Biogeochemical Stratification and Carbonate Dissolution-Precipitation in Hypersaline Microbial Mats (Salt Pond, San Salvador, The Bahamas)

Microbial mat communities host complex biogeochemical processes and play a role in the formation of most carbonate rocks by influencing both carbonate precipitation and dissolution. In this study, the biogeochemistry of microbial mats from the hypersaline Salt Pond, San Salvador, Bahamas are described using scanning electron microscopy, X-ray diffraction, microelectrode profiling, fatty acid methyl esters, and carbon and nitrogen analyses. These microbial mats are distinctly layered both chemically and with regard to composition of microbial community, where significant (?? < 0.05) differences are noted between layers and cores. Furthermore, an oxic upper zone and an H₂S-rich lower zone dominate the Salt Pond microbial mats, where H₂S concentrations were measured approaching 8 mM. The high H₂S concentrations along with the lacking evidence of mineral precipitation in SEM images point to the prevalence of carbonate dissolution. Moreover, the high concentrations of organics (3?C9%) reveal that the mats are self-sourcing and can provide ample fuel to sustain the highly active heterotrophic (both aerobic and anaerobic) metabolism. Seasonal differences in sulfide and oxygen concentrations in Salt Pond mats indicate that the carbonate dissolution and precipitation reactions are dynamic in this hypersaline lake.     

Acid saline lake systems give clues about past environments and the search for life on Mars

Acid saline lake systems in Western Australia may be the best known modern terrestrial analog for the Burns formation on Mars and, thus, provide information about past environments and life on Mars.     

Second-Hand Spaces: Restructuring Retail Geographies in an Era of E-Commerce

Are online markets replacing or remaking second-hand markets in cities? The restructuring of secondary markets in light of virtual outlets like eBay is not well understood. In this article, we describe secondary markets and their important historic, economic, cultural, and social roles in cities. The literature on e-Commerce suggests that virtual retailers compete with bricks-and-mortar stores and potentially displace them. We question whether the internet can substitute for second-hand stores, which have traditionally relied on a loyal and local customer base, personalized shopping experiences, and surprise encounters. Given the historically embedded nature of exchange, we focus on one large Mid-western city, drawing upon survey and interview data from Chicago retailers. Our exploration of supply, demand, and geographic practices reveals subtle and complex alterations in second-hand exchange, rather than a displacement of second-hand markets by eBay. We also find substantive integration, fluidity, and hybridization within and across market sectors. Rather than supplant the production of new goods, secondary markets are intertwined with and deepen primary markets, calling into question some of the presumed benefits of and meanings associated with second-hand exchange as well as the usefulness of categorical distinctions. [Key words: secondary markets, second-hand, resale, thrift, e-commerce, eBay.]     

Mississippi prodelta crusts: A clay fabric and geotechnical analysis

Abstract

"Crust”; zones, as defined by shear strength profiles, have been delineated in Mississippi prodelta sediments since the advent of the remote wire‐line probe. Attempts to map the distribution of the “crust”; on the prodelta have been hampered by sparsity of in situ measurements and its apparent lateral discontinuity. Evidence based on clay fabric, geotechnical properties, and the location of selected cores within certain geomorphic zones, suggests the “crusts”; are associated with zones of shearing during an episode of submarine sediment movement on the prodelta.

The clay fabric within the “crust”; zone differs from that found above and below in the high‐porosity sediments. A noticeable degree of clay platelet preferential alignment is characteristic of sediments within the “crust.”; This preferred orientation occurs as localizations rather than as an overall alignment of all the particles. The clay fabric of the higher‐porosity sediments above and below the “crust”; is typified by randomly arranged clay particles and domains, sharing edge‐to‐face contacts which create an open framework. Apparent increases in the coarse silt fraction in the “crust”; zone were observed initially in scanning electron and transmission electron micrographs and later confirmed by grain size analysis. The presence of this silt apparently contributes to the increase in shear strength within the “crust.”; Clay particle arrangement in close proximity to these larger grains is modified in such a manner as to reduce water contents. Transmission electron microscopy and scanning electron microscopy observations of the “crust”; reveal that the void ratio decreases, resulting in a concomitant reduction in the water content as reflected in the geotechnical properties profiles. The type of fabric exhibited by the “crust”; suggests a remolding and dewatering of initially porous silty clay sediments in response to shear stresses operating on the prodelta.

Core samples were recovered from sediments exhibiting a “crust”; in areas identified by other researchers as unstable, based on seismic and acoustic profiles and sidescan sonar records. The prodelta has been modified by a peripheral mudflow at the location where the cores were collected for this study.     

New Zealand’s National Landslide Database

A New Zealand Landslide Database has been developed to hold all of New Zealand’s landslide data and provide factual data for use in landslide hazard and risk assessment, including a probabilistic landslide hazard model for New Zealand, which is currently being developed by GNS Science. Design of a national Landslide Database for New Zealand required consideration of existing landslide data stored in a variety of digital formats and future data yet to be collected. Pre-existing landslide datasets were developed and populated with data reflecting the needs of the landslide or hazard project, and the database structures of the time. Bringing these data into a single database required a new structure capable of containing landslide information at a variety of scales and accuracy, with many different attributes. A unified data model was developed to enable the landslide database to be a repository for New Zealand landslides, irrespective of scale and method of capture. Along with landslide locations, the database may contain information on the timing of landslide events, the type of landslide, the triggering event, volume and area data, and impacts (consequences) for each landslide when this information is available. Information from contributing datasets include a variety of sources including aerial photograph interpretation, field reconnaissance and media accounts. There are currently 22,575 landslide records in the database that include point locations, polygons of landslide source and deposit areas, and linear landslide features. Access to all landslide data is provided with a web application accessible via the Internet. This web application has been developed in-house and is based on open-source software such as the underlying relational database (PostGIS) and the map generating Web Map Server (GeoServer). Future work is to develop automated data-upload routines and mobile applications to allow people to report landslides, adopting a consistent framework.     

