Size selection of Atlantic rangia clams,Rangia cuneata,by blue crabs,Callinectes sapidus

Male blue crabsCallinectes sapidus Rathbun were allowed to forage on six size classes of the Atlantic rangia clam,Rangia cuneata (Sowerby), in laboratory squaria under conditions of restricted or unrestricted prey size availability. Prey profitability (energy gained divided by handling time) decreased as prey size increased. Crabs preferred smaller clams (1–2 cm long, then 2–3 cm long), as predicted by an energy maximization model. Under conditions of restricted prey sizes (nonreplacement experiments), when the smaller clams were no longer available, crabs tended to choose progressively larger clams. Crabs did not exhibit selective feeding behavior among clams larger than 3 cm long. For the range of crab sizes tested (71–167 mm carapace width), there was no correlation between crab carapace width and the mean clam size that was eaten.     

Groundwater contributions of flow and nitrogen in a headwater agricultural watershed

Nonpoint sources of nitrogen (N) and other nutrients are a major source of water pollution within the Chesapeake Bay watershed and other basins around the world. Human activities associated with agricultural practices can account for a large percentage of N loadings delivered to streams and rivers. This work aims to improve understanding of N transport from groundwater to surface waters, quantifying the principal hydrological processes driving water and N fluxes into and out of a headwater agricultural stream reach. The study site is a 175-m stream reach in a heavily cultivated 40-ha watershed in east-central Pennsylvania. This subwatershed is underlain by fractured shale bedrock, and receives most of its baseflow from groundwater, either by diffuse matrix discharge through the streambed or by localized discharge through riparian seeps. Samples of stream, seep, and shallow groundwater were collected approximately monthly under steady hydrologic conditions in 2017. Calculated matrix flow from hydraulic head and conductivity measurements paired with differential stream gauging was used to solve for the riparian seep flux using a mass balance approach. Riparian seep fluxes ranged from 45 to 217 m³/d, transporting 0.6–4.2 kg N d⁻¹ of nitrate-N from the fractured bedrock aquifer to the stream. Hydrochemical data suggest that the stream is mainly disconnected from the underlying aquifer and that seeps supply essentially all water and N to the system. Seeps are likely sourced with N in nearby agricultural fields and accelerated through the system with shorter residence times than shallow groundwater. Water isotope data reinforced this notion. This study underscores the importance of agriculture as a source of N to ground and surface waters. Identifying source areas that are causing groundwater enrichment of N and seep areas where N discharges to streams is beneficial for developing N pollution mitigation strategies and implementing management practices that aim to reduce nutrient loads to the Chesapeake Bay.     

Palynology of seafloor samples collected by the 1911–14 Australasian Antarctic expedition: Implications for the geology of coastal East Antarctica

Fifty‐three sea‐floor samples close to Antarctica collected by Douglas Mawson during the Australasian Antarctic Expedition of 1911–1914 have beeen analysed for recycled palynomorphs. The distribution of the recycled microfossils provides a broad guide to the position of hidden sedimentary sequences on the Antarctic continental margin.

The samples were dredged off the East Antarctic coast between 91°E and 146°E. In three distinct ‐areas, concentrations of recycled palynomorphs suggest the presence nearby of eroding sedimentary sequences. Near the western edge of the Shackleton Ice Shelf the recycled suite suggests Early to Late Permian, Late Jurassic to mid‐Cretaceous, and Late Cretaceous to Early Tertiary sediments, with evidence for marine influence only in the Tertiary. Samples from the outer edge of the continental shelf and slope east of Cape Carr indicate Early Cretaceous and Late Cretaceous to Early Tertiary sequences, and the same age span is suggested by samples from the western side of the Mertz Glacier Tongue; in this area radio echosounding has suggested that inland sedimentary basins intersect the coast.

The sedimentary sequence predicted for the Shackleton Ice Shelf area probably faced the open Indian Ocean, at least since the Mesozoic. Cretaceous sequences predicted for the other localities occur at points on the Antarctic coast where they would be expected on the basis of most reconstructions. The area east of Cape Carr has as its conjugate’ coast part of the Great Australian Bight Basin; that off the Mertz Glacier, the area west of the Otway Basin. At both these areas on the southern Australian margin thick Cretaceous rift‐valley sequences occur.     

