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81.
E. S. Bazilevskaya 《Geology of Ore Deposits》2006,48(2):134-143
The current concepts of two competing sources of manganese deposited as oceanic Fe-Mn ore are reviewed and assessed critically. A new solution of this problem proposed in this paper is a further development of fundamental works by N.M. Strakhov in the light of new facts and with allowance for geological, geochemical, and geohistorical data. It has been concluded that terrigenous material removed from land serves as a main source of manganese fixed in oceanic Fe-Mn ore. The history of sedimentation and nodule formation in the World Ocean lasted for more than two billion years. Manganese has been supplied to recent bottom sediments from both present-day and older sources. The closed geochemical cycle of Mn circulation in the ocean is intimately related to its circulation in the hydrosphere. Seawater is oversaturated with Mn and serves as its immediate source for ore deposition and elevated concentrations in bottom sediments affected by hydrothermal solutions or other manifestations of endogenic activity. Seawater is a repository for Mn, where this element is retained during global cataclysms, which have repeatedly occurred in geological history. 相似文献
82.
Ekaterina Kaneva Maria Lacalamita Ernesto Mesto Emanuela Schingaro Fernando Scordari Nikolay Vladykin 《Physics and Chemistry of Minerals》2014,41(1):49-63
The structure, structural disorder and chemistry of miserite from the charoite-bearing rocks of the Murun massif (Russia) and from alkaline-syenite pegmatitic rocks of the Dara-i-Pioz massif (Tajikistan) were investigated employing a combination of electron microprobe, single crystal diffraction and micro-Fourier transform infrared spectroscopy analysis. Chemical analysis of the sample investigated by X-ray diffraction evidenced that Dara-i-Pioz miserite has a greater REE concentration than Murun miserite (~0.22 vs. 0.05 apfu, respectively) and also contains Y (0.14 apfu), which is absent in Murun miserite. The occurrence of a band at about 1,600 cm?1 testified to the presence of H2O in miserite at hand. Structural analyses yielded average cell parameters of a = 10.092, b = 16.016, c = 7.356 Å, α = 96.60°, β = 111.27° and γ = 76.34°. Anisotropic structural refinement in space group P $\bar{1}$ converged at similar values for the analyzed samples (R ~3.4, R w ~3.8 %). An interesting feature shown by both the miserite specimen is the presence, revealed by difference Fourier analysis, of a disordered part of the structure. This turned out to be due to the flipping of the tetrahedra belonging to the isolated [Si2O7]6? diorthogroups, one of the two radicals (the other is [Si12O30]12?) characterizing the miserite structure. The sixfold and seven-vertex Ca polyhedra linked to the inverted diorthogroups show variation in coordination number with respect to those of the ordered structure. 相似文献
83.
Brian L. Morris W. George Darling Daren C. Gooddy Rafael G. Litvak Ilka Neumann Ekaterina J. Nemaltseva Inna Poddubnaia 《Hydrogeology Journal》2006,14(1-2):225-243
A groundwater residence time study of the deep fluvioglacial aquifer supplying Bishkek, capital of Kyrgyzstan, has found evidence of deep infiltration of recent recharge both in the main periurban wellfield and below the city. Commonly-employed hydrochemical markers detected urban influence in the city-centre to depths of 65–100 m, but gave no indication of the important role of induced river/canal bed leakage, either upgradient in the periurban wellfield or within the city. This was revealed by O and H stable isotope measurements, which showed that local rainfall/snowfall play little part in the aquifer water balance. More remarkably, the universal detection of CFCs and SF6, including in boreholes with 140–220 m deep upper screens, demonstrated that induced leakage of water just a few decades old had penetrated much deeper into the aquifer system than other hydrochemical markers indicated. A two-dimensional flow model set up to test whether such deep pumping-induced leakage could occur below the periurban wellfield confirmed its feasibility. The results imply vertical infiltration rates of 5–10 m/year and demonstrate that in this not-uncommon intergranular aquifer setting, deep boreholes with deep screen settings do not necessarily abstract old water. Hence, there are major implications for urban groundwater management and protection in such settings.