EGRET observations of > 30 MeV emission from the brightest bursts detected by BATSE

EGRET on the Compton Gamma Ray Observatory has detected 5 gammaray bursts above 30 MeV. The sub-MeV emission, as detected by BATSE, for these 5 bursts has the largest fluence,F, and peak intensity,I, of any of the BATSE detected bursts within the EGRET field of view. The BATSE data reported in the 2B catalog and the EGRET exposure,E, are combined to select additional bursts with largeF ×E andI ×E. The EGRET data for these bright BATSE bursts are searched for prompt, as well as delayed, emission above 30 MeV. The average properties of the >30 MeV emission are obtained by adding the EGRET data from the 5 bursts. On average the fluence is greater than 15% of the fluence detected by BATSE below an MeV, and the average spectrum is flatter than the spectrum from 1-30 MeV.     

Patterns of trace element partitioning

When a phenocryst and its lava matrix have been analysed for both major and trace elements, plots of partition coefficient (mineral/matrix) against ionic radius give a family of sub-parallel curves, one univalent, one divalent, etc. Onuma et al. (1968) demonstrated this with two analyses and concluded, from the shape of these curves, that trace element partition between phenocryst and groundmass is determined primarily by crystal structure of the phenocryst. In this study, over 50 such analyses, taken from the literature, have been plotted on modified Onuma diagrams, in order to analyse the constant and variable factors in the curves. It is demonstrated that these curves can provide important additional information in trace element studies by revealing, for example, the site or sites in a mineral which a given element is occupying, the valency state of the element and even, in some cases, the proportion of different valency states present.     

Gendering transnational communities: a comparison of Singaporean and British migrants in China

Studies of transnational communities and transnational labour migration have focused almost exclusively on the movement of low-skilled and unskilled workers across international boundaries. While these groups may be numerically dominant, it must be recognised that there are increasing numbers of managers and professionals engaged in work-related migration in association with the intensification of economic globalisation processes. Work which has been conducted on highly skilled migrants has largely been limited to examinations of intra-firm mobility and the workspace. This approach fails to consider the ways in which the migrants' experiences are embedded in the social, economic and political practices of the host country, but also in a specific household context. It is unsurprising, therefore, that the gendered dimensions of the life of these migrants and their accompanying family members has been somewhat under-researched.Flows of expatriates can lead to the constitution of both ‘communities of transnationals', as particular cities become foci of the activities of the ‘transnational capitalist class', as well as ‘transnational communities' which involve regular and sustained contact between individuals across national boundaries. In this paper we examine these social formations using two groups of migrants––British and Singaporean migrants to China (both mainland China and the Hong Kong SAR). We focus on the gender characteristics of these groupings, but also the gender division of labour in the creation and maintenance of these ‘communities'. The paper is based on qualitative research carried out in China, Singapore and the UK 1997–2001.     

Ba, Ra, Th, and U in marine mollusc shells and the potential of Ra/Ba dating of Holocene marine carbonate shells

The geochemistry of Ba, Ra, Th, and U and the potential of using ²²⁶Ra/Ba ratios as an alternative dating method are explored in modern and Holocene marine mollusc shells. Five modern shells of the Antarctic scallop Adamussium colbecki collected from the present day beach and six radiocarbon dated specimens from Holocene beach terraces of the Ross Sea region (Antarctic) between 700 and 6100 calibrated yr BP old have been analysed by mass spectrometry. In clean shells ²²⁶Ra concentrations and ²²⁶Ra/Ba ratios show a clear decrease with increasing age, suggesting the possibility of ²²⁶Ra dating. Limiting factors for such dating are Ba and ²²⁶Ra present in surface contaminants, and ingrowth of ²²⁶Ra from U present within the shell. Surface contamination is difficult to clean off entirely, but moderate levels of residual contamination can be corrected using ²³²Th. Sub-samples from the same shell with different proportions of contamination form a mixing line in a ²²⁶Ra/Ba-²³²Th/Ba graph, and the ²²⁶Ra/Ba of the pure shell can be derived from the intercept on the ²²⁶Ra/Ba axis. Contaminant corrected ²²⁶Ra/Ba ratios of late-Holocene ¹⁴C-dated samples fall close to that expected from simple ²²⁶Ra excess decay from seawater ²²⁶Ra/Ba values. ²²⁶Ra ingrowth from U incorporated into the shell during the lifetime of the mollusc can be corrected for. However, the unknown timing of post mortem U uptake into the shell makes a correction for ²²⁶Ra ingrowth from secondary U difficult to achieve. In the A. colbecki shells, ²²⁶Ra ingrowth from such secondary U becomes significant only when ages exceed ∼2500 yr. In younger shells, ²²⁶Ra/Ba ratios corrected for surface contamination provide chronological information. If evidence for a constant oceanic relationship between ²²⁶Ra and Ba in the ocean can be confirmed for that time scale, the ²²⁶Ra/Ba chronometer may enable the reconstruction of variability in sea surface ¹⁴C reservoir ages from mollusc shells and allow its use as a paleoceanographic tracer.