Diagenetic evolution of Aptian evaporites in the Namibe Basin (south‐west Angola)

The widespread and dissected nature of the Angolan gypsiferous salt residuals offers a uniquely detailed view of the lateral and vertical relations inherent to secondary evaporite textures, which typify exhumed salt masses worldwide. Such secondary textures are sometimes misinterpreted as primary evaporite textures. Thin, metre‐scale and patchy, dome‐like gypsum accumulations are well‐exposed within strongly incised present‐day river valleys along the eastern margin of the Namibe and Benguela basins (south‐west Angola). These sections are time equivalent to the main basinward subsurface evaporites (Aptian Loeme Formation) which mostly consist of halite. The gypsum (here called the Bambata Formation) is interpreted to represent the final residual product of fractional dissolution and recrystallization of the halite mass that occurred during Late Cretaceous margin uplift and continues today. This halite underwent multiple episodes of diagenetic alteration between its deposition and its final exhumation, leading to the formation of various secondary gypsum fabrics and solution‐related karst and breccia textures that typify the current evaporite outcrop. Four different diagenetic gypsum fabrics are defined: thinly bedded alabastrine, nodular alabastrine, displacive selenite rosettes and fibrous satin‐spar gypsum. Current arid conditions are responsible for a thin weathered crust developed at the top of the outcropping gypsum, but the fabrics in the main core of the current at‐surface evaporite unit mostly formed during the telogenetic stage of uplift prior to complete subaerial exposure. Alteration occurred as various dissolving and rehydrating saline minerals encountered shallow aquifers in the active phreatic and vadose zones. Geomorphological and petrographic analyses, mostly based on the cross‐cutting relations and crystallographic patterns in the outcrop, are used to propose a sequence of formation of these different fabrics.     

Carbon isotope fractionation in phospholipid fatty acid biomarkers of bacteria and fungi native to an acid mine drainage lake

This study identifies isotope signatures associated with autotrophic and heterotrophic microbial communities that may provide a means to determine carbon cycling relationships in situ for acid mine drainage (AMD) sites. Stable carbon isotope ratios (δ¹³C) of carbon sources, bulk cells, and membrane phospholipids (PLFA) were measured for autotrophic and heterotrophic microbial enrichment cultures from a mine tailings impoundment in northern Ontario, Canada, and for pure strains of the sulfur oxidizing bacteria Acidithiobacillus ferrooxidans and Acidithiobacillus thiooxidans. The autotrophic enrichments had indistinguishable PLFA distributions from the pure cultures, and the PLFA cyc-C_19:0 was determined to be a unique biomarker in this system for these sulfur oxidizing bacteria. The PLFA distributions produced by the heterotrophic enrichments were distinct from the autotrophic distributions and the C_18:2 PLFA was identified as a biomarker for these heterotrophic enrichments. Genetic analysis (16S, 18S rRNA) of the heterotrophic cultures indicated that these communities were primarily composed of Acremonium fungi.Stable carbon isotope analysis revealed that bulk cellular material in all autotrophic cultures was depleted in δ¹³C by 5.6–10.9‰ relative to their atmospheric CO₂ derived carbon source, suggesting that inorganic carbon fixation in these cultures is carbon limited. Individual PLFA from these autotrophs were further depleted by 8.2–14.6‰ compared to the bulk cell δ¹³C, which are among the largest biosynthetic isotope fractionation factors between bulk cell and PLFA reported in the literature. In contrast, the heterotrophic bulk cells were not significantly fractionated in δ¹³C relative to their carbon source and heterotrophic PLFA ranged from 3‰ enriched to 4‰ depleted relative to the isotopic composition of their total biomass. These distinct PLFA biomarkers and isotopic fractionations associated with autotrophic and heterotrophic activity in this laboratory study provide potential biomarkers for delineating autotrophic and heterotrophic carbon cycling in AMD environments.     

