Conditions and timing of high-pressure Variscan metamorphism in the South Carpathians, Romania

High-pressure (HP) metamorphic rocks, including garnet peridotite, eclogite, HP granulite, and HP amphibolite, are important constituents of several tectonostratigraphic units in the pre-Alpine nappe stack of the Getic–Supragetic (GS) basement in the South Carpathians. A Variscan age for HP metamorphism is firmly established by Sm–Nd mineral–whole-rock isochrons for garnet amphibolite, 358±10 Ma, two samples of eclogite, 341±8 and 344±7 Ma, and garnet peridotite, 316±4 Ma.

A prograde history for many HP metamorphic rocks is documented by the presence of lower pressure mineral inclusions and compositional zoning in garnet. Application of commonly accepted thermobarometers to eclogite (grt+cpx±ky±phn±pg±zo) yields a range in “peak” pressures and temperatures of 10.8–22.3 kbar and 545–745 °C, depending on tectonostratigraphic unit and locality. Zoisite equilibria indicate that activity of H₂O in some samples was substantially reduced, ca. 0.1–0.4. HP granulite (grt+cpx+hb+pl) and HP amphibolite (grt+hbl+pl) may have formed by retrogression of eclogites during high-temperature decompression. Two types of garnet peridotite have been recognized, one forming from spinel peridotite at ca. 1150–1300 °C, 25.8–29.0 kbar, and another from plagioclase peridotite at 560 °C, 16.1 kbar.

The Variscan evolution of the pre-Mesozoic basement in the South Carpathians is similar to that in other segments of the European Variscides, including widespread HP metamorphism, in which P–T–t characteristics are specific to individual tectonostratigraphic units, the presence of diverse types of garnet peridotite, diachronous subduction and accretion, nappe assembly in pre-Westphalian time due to collision of Laurussia, Gondwana, and amalgamated terranes, and finally, rapid exhumation, cooling, and deposition of eroded debris in Westphalian to Permian sedimentary basins.     

Rough seas and time-lapse seismic

Time‐lapse seismic surveying has become an accepted tool for reservoir monitoring applications, thus placing a high premium on data repeatability. One factor affecting data repeatability is the influence of the rough sea‐surface on the ghost reflection and the resulting seismic wavelets of the sources and receivers. During data analysis, the sea‐surface is normally assumed to be stationary and, indeed, to be flat. The non‐flatness of the sea‐surface introduces amplitude and phase perturbations to the source and receiver responses and these can affect the time‐lapse image. We simulated the influence of rough sea‐surfaces on seismic data acquisition. For a typical seismic line with a 48‐fold stack, a 2‐m significant‐wave‐height sea introduces RMS errors of about 5–10% into the stacked data. This level of error is probably not important for structural imaging but could be significant for time‐lapse surveying when the expected difference anomaly is small. The errors are distributed differently for sources and receivers because of the different ways they are towed. Furthermore, the source wavelet is determined by the sea shape at the moment the shot is fired, whereas the receiver wavelet is time‐varying because the sea moves significantly during the seismic record.     

The planet formation imager

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.     

Seismic response and energy dissipation of 3D complex steel buildings considering the influence of interior semi-rigid connections: low- medium- and high-rise

A numerical investigation regarding the seismic behavior of complex-3D steel buildings with perimeter moment resisting frames (PMRF) and interior gravity frames (GF) is conducted. The interior connections are assumed to be first perfectly pinned (PP) and then semi-rigid (SR); the two model responses are compared. Three steel building models representing low-, medium- and high-rise buildings, and several strong motions are used. The relative stiffness of SR connections is calculated according to the Richard Model and the Beam Line Theory. The Ruaumoko Computer Program is used to perform the required step-by-step nonlinear seismic analysis. Results indicate that interstory shears and interstory displacements at PMRF may be significantly reduced when interior connections are modeled as SR. Average reductions of up to 20, 46 and 11% are observed for interstory shears, for low-, medium-, and high-rise buildings, respectively. The corresponding reductions for interstory displacements are about 14, 44 and 15%. The contribution of GF to the lateral resistance is considerable, which significantly increases when the connections are modeled as SR; relative contributions larger than 80% are observed. The dissipated energy (DE) at PMRF is larger for the buildings with PP than for the buildings with SR connections indicating that damage at PMRF is reduced. Thus, the effect of the stiffness and the DE at interior connections should not be ignored. However, the design of some elements, particularly columns of the GF, has to be revised; these members may not be able to support the loads produced by the neglected lateral contribution if they are not properly designed.     

Precise geodesy with the Very Long Baseline Array

We report on a program of geodetic measurements between 1994 and 2007 which used the Very Long Baseline Array (VLBA) and up to ten globally distributed antennas. One of the goals of this program was to monitor positions of the array at a 1 mm level of accuracy and to tie the VLBA into the international terrestrial reference frame. We describe the analysis of these data and report several interesting geophysical results including measured station displacements due to crustal motion, earthquakes, and antenna tilt. In terms of both formal errors and observed scatter, these sessions are among the very best geodetic very long baseline interferometry experiments.     

Dissolved iron(II) in the Pacific Ocean: Measurements from the PO2 and P16N CLIVAR/CO2 repeat hydrography expeditions

The redox speciation of dissolved iron in seawater was evaluated at 121 locations in the Pacific Ocean at depths of 15-1000 m, using the method of luminol chemiluminescence. The results indicate that reduced iron, Fe(II), is ubiquitous in surface seawater with a relatively consistent pattern of occurrence. Surface maxima were present in most profiles, with median concentrations of 25-30 pM representing 12-14% of the total dissolved iron. Concentrations decreased monotonically with depth to<12 pM within the upper euphotic zone. This pattern was observed during both day and nighttime sampling events, which suggests that non-photochemical production mechanisms can produce photochemical-like signatures. Further, if theoretical rates of Fe(II) oxidation are applicable to the open ocean, then the employed sampling methods precluded assessment of photochemically-produced Fe(II), regardless of ambient light conditions. For this and other reasons, the concentrations reported here for the upper water column likely represent lower limits of labile iron concentration, and suggest that dissolved iron may be more available for uptake than previously believed. Deeper in the water column, Fe(II) was also frequently detected, though it constituted a small fraction of the total dissolved iron. Possible source mechanisms at these depths include thermal (dark) reduction of Fe(III) organic complexes or remineralization of sinking biogenic particles containing Fe(II). In the northern Philippine Sea between the Japanese coast and the Izu-Bonin volcanic arc system, Fe(II) concentrations were found to be atypically high, possibly because of high atmospheric dust deposition near the surface and transport of sediment-derived iron at depth.