A non-magmatic iron projectile for the Gardnos impact event

The goal of this study is to identify the type of projectile responsible for the formation of the late Precambrian Gardnos impact structure in Norway. Fifteen impactite samples, predominantly impact breccias and suevites from the central and northeastern part of the structure, were analyzed for platinum group elements (PGE) and Au using nickel-sulfide fire assay combined with inductively coupled plasma mass spectrometry (ICP-MS). Major and trace elements were measured in the same samples using X-ray fluorescence (XRF). In addition, the concentrations of siderophile elements Ni, Cr, and Co were determined by ICP-MS after acid digestion. The samples collected at the contact between suevite and the sedimentary infill yielded the highest PGE concentrations (Ir = 1.926 ng/g, Ru = 3.494 ng/g, Pt = 4.716 ng/g, Rh = 0.766 ng/g, Pd = 2.842 ng/g for GC6). The CI-normalized PGE patterns are characterized by Ru and Rh enrichments suggesting a non-chondritic impactor. Concentration plots of the different PGE display an excellent correlation (R > 0.99), indicative of a single source for the PGE enrichment. The Ni/Cr ratio of the Gardnos impactor (2.56 ± 0.20) agrees with that of chondrites (2 to 7), whereas Ir is depleted relative to Ni in this projectile (Ni/Ir ratio of 92 000 ± 8000 compared to an average Ni/Ir ratio of 23 150 ± 4250 for chondrites). There is no clear indication of selective post-depositional remobilization of the characteristic highly siderophile elements. The Ni/Ir and Cr/Ir data combined with the non-chondritic PGE ratios probably indicate a differentiated projectile. Based on (1) the similarity of the inter-element ratios of the impactor with the iron phase of non-magmatic iron meteorites and (2) the presence of characteristics of both chondrites and iron meteorites (Ni/Cr and Ni/Ir ratios), an IA or IIIC non-magmatic iron meteorite is a very plausible impactor.     

Solar Filaments and Photospheric Network

The locations of barbs of quiescent solar filaments are compared with the photospheric/chromospheric network, which thereby serves as a proxy of regions with enhanced concentrations of magnetic flux. The study covers quiet regions, where also the photospheric network as represented by flow converging regions, i.e., supergranular cell boundaries, contain largely weak magnetic fields. It is shown that close to 65% of the observed end points of barbs falls within the network boundaries. The remaining fraction points into the inner areas of the network cells. This confirms earlier findings (Lin et al., Solar Physics, 2004) that quiescent filaments are basically connected with weaker magnetic fields in the photosphere below.     

Quality of geological CO2 storage to avoid jeopardizing climate targets

We explore allowable leakage for carbon capture and geological storage to be consistent with maximum global warming targets of 2.5 and 3 °C by 2100. Given plausible fossil fuel use and carbon capture and storage scenarios, and based on modeling of time-dependent leakage of CO₂, we employ a climate model to calculate the long-term temperature response of CO₂ emissions. We assume that half of the stored CO₂ is permanently trapped by fast mechanisms. If 40?% of global CO₂ emissions are stored in the second half of this century, the temperature effect of escaped CO₂ is too small to compromise a 2.5 °C target. If 80?% of CO₂ is captured, escaped CO₂ must peak 300?years or later for consistency with this climate target. Due to much more CO₂ stored for the 3 than the 2.5 °C target, quality of storage becomes more important. Thus for the 3 °C target escaped CO₂ must peak 400?years or later in the 40?% scenario, and 3000?years or later in the 80?% scenario. Consequently CO₂ escaped from geological storage can compromise the less stringent 3 °C target in the long-run if most of global CO₂ emissions have been stored. If less CO₂ is stored only a very high escape scenario can compromise the more stringent 2.5 °C target. For the two remaining combinations of storage scenarios and climate targets, leakage must be high to compromise these climate targets.     