Transformation of Trichloroethylene to Predominantly Non‐Regulated Products under Stimulated Sulfate Reducing Conditions

Anaerobic microcosms containing sediment and water were amended to generate a range of mass loadings of FeS. Microcosms were then spiked with trichloroethylene (TCE) and the concentration of TCE and possible volatile reaction products monitored over time. The lowest yields of TCE, as well as the lowest yields of reaction products regulated under the Safe Drinking Water Act (i.e., dichloroethylene isomers and vinyl chloride), were observed at FeS mass loadings at or above 20 g/L. Sixty eight days after spiking with TCE, selected microcosms were amended with sulfate and lactate, or sulfate, Fe(II), and lactate, and the effect of these amendments on TCE transformation and yield of regulated products was compared to microcosms that did not receive any amendments. Addition of sulfate, Fe(II), and lactate led to the greatest improvement on TCE depletion rates and the lowest yields of regulated reaction products compared with addition of sulfate and lactate, or no amendments. Analysis of kinetic modeling suggests that microbial and abiotic processes acted in concert to promote TCE transformation to a relatively low yield of regulated products in microbially active microcosms that contained high mass loadings of FeS.     

Copper Biosorption by Spent Coffee Ground: Equilibrium,Kinetics, and Mechanism

The potential use of spent coffee ground (SCG) for the removal of copper has been investigated as a low‐cost adsorbent for the biosorption of heavy metals. Adsorption batch experiments were conducted to determine isotherms and kinetics. The biosorption equilibrium data were found to fit well the Freundlich model and an experimental maximum biosorption capacity of copper ions 0.214 mmol/g was achieved. The biosorption kinetics of SCG was studied at different adsorbate concentrations (0.1–1.0 mM) and stirring speeds (100–400/min). The results showed an increase in the copper ion uptake with raising the initial metal concentration and the kinetic data followed the pseudo‐second order rate expression. The effect of stirring speed was a significant factor for the external mass transfer resistance at 100/min and coefficients were estimated by the Mathews and Weber model. Biosorption of copper ions onto SCG was observed to be related mainly with the release of calcium and hydrogen ions suggesting that biosorption performance by SCG can be attributed to ion‐exchange mechanism with calcium and hydrogen ions neutralizing the carboxyl and hydroxyl groups of the biomass.     

Island Exceptionalism and International Maritime Conflicts

Scholars have argued that due to their special geographical circumstances, island states develop a different relationship with maritime space than their continental counterparts. This is generally attributed both to island residents’ greater access to and benefit from oceanic resources and also to the metaphysical qualities of life that uniquely develop on islands. This article investigates deeper into the phenomenon of geographically determined island exceptionality by considering whether island states and mainland states truly behave differently when it comes to their treatment of and behavior in maritime spaces. Through an analysis of disputed areas in the International Correlates of War maritime data, I consider whether island states are more likely to try and confirm sovereignty over disputed maritime waters than mainland states. My examination of disputed maritime areas in the Western Hemisphere and Europe from 1900 to 2001 shows that indeed island states are both more likely to try and settle a disputed maritime area, whether by force or by negotiated resolution. This finding is then used to raise new questions about the geographic differences that characterize island states in the world political system.     

A Regional Measure of Neighborhood Multiple Environmental Deprivation: Relationships with Health and Health Inequalities

The health impacts of simultaneous exposure to multiple adverse environmental factors are of concern in the United Kingdom. UK-wide indicators exist, but context-specific finer resolution measures are lacking. An environmental deprivation index was developed for 398 neighborhoods (average population = 760) in a Scottish council area, including measures of air pollution, noise pollution, traffic environment, undesirable land uses, and crime. Adverse environmental conditions were related to ill health in the region and implicated in wider socioeconomic health inequalities. The results suggest an independent role for environmental deprivation in explaining poor health and health inequalities.     

Sex Offender Residential Movement Patterns: A Markov Chain Analysis

This article introduces a new approach to the analysis of changes in sex offender residences over time. Using a Markov chain framework, we analyze residential movement patterns of registered sex offenders in Hamilton County, Ohio, over a three-year period (2005–2007). Results indicate a 46 percent reduction in offenders violating spatial restriction zone policy as compared to a counterfactual case where offenders move as a function of housing distributions. Strong legacy effects are also found as offenders previously in violation of restriction policies move into other restricted zones at a higher rate than offenders who were previously in compliance with the policy. Parcels that previously were home to registered offenders also continue to attract offenders in future periods. Although we find differences in the probabilities of attracting offenders for parcels outside and inside restricted zones that are consistent with offender restrictive policies, these differences are actually significantly smaller than what holds under the counterfactual. Parcels in restricted zones continue to attract offenders at a higher rate than expected, despite the policy restrictions.