Resumen Un estudio sobre el tiempo de residencia del agua subterránea, en un acuífero fluvioglacial profundo que abastece a Bishkek, capital de Kyrgyzstan, ha encontrado evidencias de infiltración profunda a partir de recarga reciente, tanto en el campo de pozos de las afueras de la ciudad, como también por debajo de la ciudad. Los indicadores hidroquímicos comúnmente usados, detectaron influencia urbana en el centro de la ciudad hasta profundidades de 65–100 m, pero no dieron indicación del papel importante del goteo inducido en el lecho del canal/río, tanto aguas arriba en el campo de pozos de los suburbios, como también dentro de la ciudad. Esto se reveló mediante mediciones de isótopos estables de O y H, las cuales mostraron que las precipitaciones/nevadas de tipo local, tienen una pequeña contribución en el balance de agua del acuífero. De manera más notoria, la detección universal de CFCs y SF6, incluidos en las rejillas superiores de pozos profundos con 140–220 m de profundidad, demostraron que un goteo inducido de agua, de solo unas pocas décadas de antigüedad, ha penetrado mucho más profundo dentro del sistema acuífero, de lo que los otros marcadores hidroquímicos indicaban. Un modelo bidimensional de flujo, realizado para probar si el goteo inducido—bombeo profundo podía suceder debajo del campo de pozos suburbano, confirmó su factibilidad. Los resultados implican tasas de infiltración vertical de 5 a 10 m/año, y demuestran que los pozos profundos con tramos de rejilla también profundos, no necesariamente extraen aguas antiguas, en estos ambientes acuíferos con porosidad intergranular. Por lo tanto, hay implicaciones importantes para la gestión y protección en zonas urbanas, y para esos ambientes de las aguas subterráneas.
Résumé Lanalyse du temps de résidence des eaux souterraines dans un aquifère fluvial profond, dorigine glaciaire, qui alimente en eau Bishek, la capitale de Kyrgyzstan a mis en évidence une recharge récente tant dans le captage en eau que sous la ville même. Les traceurs chimiques ont indiqué linfluence urbaine dans le centre de la ville, à une profondeur de 65–100 m, mais ils nont pas mis en évidence le rôle important de lalimentation induite par la couche du fleuve, tant en amont, dans le captage que en aval, dans la ville. Ces effets ont été relevés par des isotopes stables, comme O et h qui ont montré linfluence récente des précipitations dans le bilan hydrique de laquifère. De plus, la détection universelle de CFC et de SF6, y compris dans les forages ayant une profondeur de 140–220 m, montre que lalimentation en eau induite de plusieurs décennies a pénétré à des profondeurs plus grandes que celles indiqués par des traceurs chimiques. Les possibilités dune drainance verticale induite par les pompages dans le puits profonds du captage ont été vérifiées par un modèle bidimensionnel découlement. Les résultats de la modélisation ont conduit à une infiltration verticale de 5–10 m/an et ont démontré aussi que leau extraite par des puits profonds dans un aquifère granulaire nest pas nécessairement dage ancienne. Il sagit donc des implications majeures concernant la gestion et la protection des captages urbaines en eaux souterraines相似文献
84.
Gaskova Olga L. Strakhovenko Vera D. Ermolaeva Nadezhda I. Zarubina Eugene Yu. Ovdina Ekaterina A. 《中国海洋湖沼学报》2017,35(4):956-966
The Kambala and Barchin brackish lakes(Baraba steppe,southern West Siberia) contain an organic-rich sapropel layer that was formed in oxygen-depleted waters.We measured the bulk sediment elemental composition,the water chemistry and determined the mineralogical composition and predominant biota species(Diatoms and Cyanobacteria in phytoplankton community respectively) in the lakes.The result indicates that the first lake has a siliceous type of sapropel and the second a carbonaceous one.A computer thermodynamic model was developed for chemical interaction in water-bottom sediment systems of the Kambala and Barchin Lakes.The surface sodium bicarbonate waters are supersaturated with respect to calcite,magnesite(or low Mg-calcite),quartz and chlorite with minor strontianite,apatite and goethite(pH8.9-9.3,Eh 0.3 V).Nevertheless,it is shown that during sapropel deposition,deep silt waters should be anoxic(Eh0 V).The virtual component CH_2O has been used to create an anoxic environment suitable for pyrite formation due to the biotic community impact and abiotic reduction.Thermodynamic calculation has shown that silt water is not necessarily euxinic(anoxic and sulfidic).Depending on Eh,sulfate sulfur can dominate in solution,causing the formation of gypsum together with pyrite.An attempt was made to find a reason for solution supersaturation with respect to Ca and Mg ions due to their complexation with humic acids. 相似文献
85.