Gravity currents down canyons: effects of rotation

The flow of dense water in a V-shaped laboratory-scale canyon is investigated by using a non-hydrostatic numerical ocean model with focus on the effects of rotation. By using a high-resolution model, a more detailed analysis of plumes investigated in the laboratory (Deep-Sea Res I 55:1021–1034 2008) for laminar flow is facilitated. The inflow rates are also increased to investigate plume structure for higher Reynolds numbers. With rotation, the plumes will lean to the side of the canyon, and there will be cross-canyon geostrophic currents and Ekman transports. In the present study, it is found that the cross-canyon velocities are approximately 5 % of the down-canyon velocities over the main body of the plume for the rotational case. With rotation, the flow of dense water through the body of the plume and into the plume head is reduced. The plume head becomes less developed, and the speed of advance of the head is reduced. Fluid parcels near the top of the plume will to a larger extent be left behind the faster flowing dense core of the plume in a rotating system. Near the top of the plume, the cross-canyon velocities change direction. Inside the plume, the cross-flow is up the side of the canyon, and above the interface to the ambient there is a compensating cross-flow down the side of the canyon. This means that parcels of fluid around the interface become separated. Parcels of fluid around the interface with small down-canyon velocity components and relative large cross-canyon components will follow a long helix-like path down the canyon. It is found that the entrainment coefficients often are larger in the rotational experiments than in corresponding experiments without rotation. The effects of rotation and higher inflow rates on the areal patterns of entrainment velocities are demonstrated. In particular, there are bands of higher entrainment velocities along the lateral edges of the plumes in the rotational cases.     

Adaptation to climate change impacts on urban storm water: a case study in Arvika, Sweden

Already today, the functionality of many sewer and storm water systems are not up to the required standards and consequently flooding problems are experienced in case of heavy storms. System upgrades are required, which are however complicated by the expected future increase in short-term rainfall intensities as a result of climate change. In this case study, focusing on the town of Arvika, Sweden, this issue is investigated in three main steps. In the first, extreme value analyses of 30-min rainfall from an ensemble of climate projections are carried out to estimate the future increase and generate a future design storm. In the second, the existing system’s response to both today’s and future design storms are simulated by a coarse sewer model setup (MOUSE) and a detailed coupled surface-sewer model setup (TSR). In the third and final step, system upgrades are designed and evaluated by both models. The results indicate an increase by 10–30 % of today’s short-term rainfall extremes by the end of the century. Upgrading the system to achieve a satisfactory performance for the future design storm would cost approximately twice as much as an upgrade based on today’s design storm.     

Fluid–rock reactions in the 1.3 Ga siderite carbonatite of the Grønnedal–Íka alkaline complex,Southwest Greenland

Petrogenetic studies of carbonatites are challenging, because carbonatite mineral assemblages and mineral chemistry typically reflect both variable pressure–temperature conditions during crystallization and fluid–rock interaction caused by magmatic–hydrothermal fluids. However, this complexity results in recognizable alteration textures and trace-element signatures in the mineral archive that can be used to reconstruct the magmatic evolution and fluid–rock interaction history of carbonatites. We present new LA–ICP–MS trace-element data for magnetite, calcite, siderite, and ankerite–dolomite–kutnohorite from the iron-rich carbonatites of the 1.3 Ga Grønnedal–Íka alkaline complex, Southwest Greenland. We use these data, in combination with detailed cathodoluminescence imaging, to identify magmatic and secondary geochemical fingerprints preserved in these minerals. The chemical and textural gradients show that a 55 m-thick basaltic dike that crosscuts the carbonatite intrusion has acted as the pathway for hydrothermal fluids enriched in F and CO₂, which have caused mobilization of the LREEs, Nb, Ta, Ba, Sr, Mn, and P. These fluids reacted with and altered the composition of the surrounding carbonatites up to a distance of 40 m from the dike contact and caused formation of magnetite through oxidation of siderite. Our results can be used for discrimination between primary magmatic minerals and later alteration-related assemblages in carbonatites in general, which can lead to a better understanding of how these rare rocks are formed. Our data provide evidence that siderite-bearing ferrocarbonatites can form during late stages of calciocarbonatitic magma evolution.     

Benthic Phosphorus Dynamics in the Gulf of Finland, Baltic Sea

Benthic fluxes of soluble reactive phosphorus (SRP) and dissolved inorganic carbon (DIC) were measured in situ using autonomous landers in the Gulf of Finland in the Baltic Sea, on four expeditions between 2002 and 2005. These measurements together with model estimates of bottom water oxygen conditions were used to compute the magnitude of the yearly integrated benthic SRP flux (also called internal phosphorus load). The yearly integrated benthic SRP flux was found to be almost 10 times larger than the external (river and land sources) phosphorus load. The average SRP flux was 1.25?±?0.56?mmol?m^?2?d^?1 on anoxic bottoms, and ?0.01?±?0.08?mmol?m^?2?d^?1 on oxic bottoms. The bottom water oxygen conditions determined whether the SRP flux was in a high or low regime, and degradation of organic matter (as estimated from benthic DIC fluxes) correlated positively with SRP fluxes on anoxic bottoms. From this correlation, we estimated a potential increase in phosphorus flux of 0.69?±?0.26?mmol?m^?2?d^?1 from presently oxic bottoms, if they would turn anoxic. An almost full annual data set of in situ bottom water oxygen measurements showed high variability of oxygen concentration. Because of this, an estimate of the time which the sediments were exposed to oxygenated overlying bottom water was computed using a coupled thermohydrodynamic ocean?Csea and ecosystem model. Total phosphorus burial rates were calculated from vertical profiles of total phosphorus in sediment and sediment accumulation rates. Recycling and burial efficiencies for phosphorus of 97 and 3%, respectively, were estimated for anoxic accumulation bottoms from a benthic mass balance, which was based on the measured effluxes and burial rates.     

