Fixed-ammonium in clays associated with crude oils

The association of ammonium (NH₄⁺) silicates with organic-rich sedimentary environments has stimulated interest in the chemical cycle of N, and its possible application as an indicator of in situ organic maturation reactions or crude oil migration. Fixed-NH₄ in clay minerals was determined from three hydrocarbon occurrences of similar depositional environment but different ages, depth and thermal maturity, to determine whether anomalously high NH₄-substitution occurs near mature hydrocarbons. Results show higher fixed-NH₄ concentrations in marginally mature mudstones than in immature sediments. The highest fixed-NH₄ concentrations were found in clays from sandstone reservoirs containing migrated crude oil.Fixed-NH₄ in clays from Holocene oil seep sediments in the Gulf of Mexico continental slope, offshore Louisiana, averages 0.08 wt % and increases with depth in shallow cores (420 cm), reflecting an early diagenetic trend that is apparently not influenced by migrating crude oil. Programmed pyrolysis shows that the sediments are thermally immature (av.T_max = 419°C). High Hydrogen Index values (av.= 359mg/g) are the result of biodegraded crude oil, and a high Oxygen Index (av.= 182mg/g) reflects the presence of authigenic carbonate.Fixed-NH₄ averages 0.16 wt % in Wilcox Group (Eocene) mudstones enclosing two sandstone reservoirs at Fordoche Field, onshore Louisiana. In comparison to these mudstones, anomalously high NH₄-fixation appears to occur in reservoir clay minerals. Pyrolysis shows that the sediments are marginally mature for crude oil generation (av.T_max = 432°C). Average Hydrogen Index (187 mg/g) and Oxygen Index values (75 mg/g) are consistent with oil-prone Type II and Type III kerogen. Increased pyrolysis Production Index values and solvent extraction shows the presence of migrated crude oil. This suggests that a reaction which releases NH₃ during crude oil generation or migration is recorded byNH₄⁺ substitution in clays.Fixed-NH₄ and total organic carbon (TOC) at Fordoche Field show no statistically significant correlation, suggesting that NH₄⁺ substitution in clay minerals is not simply related to the amount of organic matter in the section, but is also influenced by the presence of crude oil. Once NH₄⁺ has been fixed in clays, it is a more stable hydrocarbon proximity indicator than pore fluid tracers, because it is less influenced by later chemical or geological changes.     

The first rural women's network in New South Wales: seventy years of the country women's association

The Country Women's Association of NSW (CWA) is the main voice of rural women in the state. It has been the biggest women's organisation in NSW until very recently. Its significant contribution to rural community development has been overlooked. After its foundation in 1922, the CWA established a widespread women's network, as well as many facilities for women and children. The necessary fund‐raising activities required the organisation of regular social activities in country towns. The CWA has always affirmed women's traditional gender roles, and it has never challenged the male hegemony typical of rural Australia. By contributing to the improvement of rural conditions, to the stability of family life and to local social activities, the CWA has helped to develop the rural economy as well as local and national identity. It has helped women put down roots in country areas. Its future role needs to be defined in the context of the difficult economic situation, and of the changes in gender roles, in rural NSW.     

International migration and health: Sickle cell and thalassaemia health care in the United Kingdom

Human migration has contributed to the redistribution of diseases from regions where they were endemic, thereby creating new areas where the task of control and management has become necessary. This is the case with respect to the major haemoglobinopathies — sickle cell anaemia and thalassaemia — in the United Kingdom since World War II. On the one hand, the great cultural diversity of the immigrant population presents an important challenge in delivering health care to the populations at risk of the diseases. On the other hand, the spatial concentration of these populations is one of the greatest advantages in the management of the disorders, since access to centrally located services can be optimized.The case of health care relating to the major haemoglobinopathies in the United Kingdom raises practical and theoretical questions about the most effective health care delivery models for ethnic minority needs. In turn, this issue has important implications for decisions concerning national and regional budgetary priorities in the health service and the position of minority medicine in the allocation of resources.     

Size selection of Atlantic rangia clams,Rangia cuneata,by blue crabs,Callinectes sapidus

Male blue crabsCallinectes sapidus Rathbun were allowed to forage on six size classes of the Atlantic rangia clam,Rangia cuneata (Sowerby), in laboratory squaria under conditions of restricted or unrestricted prey size availability. Prey profitability (energy gained divided by handling time) decreased as prey size increased. Crabs preferred smaller clams (1–2 cm long, then 2–3 cm long), as predicted by an energy maximization model. Under conditions of restricted prey sizes (nonreplacement experiments), when the smaller clams were no longer available, crabs tended to choose progressively larger clams. Crabs did not exhibit selective feeding behavior among clams larger than 3 cm long. For the range of crab sizes tested (71–167 mm carapace width), there was no correlation between crab carapace width and the mean clam size that was eaten.     

