A combined pyrolysis mass spectrometric and light microscopic study of peatified Calluna wood isolated from raised bog peat deposits

Stem wood of the Angiosperm Calluna vulgaris (Scotch heather), isolated at different depths from a selection of raised bog peat deposits, was chemically characterized using in-source pyrolysis mass spectrometry (Py-MS) and Curie-point pyrolysis gas chromatography mass spectrometry (Py-GC-MS). Light microscopy was performed to relate mass spectrometric characteristics with anatomical features. Peatified wood samples, isolated from increasing depth show a gradual decrease in carbohydrate content. This decrease in anatomically reflected in a selective removal of secondary cell wall material from the fibre-tracheids and wood parenchyma. During prolonged peatification a selective removal of hemicellulose sugars is observed, while a part of the cellulose fraction is preserved. This highly resistant cellulose is mainly located in the secondary cell walls of the vessels. The lignin macromolecule is preserved, but a gradual decrease in syringyl to guaiacyl ratio (S/G) is observed during peatification. Because no increase in catechol and phenolic compounds is observed, we conclude that S/G shifts are due to removal the of syringyl-rich secondary cell wall material and the retention of guaiacyl-rich compound middle lamella. Small chemical changes in the lignin macromolecule involve shifts in oxygen substitutions on the aliphatic side chains of the methoxyphenolics and the occurrence of aromatic acids.     

Detection Time for Plausible Changes in Annual Precipitation, Evapotranspiration, and Streamflow in Three Mississippi River Sub-Basins

We use diagnostic studies of off-line variable infiltration capacity (VIC) model simulations of terrestrial water budgets and 21st-century climate change simulations using the parallel climate model (PCM) to estimate the time required to detect predicted changes in annual precipitation (P), evapotranspiration (E), and discharge (Q) in three sub-basins of the Mississippi River Basin. Time series lengths on the order of 50–350 years are required to detect plausible P, E, and Q trends in the Missouri, Ohio, and Upper Mississippi River basins. Approximately 80–160, 50, and 140–350 years, respectively, are needed to detect the predicted P, E, and Q trends with a high degree of statistical confidence. These detection time estimates are based on conservative statistical criteria (α = 0.05 and β = 0.10) associated with low probability of both detecting a trend when it is not occurring (Type I error) and not detecting a trend when it is occurring (Type II error). The long detection times suggest that global-warming-induced changes in annual basin-wide hydro-climatic variables that may already be occurring in the three basins probably cannot yet be detected at this level of confidence. Furthermore, changes for some variables that may occur within the 21st century might not be detectable for many decades or until the following century – this may or may not be the case for individual recording station data. The long detection times for streamflow result from comparatively low signal-to-noise ratios in the annual time series. Finally, initial estimates suggest that faster detection of acceleration in the hydrological cycle may be possible using seasonal time series of appropriate hydro-climatic variables, rather than annual time series.     

Occurrence of chromian,hercynitic spinel (“pleonaste”) in Apollo-14 samples and its petrologic implications

Many isolated grains of a reddish pleonaste-type spinel occur in fines and metabreccia samples, particularly 14 319. Electron microprobe analyses (104) of spinels and their associated phases include 58 of pleonaste which show Mg/(Mg + Fe) 0.44–0.62 and Cr/(Cr + Al) 0.017–0.134 (atomic), plus minor amounts of other ions, and differ greatly from almost all previously recorded lunar spinels; almost no spinels of intermediate composition were found. Two types of compositional zoning exist: a diffuse primary one with cores lower in Ti, and a narrow secondary one from reaction with matrix yielding rims higher in Cr, Ti, and Mn. At contacts with breccia matrix there is a narrow corona of almost pure plagioclase (An₈₀-An₉₄), free of opaque minerals and pyroxene. Two types of solid inclusions found in the pleonaste are calcic plagioclase, and tiny spherical masses of nickel-rich sulfide.     

