Hydrogeochemistry of fluoride in the Quequen river basin: natural pollutants distribution in the argentine pampa

Fluoride pollution is a widespread problem in Argentina, as it is in many areas of the World. Former investigations have demonstrated that the dissolution of volcanic glass disseminated in the loess-like sediments is the main source of fluoride in the Argentine pampas. Nevertheless, fluoride distribution is erratic and the factors controlling it are not yet well-known. A large amount of hydrochemical data collected in the Quequen Grande river catchment is used in order to contribute to the understanding of fluoride distribution and mobility in groundwater in the Argentine pampas. The Quequen Grande river catchment is 10,000 km². It extends between two low hills ranges of Precambrian metamorphic rocks and sedimentary Paleozoic rocks, filled by a thick sequence of Cenozoic sediments, mainly silts and silt-clayed, with sand layers. These sediments form a multilayer phreatic aquifer, which is recharged from precipitation infiltration, discharging through streams directly into the sea. Fluoride concentration in surface water (n = 353) ranges between 0 and 6.5 mg/l, with an average value of 2.14 mg/l. Groundwater concentration (n = 135) is from 0 up to 5.7 mg/l, with an average of 1.84 mg/l. Considering the statistic distribution of fluoride, two groups of samples can be determined. A dominant group between 0 and 3 mg/l, with a mean value around 1.5 mg/l, corresponding to samples widely distributed in the catchment; and a second one group with fluoride contents between 3 and 6 mg/l, corresponding to a smaller area in the central-west border. Two different sources are proposed. Volcanic glass dissolution is responsible for dominant values in the catchment, while the weathering of biotite from the Paleozoic bedrock can be assumed to account for the higher concentrations in the second group.     

Coda Q before and after the eruptions of 13 November 1985, and 1 September 1989, at Nevado del Ruiz Volcano, Colombia

 Coda Q^–1 was calculated at Nevado del Ruiz Volcano (NRV) before and after two phreatomagmatic eruptions (November 1985, September 1989) and for a period of stability (May 1987) using a functional form for coda derived from a single scattering model (Sato 1977). Substantial changes were found before and after the eruptions. The highest value of Q^–1 was found during the November 1985 eruption, an intermediate value for the September 1989 eruption, and the lowest value for May 1987. It seems that the changes in coda Q^–1 at NRV have a still-unknown relationship with the volume or magnitude of the eruption. A relatively strong frequency dependence was found for all periods. Also Q^–1 clearly changed with time, suggesting that the scattering was strong for the eruption of November 1985 and decreased for the eruption of September 1989, and that the intrinsic absorption probably increased. This suggests the possibility that crystallization is taking place in the NRV magma. The clear change of coda Q^–1 before and after the eruptions at NRV also suggests the possibility that coda Q^–1 is a premonitory tool of activity at this volcano. Received: 25 October 1996 / Accepted: 21 January 1998     

Area usage estimation and spatiotemporal variability in distribution patterns of southern right whales,Eubalaena australis,of southern Brazil

Southern right whales—Eubalaena australis (Desmoulins, 1822)—migrate seasonally from high‐latitude feeding grounds to coastal breeding and calving grounds at lower latitudes such as the southern coast of Brazil. Understanding how these whales are distributed along the coast is important for monitoring their postwhaling recovery and defining management strategies. In this study, we applied Kernel density estimators to aerial survey data to determine main occurrence and concentration areas of right whales in southern Brazil and investigate inter‐ and intra‐annual distribution patterns between 2003 and 2012. Our results show considerable variation in area usage within and among years, and changes in the general distribution pattern of right whales in the last years of the study. Intra‐annually, higher concentration area tended to expand from July to September and decrease in November. Some areas stood out as high‐density areas for right whales: Ribanceira/Ibiraquera, Itapirubá Sul/Sol, and from Arroio to Gaivota. Some evidences also suggest preferential areas for mother–calf pairs. The higher concentration area of right whales in southern Brazil was estimated at 52,541 km² and the occurrence area was 682.69 km², which is the whole study area. As right whale distribution in the region is likely expanding due to this population's current recovery, our study provides essential information for management plan of the Right Whale Environmental Protection Area.     

Assessment of the effects of a marine urban outfall discharge on caged mussels using chemical and biomarker analysis

To assess the presence of endocrine disruptors in treated marine outfall discharges and their possible effects, mussels (Mytilus galloprovincialis) were caged in the environmental mixing zone of the outfall of the Santander sanitation system and in one control area. After 30, 60 and 90 days, samples were collected to perform chemical analyses (metals, anionic surfactants, alkylphenols, bisphenol A, phthalates and estrogenic hormones), biomarkers of general stress (lysosomal membrane stability-LMS, histopathology) and biomarkers of endocrine disruption (vitellogenin-like proteins and gonad index). There were no significant differences between outfall and control sites on contaminant levels, except for 4-tert-octylphenol which was higher in the outfall site. Bacteriological counts were higher in the outfall area. No relevant differences in biomarkers were detected between treated and control mussels. A significant reduction in LMS occurred in both groups after 90 days caging, indicating a stress situation possibly related to caging or to post-spawning reproductive state.     

