Pressure dependence of electrical conductivity of (Mg,Fe)SiO<Subscript>3</Subscript> ilmenite

The electrical conductivity of (Mg_0.93Fe_0.07)SiO₃ ilmenite was measured at temperatures of 500–1,200 K and pressures of 25–35 GPa in a Kawai-type multi-anvil apparatus equipped with sintered diamond anvils. In order to verify the reliability of this study, the electrical conductivity of (Mg_0.93Fe_0.07)SiO₃ perovskite was also measured at temperatures of 500–1,400 K and pressures of 30–35 GPa. The pressure calibration was carried out using in situ X-ray diffraction of MgO as pressure marker. The oxidation conditions of the samples were controlled by the Fe disk. The activation energy at zero pressure and activation volume for ilmenite are 0.82(6) eV and −1.5(2) cm³/mol, respectively. Those for perovskite were 0.5(1) eV and −0.4(4) cm³/mol, respectively, which are in agreement with the experimental results reported previously. It is concluded that ilmenite conductivity has a large pressure dependence in the investigated P–T range.     

Phytoremediation of shallow organically enriched marine sediments using benthic microalgae

We examined whether replantation of benthic microalgae (BMA) can remediate shallow organically enriched sediment. Nitzschia sp., the dominant species in the tested area (Hiroshima Bay, Japan), was isolated and mass cultured, then replanted in the same area. Changes in the condition of the sediment were monitored for five months. During the study period, we observed an increase in redox potential (ORP) and a decrease in acid-volatile sulfide (AVS) in the experimental area, indicating that the sediment condition changed from reduced to oxic. Organic matter in the sediment, represented by chemical oxygen demand (COD), ignition loss (IL) and organic nitrogen (ON) decreased significantly, while inorganic nutrients (ammonia and phosphate) increased in the interstitial water. These changes imply that oxygen produced by the replanted BMA may have enhanced aerobic bacterial activity, accelerating the decomposition of organic matter. Thus, replantation of BMA shows potential as a novel and promising "phytoremediation" method for organically enriched sediment.     

越南红河三角洲近五千年来的几个降温事件

根据对越南红河三角洲的2个钻孔的孢粉分析结果，结合沉积特征和高精度的AMS^14C测年数据，恢复了近五千年来百年一千年尺度的气候变化，发现了3个分别开始于4530cal．aBP，2100cal．aBP和620cal．aBP的明显降温事件，其中4530cal．aBP和620cal．aBP降温事件可与全球全新世气候变冷事件中的“新冰期(Neoglacial)”和“小冰期(Little Ice Age)”相对应，可能与由北大西洋地区几个短期变冷事件的全球气候响应机制有关。3340cal．aBP以来，人类干扰性植物成分的增加，表明人类活动对自然植被的影响改造作用增强，因此，本研究中气候的降温事件不排除人类影响的因素，仍需要进一步深入研究。     

Predicting forest fire in the Brazilian Amazon using MODIS imagery and artificial neural networks

The presented work describes a methodology that employs artificial neural networks (ANN) and multi-temporal imagery from the MODIS/Terra-Aqua sensors to detect areas of high risk of forest fire in the Brazilian Amazon. The hypothesis of this work is that due to characteristic land use and land cover change dynamics in the Amazon forest, forest areas likely to be burned can be separated from other land targets. A study case was carried out in three municipalities located in northern Mato Grosso State, Brazilian Amazon. Feedforward ANNs, with different architectures, were trained with a backpropagation algorithm, taking as inputs the NDVI values calculated from MODIS imagery acquired during five different periods preceding the 2005 fire season. Selected samples were extracted from areas where forest fires were detected in 2005 and from other non-burned forest and agricultural areas. These samples were used to train, validate and test the ANN. The results achieved a mean squared error of 0.07. In addition, the model was simulated for an entire municipality and its results were compared with hotspots detected by the MODIS sensor during the year. A histogram analysis showed that the spatial distribution of the areas with fire risk were consistent with the fire events observed from June to December 2005. The ANN model allowed a fast and relatively precise method to predict forest fire events in the studied area. Hence, it offers an excellent alternative for supporting forest fire prevention policies, and in assisting the assessment of burned areas, reducing the uncertainty involved in currently used methods.     

Landslide inventory using image fusion techniques in Brazil

The present work aims to assess the accuracy of six fusion techniques (Brovey, IHS, HSV, PCA, WTYO and WTVE) in order to compile landslide inventories using orbital images (ETM+ and PAN HRV). The study area is characterized by steep terrain and dense forest in Caraguatatuba, São Paulo State, Brazil. In terms of spatial quality, the Wavelet Transform technique provided the best results, presenting correlations above 90%. As for spectral quality, the best results were obtained with the IHS fusion. Based on the results, it may be concluded that the IHS is the best technique for preserving spatial and spectral information from the original images, so as to more clearly identify landslide scars. However, it was still not possible to typify the landslides from remote sensing data. Nonetheless, it is believed that image fusion techniques adequately met expectations in terms of their capacity to identify landslide for the creation of an inventory for the studied area.     

