The stiff upper LIP: investigating the High Arctic Large Igneous Province

The Canadian Arctic Islands expose a complex network of dykes and sills that belong to the High Arctic Large Igneous Province (HALIP), which intruded volatile‐rich sedimentary rocks of the Sverdrup Basin (shale, limestone, sandstone and evaporite) some 130 to 120 million years ago. There is thus great potential in studying the HALIP to learn how volatile‐rich sedimentary rocks respond to magmatic heating events during LIP emplacement. The HALIP remains, however, one of the least well known LIPs on the planet due to its remote location, short field season, and harsh climate. A Canadian–Swedish team of geologists set out in summer 2015 to further explore HALIP sills and their sedimentary host rocks, including the sampling of igneous and meta‐sedimentary rocks for subsequent geochemical analysis, and high pressure‐temperature petrological experiments to help define the actual processes and time‐scales of magma–sediment interaction. The research results will advance our understanding of how climate‐active volatiles such as CO_2, SO₂ and CH₄ are mobilised during the magma–sediment interaction related to LIP events, a process which is hypothesised to have drastically affected Earth's carbon and sulphur cycles. In addition, assimilation of sulphate evaporites, for example, is anticipated to trigger sulphide immiscibility in the magma bodies and in so doing could promote the formation of Ni‐PGE ore bodies. Here we document the joys and challenges of ‘frontier arctic fieldwork’ and discuss some of our initial observations from the High Arctic Large Igneous Province.     

Middle Paleolithic occupation on a Marine Isotope Stage 5 lakeshore in the Nefud Desert,Saudi Arabia

Major hydrological variations associated with glacial and interglacial climates in North Africa and the Levant have been related to Middle Paleolithic occupations and dispersals, but suitable archaeological sites to explore such relationships are rare on the Arabian Peninsula. Here we report the discovery of Middle Paleolithic assemblages in the Nefud Desert of northern Arabia associated with stratified deposits dated to 75,000 years ago. The site is located in close proximity to a substantial relict lake and indicates that Middle Paleolithic hominins penetrated deeply into the Arabian Peninsula to inhabit landscapes vegetated by grasses and some trees. Our discovery supports the hypothesis of range expansion by Middle Paleolithic populations into Arabia during the final humid phase of Marine Isotope Stage 5, when environmental conditions were still favorable.     

Response of suspended sediment particle size distributions to changes in water chemistry at an Andean mountain stream confluence receiving arsenic rich acid drainage

Acid drainage is an important water quality issue in Andean watersheds, affecting the sustainability of urban, agricultural, and industrial activities. Mixing zones receiving acid drainage are critical sites where changes in pH and chemical environment promote the formation and dissolution of iron and aluminum oxy/hydroxides. These particles can significantly change the speciation of toxic metals and metalloids throughout drainage networks via sorption, desorption, and settling processes. However, little is known about the behavior of particle size distributions (PSDs) in streams affected by acid drainage and their relationship to metal speciation. This work studied: (a) the PSDs for a wide range of mixing ratios found at a fluvial confluence affected by acid drainage, and (b) the response of PSDs and arsenic speciation to environmental changes found when the particles approach complete mixing conditions. The confluence between the Azufre River (pH ~ 2, high concentration of dissolved metals) and Caracarani River (pH = 8.6, low concentration of dissolved metals) was used as a representative model for study. Field measurements show a bimodal PSD with modal diameters of ~50 and 300 μm. At shorter distances from the junction, the smaller modes with smaller particle volumes were dominant across the stream cross‐sections. A systematic shift towards larger particle sizes and larger particle volumes occurred downstream. The analysis of laboratory PSDs for Azufre/Caracarani mixing ratios between 0.01 and 0.5 (pH from 6.2 to 2.3) showed a bimodal trend with ~15 and 50 μm characteristic diameters; larger particles formed at pH>4. When particle suspensions were transferred in laboratory experiments from very low pH to full mixing conditions (pH ~ 2.8 and mixing ratio ~ 0.25) particle sizes varied, and the dissolved arsenic concentration decreased. The observed reaction kinetics were slow compared to the time scale of advective transport, creating opportunities for engineered controls for arsenic. This work contributes to a better understanding of the chemical‐hydrodynamic interactions in watersheds affected by mining, and identifying opportunities to improve water quality at points of use.     