Modelling shallow landslide susceptibility: a new approach in logistic regression by using favourability assessment

A new method for estimating shallow landslide susceptibility by combining Geographical Information System (GIS), nonparametric kernel density estimation and logistic regression is described. Specifically, a logistic regression is applied to predict the spatial distribution by estimating the probability of occurrence of a landslide in a 16 km² area. For this purpose, a GIS is employed to gather the relevant sample information connected with the landslides. The advantages of pre-processing the explanatory variables by nonparametric density estimation (for continuous variables) and a reclassification (for categorical/discrete ones) are discussed. The pre-processing leads to new explanatory variables, namely, some functions which measure the favourability of occurrence of a landslide. The resulting model correctly classifies 98.55% of the inventaried landslides and 89.80% of the landscape surface without instabilities. New data about recent shallow landslides were collected in order to validate the model, and 92.20% of them are also correctly classified. The results support the methodology and the extrapolation of the model to the whole study area (278 km²) in order to obtain susceptibility maps.     

Estimation and prediction of the spatial occurrence of fish species using Bayesian latent Gaussian models

A methodological approach for modelling the occurrence patterns of species for the purpose of fisheries management is proposed here. The presence/absence of the species is modelled with a hierarchical Bayesian spatial model using the geographical and environmental characteristics of each fishing location. Maps of predicted probabilities of presence are generated using Bayesian kriging. Bayesian inference on the parameters and prediction of presence/absence in new locations (Bayesian kriging) are made by considering the model as a latent Gaussian model, which allows the use of the integrated nested Laplace approximation ( INLA ) software (which has been seen to be quite a bit faster than the well-known MCMC methods). In particular, the spatial effect has been implemented with the stochastic partial differential equation (SPDE) approach. The methodology is evaluated on Mediterranean horse mackerel (Trachurus mediterraneus) in the Western Mediterranean. The analysis shows that environmental and geographical factors can play an important role in directing local distribution and variability in the occurrence of species. Although this approach is used to recognize the habitat of mackerel, it could also be for other different species and life stages in order to improve knowledge of fish populations and communities.     

Possibilities of GPS kinematic measurements for geological survey in East Slovakia

This paper deals with transformation procedures for observed GPS data from the world geodetic system WGS-84 into the national geodetic grid datum S-UTCN (system of united trigonometric cadaster network) and Baa (the Baltic Sea after adjustment). Transformation from WGS-84 into SUTCN is performed most frequently by means of the 7-element Helmert transformation with three identical points. Geodetic network was adjusted by two ways.     

Hydrostratigraphic framework and hydrogeological behaviour of the Mancha Oriental System (SE Spain)

The Mancha Oriental System (MOS) has a surface area of 7,260 km², making it one of the largest carbonate aquifer systems in Spain. The system sustains about 1,000 km² of irrigated crops and supplies groundwater to 275,000 inhabitants. The economic transformation brought about by the development of extensive irrigated cropland has led to a water-balance disequilibrium of about 75 million m³/year. This input–output deficit has negative consequences in the quantity and quality of the available resources, in the river–aquifer relationship, and in the associated ecosystems as well. To understand the hydrogeological behaviour of the system, it is necessary to design a conceptual model. Further, the conceptualisation of a groundwater flow system is a requirement of the European Water Framework Directive for the characterisation of groundwater bodies. The robustness of the conceptual model depends heavily on the user capability of representing the real system. In this work, a multidisciplinary approach has been used to represent the three-dimensional geological framework and the groundwater flow conceptualisation of the MOS. Data management and three-dimensional visualisation have been carried out by means of geographical information system (GIS) tools and software for contouring and three-dimensional surface mapping.     

Assessment of evaporation and water fluxes in a column of dry saline soil subject to different water table levels

Dry saline soils are common in the arid and hyper‐arid basins located in the Chilean Altiplano, where evaporation from shallow groundwater is typically the major component of the water balance. Thus, a good understanding of evaporation processes is necessary for improving water resource planning and management in these regions. In this study, we conducted laboratory experiments with a natural saline soil column to estimate evaporation rates and assess the liquid and water vapor fluxes under different water table levels. Water content, electrical conductivity and temperature at different depths were utilized to assess the liquid and water vapor fluxes in the soil column. We observed movement of water that dissolves salts from the soil and transports them to areas in the column where they accumulate. Isothermal liquid flux was predominant, while thermal and isothermal liquid and thermal water vapor fluxes were negligible, except for deep water table levels where isothermal and thermal water vapor fluxes had similar magnitude but opposite directions. Differences observed in total fluxes for all water table levels were due to different upward and downward fluxes, which depend on changes in water content and temperature within the soil profile. Both the vapor flux magnitude and direction were found to be very sensitive to the choice of empirical parameters used in flux quantification, such as tortuosity and the enhancement factor for local temperature gradients in the air phase within the column. Copyright © 2013 John Wiley & Sons, Ltd.