Reports from the Smithsonian’s Global Volcanism Network, July 2009

Information included in this summary is based on more detailed reports published in the Bulletin of the Global Volcanism Network, vol. 34, no. 7, July 2009 (on the Internet at ). Edited by scientists at the Smithsonian, this bulletin includes reports provided by a worldwide network of correspondents. The reports contain the names and contact information for all sources. Please note that these reports are preliminary and subject to change as events are studied in more detail. The Global Volcanism Program welcomes further reports of current volcanism, seismic unrest, monitoring data, and field observations.     

Tephrostratigraphy and glass compositions of post-15 kyr Campi Flegrei eruptions: implications for eruption history and chronostratigraphic markers

Volcanic ash (tephra) erupted from the frequently active Campi Flegrei volcano forms layers in many palaeoenvironmental archives across Italy and the Mediterranean. Proximal deposits of 50 of the post-15 ka eruptions have been thoroughly sampled and analysed to produce a complete database of glass compositions (>1900 analyses) to aid identification of these units. The deposits of individual eruptions are compositionally diverse and this variability is often greater than that observed between different units. Many of the tephra units do not have a unique glass chemistry, with compositionally similar tephra often erupted over long periods of time (1000s years). Thus, glass chemistry alone is not enough to robustly correlate most of the tephra from Campi Flegrei, especially in the last 10 kyrs. In order to reliably correlate the eruption units it is important to take into account the stratigraphy, chronology, magnitude, and dispersal of the eruptions, which has been collated to aid identification. An updated chronology is also presented, which was constrained using Bayesian analysis (OxCal) of published radiocarbon dates and ⁴⁰Ar/³⁹Ar ages. All the data presented can be employed to help correlate post-15 ka tephra units preserved in archaeological and Holocene palaeoenvironmental archives. The new database of proximal glass compositions has been used to correlate proximal volcanic deposits through to distal tephra layers in the Lago di Monticchio record (Wulf et al., 2004, Wulf et al., 2008) and these correlations provide information on eruption stratigraphy and the tempo of volcanism at Campi Flegrei.     

Development and deployment of a deep-sea Raman probe for measurement of pore water geochemistry

We have developed, deployed, and tested a novel probe for study of the geochemistry of sediment pore waters based upon Raman spectroscopy. The Raman technique has already been used successfully for in situ measurements of targets of scientific interest including gas and hydrothermal vents and complex gas hydrates, but sediment geochemistry has so far been an intractable problem since the sediments themselves are strongly fluorescent and typically only very small sample volumes are obtainable. The 35 cm long probe extracts pore fluids through a 10 μm sintered metallic frit and draws the sample through a 2 mm diameter channel into a sapphire windowed optical cell within which the laser beam is focused and the spectrum recorded. The dead volume of the system is ～1 ml and the instrument is ROV deployable with activation of probe insertion and sample withdrawal under direct operator control. The unique features of this mode of detection include observation of the sulfate gradient in marine pore waters as an indicator of diagenesis, direct measurement of the dissolved sulfide species H₂S and HS^?, and measurement of dissolved methane; all of which are of primary geochemical interest. Quantitative analysis is achieved by area ratio to known water peaks and from standard calibration curves with a precision of ±5%. We find only very small fluorescence from pore waters measured in situ, but observe rapid increases in fluorescence from cores returned to the surface and exposed to oxygen.     

Reports from the Smithsonian’s Global Volcanism Network, February 2010

Information included in this summary is based on more detailed reports published in the Bulletin of the Global Volcanism Network, vol. 35, no. 2, February 2010 (on the Internet at ). Edited by scientists at the Smithsonian, this bulletin includes reports provided by a worldwide network of correspondents. The reports contain the names and contact information for all sources. Please note that these reports are preliminary and subject to change as events are studied in more detail. The Global Volcanism Program welcomes further reports of current volcanism, seismic unrest, monitoring data, and field observations.     