Water-level variations in Lake Nhauhache, Mozambique, during the last 2,300?years

Stratigraphic variations in diatom composition and phytolith abundance in a sediment core from a small, hydrologically isolated waterbody, Lake Nhauhache, Mozambique, provide evidence of water-level fluctuations over the past ~2,300?years. Ten AMS radiocarbon dates on bulk sediment samples show that the lake came into existence about 2,300?years ago and that it has dried out since then, but only for brief time periods. Changes in the diatom assemblage composition indicate that lake level fluctuated in response to shifting humidity conditions. The changes reflect wetter conditions ca. 300 BC?CAD 800, more variable conditions between AD 800 and 1150, a distinct dry phase within the time span AD 1150?C1700 and a return thereafter to more humid conditions until present. There is general agreement between the Lake Nhauhache record and other records from the Southern Hemisphere summer rainfall region. This suggests that sediments from small interdunal lakes, which are abundant along the coast of southern Africa, provide reliable, regional paleoenvironmental information about an area from which more such data are needed.     

Social–ecological traps and transformations in dryland agro-ecosystems: Using water system innovations to change the trajectory of development

Recent efforts to achieve a much needed productivity increase in farming systems across semi-arid and dry sub-humid sub-Saharan Africa have highlighted the potential of small-scale water system innovations (SWSIs). This paper takes a social–ecological resilience approach to investigate how this type of water management technology would influence agro-ecosystem dynamics, using a catchment in northeastern Tanzania as an example. The analysis finds that three external drivers (increasing dryspell frequency, population growth, and institutional changes) have interacted with a set of key variables in the studied system to shape a development trajectory over the past half-century where off-farm ecosystem services are being degraded while agricultural yields remain low and people remain poor. The analysis further finds that the evaluated SWSIs have the potential to destabilize feedbacks maintaining this social–ecological trap through several different mechanisms, and thereby open up for new development trajectories. A concluding discussion identifies a number of challenges to this type of transformation in sub-Saharan Africa, and outlines the type of investment approaches that would be needed to go from potential to reality.     

Effects of resuspension on benthic fluxes of oxygen,nutrients, dissolved inorganic carbon,iron and manganese in the Gulf of Finland,Baltic Sea

The effect of resuspension on benthic fluxes of oxygen (O₂), ammonium (NH₄⁺), nitrate (NO₃^?), phosphate (PO₄^3?), silicate (Si(OH)₄), dissolved inorganic carbon (DIC), total dissolved iron (Fe) and total dissolved manganese (Mn) was studied at three different stations in the Gulf of Finland (GoF), Baltic Sea during three cruises in June–July 2003, September 2004 and May 2005. The stations were situated on different bottom types in the western, central and eastern part, respectively, of the open GoF. The fluxes were measured in-situ using the autonomous Göteborg benthic lander. To simulate resuspension events, the stirring speed was increased in two of the four chambers of the lander after approximately half of the incubation time. The other two chambers were used as control chambers. Clear effects of resuspension were observed on the oxygen fluxes where an increase of the consumption was observed in 88% of the cases and on average with 59% (stdev=53). The NH₄⁺ fluxes were affected in 50% of the cases (4 out of 8 incubations) at stations with low bottom water oxygen concentrations, but in no cases where the bottom water was oxygenated (0 out of 9 incubations). The NH₄⁺ fluxes decreased by 26±27% in 2005 and by 114±19% in 2003. There was no clear effect of resuspension on the fluxes of any of the other solutes in this study. Thus, resuspension events did not play a significant role in release/uptake of NO₃^?, PO₄^3?, Si(OH)₄, DIC, Fe and Mn in GoF sediments. However, increased oxygen consumption as a result of resuspension may lead to spreading of anoxic/suboxic bottom water conditions, and thus indirectly to increased benthic release of phosphate, ammonium and iron.