Groundwater contributions of flow and nitrogen in a headwater agricultural watershed

Nonpoint sources of nitrogen (N) and other nutrients are a major source of water pollution within the Chesapeake Bay watershed and other basins around the world. Human activities associated with agricultural practices can account for a large percentage of N loadings delivered to streams and rivers. This work aims to improve understanding of N transport from groundwater to surface waters, quantifying the principal hydrological processes driving water and N fluxes into and out of a headwater agricultural stream reach. The study site is a 175-m stream reach in a heavily cultivated 40-ha watershed in east-central Pennsylvania. This subwatershed is underlain by fractured shale bedrock, and receives most of its baseflow from groundwater, either by diffuse matrix discharge through the streambed or by localized discharge through riparian seeps. Samples of stream, seep, and shallow groundwater were collected approximately monthly under steady hydrologic conditions in 2017. Calculated matrix flow from hydraulic head and conductivity measurements paired with differential stream gauging was used to solve for the riparian seep flux using a mass balance approach. Riparian seep fluxes ranged from 45 to 217 m³/d, transporting 0.6–4.2 kg N d⁻¹ of nitrate-N from the fractured bedrock aquifer to the stream. Hydrochemical data suggest that the stream is mainly disconnected from the underlying aquifer and that seeps supply essentially all water and N to the system. Seeps are likely sourced with N in nearby agricultural fields and accelerated through the system with shorter residence times than shallow groundwater. Water isotope data reinforced this notion. This study underscores the importance of agriculture as a source of N to ground and surface waters. Identifying source areas that are causing groundwater enrichment of N and seep areas where N discharges to streams is beneficial for developing N pollution mitigation strategies and implementing management practices that aim to reduce nutrient loads to the Chesapeake Bay.     

Palynology of seafloor samples collected by the 1911–14 Australasian Antarctic expedition: Implications for the geology of coastal East Antarctica

Fifty‐three sea‐floor samples close to Antarctica collected by Douglas Mawson during the Australasian Antarctic Expedition of 1911–1914 have beeen analysed for recycled palynomorphs. The distribution of the recycled microfossils provides a broad guide to the position of hidden sedimentary sequences on the Antarctic continental margin.

The samples were dredged off the East Antarctic coast between 91°E and 146°E. In three distinct ‐areas, concentrations of recycled palynomorphs suggest the presence nearby of eroding sedimentary sequences. Near the western edge of the Shackleton Ice Shelf the recycled suite suggests Early to Late Permian, Late Jurassic to mid‐Cretaceous, and Late Cretaceous to Early Tertiary sediments, with evidence for marine influence only in the Tertiary. Samples from the outer edge of the continental shelf and slope east of Cape Carr indicate Early Cretaceous and Late Cretaceous to Early Tertiary sequences, and the same age span is suggested by samples from the western side of the Mertz Glacier Tongue; in this area radio echosounding has suggested that inland sedimentary basins intersect the coast.

The sedimentary sequence predicted for the Shackleton Ice Shelf area probably faced the open Indian Ocean, at least since the Mesozoic. Cretaceous sequences predicted for the other localities occur at points on the Antarctic coast where they would be expected on the basis of most reconstructions. The area east of Cape Carr has as its conjugate’ coast part of the Great Australian Bight Basin; that off the Mertz Glacier, the area west of the Otway Basin. At both these areas on the southern Australian margin thick Cretaceous rift‐valley sequences occur.     

Transformation of Trichloroethylene to Predominantly Non‐Regulated Products under Stimulated Sulfate Reducing Conditions

Anaerobic microcosms containing sediment and water were amended to generate a range of mass loadings of FeS. Microcosms were then spiked with trichloroethylene (TCE) and the concentration of TCE and possible volatile reaction products monitored over time. The lowest yields of TCE, as well as the lowest yields of reaction products regulated under the Safe Drinking Water Act (i.e., dichloroethylene isomers and vinyl chloride), were observed at FeS mass loadings at or above 20 g/L. Sixty eight days after spiking with TCE, selected microcosms were amended with sulfate and lactate, or sulfate, Fe(II), and lactate, and the effect of these amendments on TCE transformation and yield of regulated products was compared to microcosms that did not receive any amendments. Addition of sulfate, Fe(II), and lactate led to the greatest improvement on TCE depletion rates and the lowest yields of regulated reaction products compared with addition of sulfate and lactate, or no amendments. Analysis of kinetic modeling suggests that microbial and abiotic processes acted in concert to promote TCE transformation to a relatively low yield of regulated products in microbially active microcosms that contained high mass loadings of FeS.     

Copper Biosorption by Spent Coffee Ground: Equilibrium,Kinetics, and Mechanism

The potential use of spent coffee ground (SCG) for the removal of copper has been investigated as a low‐cost adsorbent for the biosorption of heavy metals. Adsorption batch experiments were conducted to determine isotherms and kinetics. The biosorption equilibrium data were found to fit well the Freundlich model and an experimental maximum biosorption capacity of copper ions 0.214 mmol/g was achieved. The biosorption kinetics of SCG was studied at different adsorbate concentrations (0.1–1.0 mM) and stirring speeds (100–400/min). The results showed an increase in the copper ion uptake with raising the initial metal concentration and the kinetic data followed the pseudo‐second order rate expression. The effect of stirring speed was a significant factor for the external mass transfer resistance at 100/min and coefficients were estimated by the Mathews and Weber model. Biosorption of copper ions onto SCG was observed to be related mainly with the release of calcium and hydrogen ions suggesting that biosorption performance by SCG can be attributed to ion‐exchange mechanism with calcium and hydrogen ions neutralizing the carboxyl and hydroxyl groups of the biomass.