A methodology for regionalizing 3‐D effective porosity at watershed scale in crystalline aquifers

An innovative approach for regionalizing the 3‐D effective porosity field is presented and applied to two large, overexploited, and deeply weathered crystalline aquifers located in southern India. The method derives from earlier work on regionalizing a 2‐D effective porosity field in that part of an aquifer where the water table fluctuates, which is now extended over the entire aquifer using a 3‐D approach. A method based on geological and geophysical surveys has also been developed for mapping the weathering profile layers (saprolite and fractured layers). The method for regionalizing 3‐D effective porosity combines water table fluctuation and groundwater budget techniques at various cell sizes with the use of satellite‐based data (for groundwater abstraction), the structure of the weathering profile, and geostatistical techniques. The approach is presented in detail for the Kudaliar watershed (983 km²) and tested on the 730 km² Anantapur watershed. At watershed scale, the effective porosity of the aquifer ranges from 0.5% to 2% in Kudaliar and between 0.3% and 1% in Anantapur, which agrees with earlier works. Results show that (a) depending on the geology and on the structure of the weathering profile, the vertical distribution of effective porosity can be very different and that the fractured layers in crystalline aquifers are not necessarily characterized by a rapid decrease in effective porosity and (b) that the lateral variations in effective porosity can be larger than the vertical ones. These variations suggest that within a same weathering profile, the density of open fractures and/or degree of weathering in the fractured zone may significantly vary from a place to another. The proposed method provides information on the spatial distribution of effective porosity that is of prime interest in terms of flux and contaminant transport in crystalline aquifers. Implications for mapping groundwater storage and scarcity are also discussed, which should help in improving groundwater resource management strategies.     

The supergene origin of ruthenian hexaferrum in Ni‐laterites

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.     

Exploration of remotely sensed forest structure and ultrasonic range sensor metrics to improve empirical snow models

Current methods to estimate snow accumulation and ablation at the plot and watershed levels can be improved as new technologies offer alternative approaches to more accurately monitor snow dynamics and their drivers. Here we conduct a meta‐analysis of snow and vegetation data collected in British Columbia to explore the relationships between a wide range of forest structure variables – obtained from Light Detection and Ranging (LiDAR), hemispherical photography (HP) and Landsat Thematic Mapper – and several indicators of snow accumulation and ablation estimated from manual snow surveys and ultrasonic range sensors. By merging and standardizing all the ground plot information available in the study area, we demonstrate how LiDAR‐derived forest cover above 0.5 m was the variable explaining the highest percentage of absolute peak snow water equivalent (SWE) (33%), while HP‐derived leaf area index and gap fraction (45° angle of view) were the best potential predictors of snow ablation rate (explaining 57% of variance). This study reveals how continuous SWE data from ultrasonic sensors are fundamental to obtain statistically significant relationships between snow indicators and structural metrics by increasing mean r² by 20% when compared to manual surveys. The relationships between vegetation and spectral indices from Landsat and snow indicators, not explored before, were almost as high as those shown by LiDAR or HP and thus point towards a new line of research with important practical implications. While the use of different data sources from two snow seasons prevented us from developing models with predictive capacity, a large sample size helped to identify outliers that weakened the relationships and suggest improvements for future research. A concise overview of the limitations of this and previous studies is provided along with propositions to consistently improve experimental designs to take advantage of remote sensing technologies, and better represent spatial and temporal variations of snow. Copyright © 2013 John Wiley & Sons, Ltd.