The ionization balance of the Fe in the solar corona for a non-Maxwellian electron distribution function

The ionization equilibrium of the Fe in the solar corona for a non-Maxwellian electron distribution with an enhanced number of particles in the high-energy tail is presented. A parametric form of the distribution function is used to demonstrate the changes in the ionization equilibrium with changes in the shape of the distribution. The results over the range of temperature 10⁵ K T 10⁸ K for different deviations of the distribution from a Maxwellian are given in tabular form. The results can be used for specific applications in the solar corona, especially in the active corona, where deviations from the Maxwellian distribution can be significant.     

Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.     

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

Interglacial History of a Palaeo-lake and Regional Environment: A Multi-proxy Study of a Permafrost Deposit from Bol’shoy Lyakhovsky Island, Arctic Siberia

Chironomid, pollen, and rhizopod records from a permafrost sequence at Bol’shoy Lyakhovsky Island (New Siberian Archipelago) document the development of a thermokarst palaeo-lake and environmental conditions in the region during the last Interglacial (MIS 5e). Open Poaceae and Artemisia associations dominated vegetation at the beginning of the interglacial period. Rare shrub thickets (Salix, Betula nana, Alnus fruticosa) grew in more protected and wetter places as well. Saalian ice wedges started to melt during this time, resulting in the formation of an initial thermokarst water body. The high percentage of semi-aquatic chironomids suggests that a peatland-pool initially existed at the site. A distinct decrease in semi-aquatic chironomid taxa and an increase in lacustrine ones point to a gradual pooling of water in the basin, which could in turn induce thermokarst and create a permanent pond during the subsequent period. The highest relative abundance of Chironomus and Procladius reflects unfrozen water remaining under the ice throughout the ice-covered period during the later stage of palaeo-lake development. The chironomid record points to three successive stages during the history of the lake: (1) a peatland pool; (2) a pond (i.e., shallower than the maximum ice-cover thickness); and (3) a shallow lake (i.e., deeper than the maximum ice-cover thickness). The trend of palaeo-lake development indicates that intensive thermokarst processes occurred in the region during the last Interglacial. Shrub tundra communities with Alnus fruticosa and Betula nana dominated the vegetation during the interglacial optimum. The climate was moister and warmer than present. The results of this study suggest that quantitative chironomid-based temperature reconstructions from Arctic thermokarst ponds/lakes may be problematic due to other key environmental factors, such as prolonged periods of winter anoxia and local hydrological/geomorphological processes, controlling the chironomid assemblages.     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

新时期我国区域经济地理学发展问题初探

我国新时期的区域经济地理学在取得全面发展的同时，在理论体系，研究方法和实践领域等方面还需要进一步的发展，文章根据学习和实践区域经济地理学的体会，初步提出基础理论和应用理论，思维方法和技术方法等方面发展见解，并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域，最后提出我国区域经济地理学科发展的建议。     

华南地区凉果加工业与凉果资源的匹配关系分析——以广东省新兴县为例

文章以广东省新兴县为例，从凉果资源分布与加工能力的匹配关系角度对华南地区凉果资源的分布，凉果加工业的分布与布局，凉果市场分布与竞争力，凉果加工业与资源的匹配关系等进行了分析，并针对华南地区凉果加工业面临的主要问题提供了一些建议。     

成都市民消费结构与休闲活动关系研究

城市居民消费水平，消费结构会影响其休闲消费能力，消费意愿，消费方式，消费态度和休闲时空结构，文章以成都市7个城区歌舞，茶棋牌，电影及城市公园休闲活动调查为基础，探讨了城市居民消费结构及其变化与休闲活动特征的关系。研究结果表明，城市居民消费结构的改变对歌舞，茶棋牌娱乐活动影响最大。