Copper (II) Speciation in a Freshwater Ecosystem

Results of chemico-biological experiments in a natural water body with the use of model systems with Cu (II) introduced in them at different proportions of its chemical forms (natural and simulated) in the solution. The model forms used in the experiments were Cu complexes with benzyl- and hexadecylmalonic acids, simulating low-molecular dissolved organic substances. The experimental conditions were chosen based on a preliminary calculation using WATEQ–4f program. The complexes of Cu with hexadecylmalonic acid are found to be absorbed by suspensions and removed into bottom sediment more actively than other Cu forms. The toxicity of introduced Cu for the phyto- and zooplanktonic communities is found to depend on the concentration of Cu²⁺ aqua-ions in the solution, in the presence of which the higher concentrations of complexes with malonic acids do not exert their toxic effect.     

Environmental Condition of Water Bodies in the Territory of an Oil–Gas Condensate Field (the Pechora Delta)

Chemical characteristics of the surface water and algae in lakes in the Seduiyakha River basin are presented. Specific features of components of limnetic ecosystems under the influence of anthropogenic factors in the territory of an oil–gas condensate field are shown. Ambiguous response of algal communities to changes in the aquatic environment is revealed.     

Calculating Sediment Transport in the Coastal Zone of the Sea

The mathematical model described is intended for the prediction of anthropogenic sediment transport in the coastal zone of the sea. Calculation results are presented.     

Study of Heavy Metal Compound Transformations in Surface Waters

Results of studying Fe(III) hydrolysis and sorption of heavy metal compounds by organic matter of bottom sediments are discussed. The rate of Fe(III) hydrolysis is found to be largely determined by the concentration of dissolved organic substances. Values of kinetic parameters are obtained for heavy metal compounds sorption under static and dynamic conditions. Calculating the solubility of Fe, Cu, Cd, Zn, and Pb sulfides allowed the assessment of the amount of metals lost by bottom sediments due to the formation of metal complexes with dissolved organic substances contained in natural waters.     

Natural and Human-Induced Variations in Water and Sediment Runoff in the Danube River Mouth

Long-term natural and human-induced variations in water and sediment runoff in the Danube Delta head were studied on the basis of analysis of an extremely long series of observations (1840–2002). A considerable reduction of sediment runoff in the second half of the 20th century related to sediment accumulation in reservoirs was revealed. It was found that human activities had an insignificant impact on the water runoff variations and the period of 1961–2002 turned out to be abnormally water-abundant.     

On the Problem of Differential Payment for the Use of Different-Quality Surface Waters in Ukraine

The evolution of views and practical decisions regarding the problem of collecting payment for the use of surface waters with regard to their quality in the former USSR and present-day Ukraine is discussed. A simple and feasible method is proposed for differentitation of regional (basin) rates of payment for the use of surface water in Ukraine with allowance made for its quality assessed based on a system of environmental classifications.     

Water Quality Estimation Based on Histological Investigations of Fish: Case Study of Kenozero Lake

Specific hydrological and hydrochemical conditions in Kenozero Lake have led to changes in the morphology of fishes at a cellular level. The abnormalities in the function of the respiratory, digestive, and excretory systems were recorded. The degree of pathology depended on the ecological features of the fish. The pathological changes were most pronounced in the gills of the fish species (orfe, perch, and roach) characterized by active mode of life and sensible to oxygen deficiency. The changes in the epithelium of gill filaments had a compensatory significance and were aimed at increasing the area of the functional surface of the gills under the conditions of hypoxia.     

Long-Term Variations in the Vertical Thermohaline Structure in Deep-Water Zones of the Caspian Sea

Long-term variability in water temperature and salinity in August has been determined for deep-water segments of standard profiles in the Central and Southern Caspian Sea based on data of on-board observations carried out in 1956–2000. Estimates of parameters of the vertical thermohaline structure of waters were obtained for four time intervals. These estimates have been compared to the variability in the main external factors governing the formation of thermohaline regime. Appreciable long-term variations in the vertical thermohaline structure of waters, caused by a nonperiodic alternation of two main types of hydrological processes in the Caspian Sea are revealed. Qualitative characteristics of these two types are presented.     

An automated seamless mosaicing system of multi-charge coupled devices of panchromatic data

Panchromatic data of pixel resolution 5.8 m obtained from IRS-1C and IRS-1D satellites proved to be very useful for mapping purposes. One of the popular data product is the 70 km swath mosaic which is covered by a combination of 3 CCD line sensors, each with 4096 pixels. Each CCD-line sensor with different imaging times causes geometric problems of mosaicing three strips data together. In this paper, we propose the details of the design elements of system that caters to the need for accurate and automatic multi strip image registration without any second resampling of the data. The systematic geometric correction grid mapping is improved to facilitate accurate mosaicing by automatic image registration task that makes use of the overlap data within image strips and image registration is achieved up to sub-pixel level.     

New geochemical data from the Nigerian sector of the Chad basin: implications on hydrocarbon prospectivity

Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and T_max indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output.