources, differences between the two pools suggest potential effects from some combination of source and diagenetic factors. The lipid biomarker data are further evaluated relative to previous studies of radiocarbon (¹⁴C) and elemental (C:N:P) characteristics of UDOM and POM in the SS and NCP.     

Discovery of a single faint AGN in a large sample of z > 5 Lyman break galaxies

As part of a large spectroscopic survey of   z > 5  Lyman break galaxies (LBGs), we have identified a single source which is clearly hosting an active galactic nucleus (AGN). Out of a sample of more than 50 spectroscopically confirmed R -band dropout galaxies at   z ∼ 5  and above, only J104048.6−115550.2 at   z = 5.44  shows evidence for a high ionization potential emission line indicating the presence of a hard ionizing continuum from an AGN. Like most objects in our sample the rest-frame-UV spectrum shows the UV continuum breaking across a Lyα line. Uniquely within this sample of LBGs, emission from N  v is also detected, a clear signature of AGN photoionization. The object is spatially resolved in Hubble Space Telescope ( HST ) imaging. This, and the comparatively high Lyα/N  v flux ratio indicates that the majority of the Lyα (and the UV continuum longward of it) originates from stellar photoionization, a product of the ongoing starburst in the LBG. Even without the AGN emission, this object would have been photometrically selected and spectroscopically confirmed as a Lyman break in our survey. The measured optical flux  ( I _AB= 26.1)  is therefore an upper limit to that from the AGN and is of order 100 times fainter than the majority of known quasars at these redshifts. The detection of a single object in our survey volume is consistent with the best current models of high redshift AGN luminosity function, providing a substantial fraction of such AGN is found within luminous starbursting galaxies. We discuss the cosmological implications of this discovery.     

Forensic identification of sixteen species of Chesapeake Bay sportfishes using mitochondrial DNA restriction fragment-length polymorphism (RFLP) analysis

A method for the genetic identification of sixteen species of Chesapeake Bay sportfishes was developed using restriction fragment-length polymorphism (RFLP) analysis of two mitochondrial (mt) DNA gene regions amplified by the polymerase chain reaction (PCR). To facilitate molecular-based identifications we screened for genetic markers that revealed minimal intraspecific variation but consistently discriminated among the different species. Two mitochondrial markers were developed to provide redundancy for identifications, and 40 individuals of each species were screened with both markers. The primary marker was a region of mtDNA approximately 1,495 base-pairs (bp) in length that included part of the 12S ribosomal RNA (rRNA) gene and crossed into the adjacent 16S rRNA gene. When digested with the restriction enzymeRsa I, this region provided unique restriction patterms for all sixteen species. The second marker was a region of the mitochondrial NADH dehydrogenase 4 (ND4) gene approximately 1,700 bp in length and digested with the restriction enzymeBstO I. This marker also discriminated among all sixte en species, but revealed higher levels of intraspecific variation than the rRNA genes. An additional set of restriction profiles was obtained for this region using the enzymeAva II to provide identification in the event a novel restriction pattern might be encountered in future studies. Because a minimal amount of tissue is required for the PCR/RFLP analysis, these molecular markers should prove useful in identifying fishes both as adults and in their early life history stages.     

'Situating' Simulation to Model Human Spatio-Temporal Interactions: An Example Using Crime Events

Many social phenomena have a spatio‐temporal dimension and involve dynamic decisions made by individuals. In the past, researchers have often turned to geographic information systems (GIS) to model these interactions. Although GIS provide a powerful tool for examining the spatial aspects of these interactions, they are unable to model the dynamic, individual‐level interactions across time and space. In an attempt to address these issues, some researchers have begun to use simulation models. But these models rely on artificial landscapes that do not take into account the environment in which humans move and interact. This research presents the methodology for ‘situating’ simulation through the use of a new modeling tool, Agent Analyst, which integrates agent‐based modeling (ABM) and GIS. Three versions of a model of street robbery are presented to illustrate the importance of using ‘real’ data to inform agent activity spaces and movement. The successful implementation of this model demonstrates that: (1) agents can move along existing street networks; (2) land use patterns can be used to realistically distribute agent's homes and activities across a city; and (3) the incidence and pattern of street robberies is significantly different when ‘real’ data are used.     

Community structure and phenology of chironomids (Insecta: Chironomidae) in a Patagonian Andean stream

In this paper, we studied the assemblage of Chironomidae from headwaters of Ñireco stream by recording drifting pupal exuviae caught in the debris close to the shore. Samples were collected in three stations along 18 km of the stream every 2 weeks during spring–summer months and monthly during autumn–winter over a year. A total of 15949 exuviae were collected and 55 taxa were identified. The most abundant taxa were Cricotopus spp. with highest numbers of exuviae recorded in each station over the study period. Subfamily Orthocladiinae was the most abundant taxa, followed by Chironominae and Podonominae. The emergence period in the stream occurred between December 1998 and March 1999. Most of the dominant and frequent species were univoltine. The emergence peaks at each sampling station occurred at the highest temperature of the water recorded.     

A multi-site campaign on the long period variable subdwarf b star PG 1627+017

We report on the outcome of the first major multi-site campaign on a long-period variable subdwarf B star. The target PG 1627+017 was observed for a total of 334 h during April/May/June 2003 from the lynchpin observatory at Mt. Bigelow, Arizona, with important contributions coming from co-observations at SAAO, Calar Alto and Siding Spring. Preliminary analysis indicates the presence of 8–10 probable periods in the range ～4500 to ～8900 s with relative amplitudes between 0.1 and 0.5%;. The range over which the periods are found is in qualitative agreement with theoretical predictions and the number of periods found shows potential for an in-depth asteroseismological analysis. Multi-colour observations show that the relative amplitudes of pulsation are larger in the U-band than in the R, which again is in agreement with theory. However, more multi-colour observations are needed to be able to make statements at the quantitative level.     

FINANCIAL ANALYSIS OF SUBURBAN ANNEXATION ALTERNATIVES

This study evaluates municipal and school-district services required by a set of proposed annexations in Murray, Utah. Long-term fiscal implications of boundary expansion were examined using financial analysis procedures. The analysis reveals that a limited annexation policy is financially advantageous for communities preferring locally provided public services. Such a policy ignores nonfiscal municipal goals and impacts on other jurisdictions.