Pb-concentrations and Pb-isotope ratios in soils collected along an east–west transect across the United States

Analytical results for Pb-concentrations and isotopic ratios from ca. 150 samples of soil A horizon and ca. 145 samples of soil C horizon collected along a 4000-km east–west transect across the USA are presented. Lead concentrations along the transect show: (1) generally higher values in the soil A-horizon than the C-horizon (median 21 vs. 16.5 mg/kg), (2) an increase in the median value of the soil A-horizon for central to eastern USA (Missouri to Maryland) when compared to the western USA (California to Kansas) (median 26 vs. 20 mg/kg) and (3) a higher A/C ratio for the central to eastern USA (1.35 vs. 1.14). Lead isotopes show a distinct trend across the USA, with the highest ²⁰⁶Pb/²⁰⁷Pb ratios occurring in the centre (Missouri, median A-horizon: 1.245; C-horizon: 1.251) and the lowest at both coasts (e.g., California, median A-horizon: 1.195; C-horizon: 1.216). The soil C-horizon samples show generally higher ²⁰⁶Pb/²⁰⁷Pb ratios than the A-horizon (median C-horizon: 1.224; A-horizon: 1.219). The ²⁰⁶Pb/²⁰⁷Pb-isotope ratios in the soil A horizon show a correlation with the total feldspar content for the same 2500-km portion of the transect from east-central Colorado to the Atlantic coast that shows steadily increasing precipitation. No such correlation exists in the soil C horizon. The data demonstrate the importance of climate and weathering on both Pb-concentration and ²⁰⁶Pb/²⁰⁷Pb-isotope ratios in soil samples and natural shifts thereof in the soil profile during soil-forming processes.     

Lateglacial and Holocene cosmogenic surface exposure age glacial chronology and geomorphological evidence for the presence of cold‐based glaciers at Nevado Sajama,Bolivia

Comparisons of palaeo‐equilibrium line altitudes between the Western and Eastern Cordilleras in the Central Andes are commonly based on the assumption that the tall outermost moraines visible in remotely sensed images of the Western Cordillera date to the Last Glacial Maximum (LGM). However, field investigation and geomorphic mapping at Nevado Sajama, Bolivia, indicates the tall moraines are relic features with shorter moraines overlying and in some cases extending beyond them. ³⁶Cl exposure ages from the shorter moraines suggest that they date to Lateglacial times ca. 16.9–10.2 ka. Although Lateglacial deposits have been found throughout the Central Andes, the extent of these deposits relative to LGM deposits varies both between the Western and Eastern Cordilleras and north‐to‐south along the Western Cordillera. In the Western Cordillera in the zone of easterly winds, the Lateglacial appears to be the most extensive glacial advance of the last glacial cycle. Geomorphic evidence also suggests that some Lateglacial moraines were deposited by cold‐based ice, a previously unreported finding in the tropical Andes. Retreat from other glacial features occurred at about 7.0–4.4 ka and 4.7–3.3 ka. These are the first directly dated Holocene glacial deposits in the Western Cordillera of Bolivia, and their presence suggests that the mid Holocene may not have been as warm and dry as previously thought. Copyright © 2008 John Wiley & Sons, Ltd.     

Twenty‐year weathering remeasurements at St Paul's Cathedral,London

Microerosion meter (MEM) measurements of the surface height of the balustrade of St Paul's Cathedral, London, have been repeated in the year 2000 following earlier measurements in 1980, 1981, 1985 and 1990. Methodological sources of error mean that while the measurements were made to 0·0001 mm, the data are reliable to two decimal places. There was a reduction in the mean erosion rate on horizontal sites from 0·045 mm a^?1 in the period 1980–1990 to 0·025 mm a^?1 in 1990–2000. Decreases in atmospheric SO₂ levels from 20–25 ppb in 1980–1982 to around 10 ppb in 1990–2000, offer a causal explanation. The surface topography evolved more erratically in 1990–2000 than before, with much, but not all, of the more microelevated areas showing greater, and often more variable erosion. There are also indications of less erosion and more surface rises in low‐lying microareas on horizontal sites which is interpreted as possible deposition and/or microfloral growth in wetter depressions, the pattern being largely absent on a well drained vertical site. Copyright © 2001 John Wiley & Sons, Ltd.