Wind-driven diversion of summer river runoff preconditions the Laptev Sea coastal polynya hydrography: Evidence from summer-to-winter hydrographic records of 2007–2009

This paper examines the role of atmospheric forcing in modifying the pathways of riverine water on the Laptev Sea shelf, using summer-to-winter hydrographic surveys from 2007 to 2009. Over the two consecutive winter seasons of 2007–2008 and 2008–2009 in the area of the winter coastal polynya, our data clearly link winter surface salinity fields to the previous summer conditions, with substantially different winter salinity patterns preconditioned by summer atmospheric forcing. In the summer of 2007, dominant along-shore westerly winds in the cyclonic regime force the Lena River runoff to flow eastward. In contrast, in the summer of 2008, dominant along-shore easterly winds over the East Siberian Sea and on-shore northerly winds over the Laptev Sea in the anticyclonic regime lock the riverine water in the vicinity of the Lena Delta. Over the coastal polynya area in the southeastern Laptev Sea these patterns precondition a surface salinity difference of 8–16 psu between the winters of 2008 and 2009. Overall, this indicates a residence time of at least half a year for riverine water on the Laptev Sea shelf. Future climate change associated with an enhanced summer cyclonicity over the eastern Arctic may turn more riverine water eastward along the eastern Siberian coast, resulting in weaker vertical density stratification over the Laptev Sea shelf, with possible impact on the efficiency of vertical mixing and polynya dense water production.     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.     

Drinking water production from surface water sources in the tropics: Brasília DF,Brazil

Drinking water production at three waterworks was evaluated with respect to variable weather conditions in the Brasília Distrito Federal. Results of the investigation revealed that seasonal variations in rainfall play an important role in influencing the quality of the surface water sources used for drinking water production in the district. In most surface sources, particles and apparent colour are likely to originate from erosion during rain events. This represents the primary challenge facing waterworks, notably when the raw water qualities of the sources to be treated at one facility differ by one order of magnitude, as well significantly varying from one season to the next. Treatment efficiencies in terms of turbidity, apparent colour and dissolved organic carbon (DOC) removal were evaluated. Drinking water quality was found to be significantly influenced by raw water quality at all considered treatment plants. With regard to DOC removal, treatment was most efficient in waterworks which treated raw water with high percentages of biopolymers and humics. Most dissolved organics were removed by coagulation. Finally, conclusions are drawn on how to better cope with challenges facing drinking water production in a tropical climate. The first of these recommendations is the introduction of online turbidity and dissolved organic matter monitoring in order to optimise the coagulation process for the removal of these two parameters. A combination of different coagulants could also be considered for this process. Additional more sophisticated improvements to process stability, such as determination of floc characteristics, introduction of artificial neural networks or the eventual upgrade of the treatment train using membrane filtration, are also suggested.     

Campanian Climatic Change: Isotopic Evidence from Far East, North America, North Atlantic and Western Europe

Paleoclimatic settings have been reconstructed for the Campanian using original oxygen-isotopic analyses of well-preserved molluskan and foraminifera shells from Russian Far East, Hokkaido, USA, Belgium and some DSDP holes (95, 98, 102, 390A, and 392A) in North Atlantic. Early Early Campanian climatic optimum has been recognized from data on high bottom shelf water paleotemperatures in middle latitudes of both the western circum-Pacific (to 24.2°C) and the eastern circum-Pacific (to 26.4°C) areas and high bottom shallow water paleotemperatures in high latitudes of the Koryak Upland (22.4–25.5°C), which agrees with the data on the Campanian Barykovskaya flora in high latitudes (Golovneva and Herman, 1998) and Jonker flora and its equivalents in middle latitudes. Judging from the data on comparatively high bottom shallow water paleotemperature values in high latitudes, South Alaska (19.4°C) and the Koryak Upland (22.4–25.5°C), we also expect Latest Campanian temperature maximum, which has not been confirmed, however, for low and middle latitudes by neither of isotopic nor paleobotanic data now. Main climatic tendency during the Campanian (with the exception of Latest Campanian) has been learned from isotopic composition of Campanian aragonitic ammonoid shells from the Hokkaido-South Sakhalin (Krilyon) marine basin. In contrary to Huber’s et al. (2002) assumption, we expect warm greenhouse conditions during the most part of the Campanian.     