Regional estimation of base recharge to ground water using water balance and a base-flow index

Naturally occurring long-term mean annual base recharge to ground water in Nebraska was estimated with the help of a water-balance approach and an objective automated technique for base-flow separation involving minimal parameter-optimization requirements. Base recharge is equal to total recharge minus the amount of evapotranspiration coming directly from ground water. The estimation of evapotranspiration in the water-balance equation avoids the need to specify a contributing drainage area for ground water, which in certain cases may be considerably different from the drainage area for surface runoff. Evapotranspiration was calculated by the WREVAP model at the Solar and Meteorological Surface Observation Network (SAMSON) sites. Long-term mean annual base recharge was derived by determining the product of estimated long-term mean annual runoff (the difference between precipitation and evapotranspiration) and the base-flow index (BFI). The BFI was calculated from discharge data obtained from the U.S. Geological Survey's gauging stations in Nebraska. Mapping was achieved by using geographic information systems (GIS) and geostatistics. This approach is best suited for regional-scale applications. It does not require complex hydrogeologic modeling nor detailed knowledge of soil characteristics, vegetation cover, or land-use practices. Long-term mean annual base recharge rates in excess of 110 mm/year resulted in the extreme eastern part of Nebraska. The western portion of the state expressed rates of only 15 to 20 mm annually, while the Sandhills region of north-central Nebraska was estimated to receive twice as much base recharge (40 to 50 mm/year) as areas south of it.     

Effect of freezing and thawing on the permeability and structure of soils

The permeability and structure of four fine-grained soils were observed to be changed by freezing and thawing. In all cases freezing and thawing caused a reduction in void ratio and an increase in vertical permeability. The increase in permeability is attributed to the formation of polygonal shrinkage cracks and/or to the reduction of the volume of fines in the pores of the coarse fraction, the mechanism controlling the process depending on material type. No definite relationships are established; however, it appears that the largest increase in permeability occurs for the soil of highest plasticity.     

Effect of freeze—thaw cycles on resilient properties of fine-grained soils

Stress-deformation data for silt and clay subgrade soils were obtained from in-situ tests and laboratory tests, for use in mechanistic models for design of pavements that will experience freezing and thawing. Plate-bearing tests were run on in-service allbituminous-concrete (ABC) pavements constructed directly on silt subgrade, and on an experimental ABC pavement constructed on clay subgrade, applying repeated loads to the pavement surfaces while the subgrade was frozen, thawing, thawed, and fully recovered. The in-service pavement had experienced several seasons of natural cyclic freezing and thawing, while the experimental pavement was artificially frozen and thawed twice. Repeated-load laboratory triaxial compression tests were performed on the same soils in the frozen and thawed states.

Analysis of deflection data from the in-situ tests showed resilient moduli of the subgrade soils up to more than 10 GPa when frozen, as low as 2 MPa during the thawing period, and up to more than 100 MPa when fully recovered. Analysis of the laboratory tests, which gave moduli comparable to the latter values, showed that resilient modulus and Poisson's ratio in the thawed and recovering conditions can be expressed as a function of the stress state, the moisture content, and the dry density.     

The Nazca Group of south-central Peru: Age,source, and regional volcanic and tectonic significance

The Nazca Group, exposed east of Nazca, Peru, consists of a lower part composed of conglomerate and finer-grained clastic strata and an upper part made up of at least seven ash-flow sheets (cooling units or ignimbrites), collectively known as the Nazca Tuff. These tuffs were erupted between about 22 and 18 m.y. ago from a vent area in the vicinity of Pampa Galeras now marked by a collapse caldera. The early Miocene age of the Nazca Tuff provides additional evidence for a major pulse of largely pyroclastic felsic volcanism throughout the central Andes during the early Miocene. Recognition of the Pampa Galeras caldera supports the idea that many of these rocks were erupted from vent areas of the collapse-caldera type located near the eastern margin of the Coastal batholith.The Nazca Group overlies a major erosional surface cut on the Coastal batholith and its envelope that can be traced southward to the Chilean border. This surface is a continuation of the post-Incaic erosional surface to the north, which is overlain by conglomerate and radiometrically dated volcanic rock of late Eocene age. The post-Incaic surface therefore represents a major episode of regional uplift and pedimentation that followed early Tertiary orogeny. The absence of volcanic rocks of late Eocene/early Oligocene age overlying the Coastal batholith near Nazca and in southern Peru may reflect a general absence of post-Incaic volcanism in this portion of the Andes possibly related to differences in the angle of subduction and/or restriction of volcanic and volcaniclastic rocks of this age to depositional basins east of the batholith.