越南红河水下三角洲北区表层沉积物类型及分布特征初探

对2007年采自越南红河水下三角洲北区24个表层沉积物样品进行了粒度分析和粒度参数计算,初步探讨了该区沉积物的主要类型及分布特征。结果表明,越南红河水下三角洲北区的表层沉积物主要由粉砂组成(体积平均含量为54.35%),平均粒径为6φ。按Link沉积物命名法,该区沉积物主要类型有砂、砂质粉砂和黏土质粉砂。水平分布上,由西部的砂向东逐渐变为黏土质粉砂,呈现出由近岸三角洲前缘相的粗粒级沉积物逐渐向前三角洲-浅海相的细粒级沉积物变化的趋势。与前人研究成果对比发现,红河水下三角洲北区沉积物黏土的比例较1996年的比例明显增大,可能与海岸线近10a来总体上呈向陆迁移、水下三角洲沉积向岸蚀退以及纵向上水动力逐渐变弱有关。     

越南红河流域沉积物的镜下碳屑分析实验室处理方法对比研究

本文设计4个不同的实验方法,以越南红河流域原始森林区、河漫滩区和水下三角洲区3个不同沉积环境下的9个样品为实验对象,对镜下碳屑不同的实验室处理方法进行对比研究,实验发现样品用六偏磷酸钠分散法(方法A)和盐酸分散法(方法B)处理后,镜下碳屑形态不易分辨,杂质多,而用氢氟酸处理法(方法C)和附加醋酸酐混合液处理法(方法D),镜下碳屑的形态清晰,杂质少,碳屑数量容易统计,但是方法D中利用醋酸酐与浓硫酸混合液去纤维素与染色过程会使纤维素碳化,结果显示碳屑浓度明显比用前3种方法处理的浓度高。以上实验结果表明方法C是最优的。另外,本研究在进行碳屑统计时,利用NIS­Elements Br 3.0软件的自动统计计数功能,不仅可以减小人为计数产生的误差,还可以实现碳屑的多参数统计,有利于古环境、古气候、古植被变化的多信息解译。     

Majoritic garnet: A new approach to pressure estimation of shock events in meteorites and the encapsulation of sub-lithospheric inclusions in diamond

A means for estimating pressures in natural samples based on both the coupled substitution (Na+)^[1+] (Ti + ^[VI]Si)^[4+] = (M)^[2+] (Al + Cr)^[3+], and the classic pyroxene-stoichiometry majorite-substitution into garnet at high-pressure, is derived for garnets with majoritic chemistry. The technique is based on a compilation of experimental data for different bulk compositions. It is compositionally and thermally robust and can be used to estimate pressures experienced by natural materials during formation of majoritic garnet. In addition, it can be used either retrospectively, or in new experimental studies to establish the pressures of crystallization of reaction products, and determine if disequilibrium is recorded by the chemistries of majoritic garnets. Pressures are calculated based on majoritic chemistries in chondritic meteorites and diamond inclusions. Majoritic garnets associated with Mg perovskite in shocked L chondrites (n = 4) yield uniform pressures of 23.8 ± 0.2 GPa that are slightly higher than pressures recorded by majoritic garnet in shock-derived melt veins in L chondrites (22.4 ± 0.6 GPa; n = 5). Similar pressures are also exhibited by shock-derived majoritic garnets in H chondrites (22.2 ± 1.1 GPa; n = 3). Diamond inclusions with eclogitic and peridotitic majoritic garnet chemistries exhibit mean pressures of 10.7 ± 2.7 GPa (n = 30) and 8.3 ± 1.6 GPa (n = 15) respectively, consistent with a sub-lithospheric origin. However, pressures defined by majoritic diamond inclusions from Jagersfontein (22.3 ± 0.8 GPa and 16.9 ± 1 GPa), Monastery (15.7 ± 7 GPa) and Kankan (15.5 ± 0.2 GPa) show that these inclusions originated from the mantle transition zone. Thus, this new single-phase method for pressure estimation has unmatched potential to map the depth of formation of garnets with majoritic chemistries that occur as diamond inclusions in all parageneses except those that include Ca silicate perovskite. The derived pressures confirm the sub-lithospheric origin of eclogitic majoritic diamond inclusions, and thus provide a more comprehensive picture of the important role of storage of oceanic lithosphere in the transition zone.     

Raman spectra and X-ray diffraction of tuite at various temperatures

High-temperature Raman spectra and thermal expansion of tuite, γ-Ca₃(PO₄)₂, have been investigated. The effect of temperature on the Raman spectra of synthetic tuite was studied in the range from 80 to 973 K at atmospheric pressure. The Raman frequencies of all observed bands for tuite continuously decrease with increasing temperature. The quantitative analysis of temperature dependence of Raman bands indicates that the changes in Raman frequencies for stretching modes (ν₃ and ν₁) are faster than those for bending modes (ν₄ and ν₂) of PO₄ in the present temperature range, which may be attributed to the structural evolution of PO₄ tetrahedron in tuite at high temperature. The thermal expansion of tuite was examined by means of in situ X-ray diffraction measurements in the temperature range from 298 to 923 K. Unit cell parameters and volume were analyzed, and the thermal expansion coefficients were obtained as 3.67 (3), 1.18 (1), and 1.32 (3) × 10^?5 K^?1 for V, a, and c, respectively. Thermal expansion of tuite shows an axial anisotropy with a larger expansion coefficient along the c-axis. The isothermal and isobaric mode Grüneisen parameters and intrinsic anharmonicity of tuite have been calculated by using present high-temperature Raman spectra and thermal expansion coefficient combined with previous results of the isothermal bulk modulus and high-pressure Raman spectra.