Chromium solubility in anhydrous Phase B

The crystal structure and chemical composition of a crystal of (Mg_14?x Cr _x )(Si_5?x Cr _x )O₂₄ (x ≈ 0.30) anhydrous Phase B (Anh-B) synthesized in the model system MgCr₂O₄–Mg₂SiO₄ at 12 GPa and 1600 °C have been investigated. The compound was found to be orthorhombic, space group Pmcb, with lattice parameters a = 5.900(1), b = 14.218(2), c = 10.029(2) Å, V = 841.3(2) Å³ and Z = 2. The structure was refined to R ₁ = 0.065 using 1492 independent reflections. Chromium was found to substitute for both Mg at the M3 site (with a mean bond distance of 2.145 Å) and Si at the octahedral Si1 site (mean bond distance: 1.856 Å), according to the reaction Mg²⁺ + Si⁴⁺ = 2Cr³⁺. Such substitutions cause a reduction in the volume of the M3 site and an increase in the volume of the Si-dominant octahedron with respect to the values typically observed for pure Anh-B and Fe²⁺-bearing Anh-B. Taking into account that Cr³⁺ is not expected to be Jahn–Teller active, it appears that both the Cr³⁺–for–Mg and Cr³⁺–for–Si substitutions in the Anh-B structure decrease the distortion of the octahedra. Electron microprobe analysis gave the Mg_13.66(8)Si_4.70(6)Cr_0.62(4)O₂₄ stoichiometry for the studied phase. The successful synthesis of this phase provides new information for the possible mineral assemblages occurring in the Earth’s deep upper mantle and shed new light on the so-called X discontinuity that has been observed at 275–345 km depth in several subcontinental and subduction zone environments.     

On the application of a turbulence closure modified model to the description of the density jump evolution in a stably stratified medium

The self-similar turbulent density jump evolution has been studied in the scope of a turbulence closure modernized theory which takes into account the anisotropy and mutual transformation of the turbulent fluctuation kinetic and potential energy for a stably stratified fluid. The numerical calculation, performed using the equations for the average density and kinetic and potential energies of turbulent fluctuations, indicates that the vertical profiles of the buoyancy frequency, turbulence scale, and kinetic and potential energies drastically change when the turbulence anisotropy is strong. The vertical profiles of the corresponding energy and spatial discontinuity parameters, calculated at a weaker anisotropy, indicate that similar drastic changes are absent and a qualitative agreement exists with the known analytical solution, which describes the density jump evolution in a freshwater basin and was obtained previously [5, 8] in the scope of a turbulence local-similarity hypothesis applied in combination with the budget equation for the turbulent fluctuation kinetic energy.     

Ostracod palaeoecology and environmental change in the Laptev and Kara seas (Siberian Arctic) during the last 18 000 years

Fossil ostracod assemblages were investigated in five AMS ¹⁴ C‐dated cores from various water depths of the Laptev and Kara seas ranging from the upper continental slope (270 m) to the present‐day shelf depth (40 m). Six fossil assemblages were distinguished. These represent the varying environmental conditions at the North Siberian continental margin since about 18 ka. In the cores from the shelf the ostracod assemblages reflect the gradual transition from an estuarine brackish‐water environment to modern marine conditions since 12.3 ka, as induced by the regional early Holocene transgression. The core from the upper continental slope dates back to c. 17.6 ka and contains assemblages that are absent in the shelf cores. The assemblage older than 10 ka stands out as a specific community dominated by relatively deep‐water Arctic and North Atlantic species that also contains euryhaline species. Such an assemblage provides evidence for past inflows of Atlantic‐derived waters from as early as c. 17.2 ka, probably facilitated by upwelling in coastal polynyas, and a considerable riverine freshwater influence with enhanced surface water stratification owing to the proximity of the palaeocoastline until early Holocene times. In all studied cores, relative increases in euryhaline species dominant in the inner‐shelf regions are recorded in the mid–late Holocene sediments (<7 ka), which otherwise already contain modern‐like ostracod assemblages with relatively deep‐water species. This observation suggests euryhaline species to be largely sea‐ice‐ and/or iceberg‐rafted and therefore may provide evidence for a climate cooling trend.