Greenhouse sensitivity experiments with penetrative cumulus convection and tropical cirrus albedo effects

Results are presented from two versions of a global R15 atmospheric general circulation model (GCM) coupled to a nondynamic, 50-m deep, slab ocean. Both versions include a penetrative convection scheme that has the effect of pumping more moisture higher into the troposphere. One also includes a simple prescribed functional dependence of cloud albedo in areas of high sea-surface temperature (SST) and deep convection. Previous analysis of observations has shown that in regions of high SST and deep convection, the upper-level cloud albedos increase as a result of the greater optical depth associated with increased moisture content. Based on these observations, we prescribe increased middle- and upper-level cloud albedos in regions of SST greater than 303 K where deep convection occurs. This crudely accounts for a type of cloud optical property feedback, but is well short of a computed cloud-optical property scheme. Since great uncertainty accompanies the formulation and tuning of such schemes, the prescribed albedo feedback is an intermediate step to examine basic feedbacks and sensitivities. We compare the two model versions (with earlier results from the same model with convective adjustment) to a model from the Canadian Climate Centre (CCC) having convective adjustment and a computed cloud optical properties feedback scheme and to several other GCMs. The addition of penetrative convection increases tropospheric moisture, cloud amount, and planetary albedo and decreases net solar input at the surface. However, the competing effect of increased downward infrared flux (from increased tropospheric moisture) causes a warmer surface and increased latent heat flux. Adding the prescribed cirrus albedo feedback decreases net solar input at the surface in the tropics, since the cloud albedos increase in regions of high SST and deep convection. Downward infrared radiation (from increased moisture) also increases, but this effect is overpowered by the reduced solar input in the tropics. Therefore, the surface is somewhat cooler in the tropics, latent heat flux decreases, and global average sensitivity to a doubling of CO₂ with regard to temperature and precipitation/evaporation feedback is reduced. Similar processes, evident in the CCC model with convective adjustment and a computed cloud optical properties feedback scheme, occur over a somewhat expanded latitudinal range. The addition of penetrative convection produces global effects, as does the prescribed cirrus albedo feedback, although the strongest local effects of the latter occur in the tropics.Portions of this study are supported by the Office of Health and Environmental Research of the U.S. Department of Energy as part of its Carbon Dioxide Research Program, and by the Electric Power Research Institute as part of its Model Evaluation Consortium for Climate Assessment ProjectThe National Center for Atmospheric Research is sponsored by the National Science Foundation     

Benthic nutrient regeneration in South Texas coastal waters

Because of the variable, unpredictable nature of many potential nutrient sources for coastal phytoplankton primary production needs in the north-western Gulf of Mexico, benthic regeneration was investigated as a more constant source of nutrients to this ecosystem. Water column ammonia profiles taken at several locations on the south Texas inner-shelf in the last seven years showed peak concentrations in bottom waters. Benthic chamber measurements verified the presence of ammonia fluxes at the mud-water interface in south Texas coastal waters. These fluxes were related to benthic faunal activity as measured by sediment metabolism. Laboratory experiments, designed to test the effect of benthic faunal removal on nutrient regeneration, suggested that the fauna play a role in regulating this process. How this regulation may occur is discussed. It was estimated that annual benthic regeneration rates can supply 69% of the nitrogen required to support phytoplankton primary production in these coastal waters.     

Hull-mounted sonar/ship design evolution and transition tolow-frequency applications

The author traces the development of hull-mounted sonars over the past 70 years in terms of their impact on the ship design and construction process, with emphasis on the transducer arrays. He then identifies the technology issues involved in making the transition from today's midfrequency sonars to their future low-frequency counterparts     

Diversity of oligotrich ciliates (Ciliophora,Spirotrichea) in the northern coast of South China Sea as revealed in LSU rDNA sequences

Journal of Oceanology and Limnology - Although the taxonomy of oligotrich ciliates has been widely investigated, yet the species diversity remains poorly known. We newly designed a pair of...     

The GF algorithm for reservoir storage, yield and spillage distributions for non-seasonal and seasonal independent inflow processes

a well-known generating function formula for the equilibrium storage distribution in a finite Moran reservoir having IID inflows and unit release is extended to apply to a class of nondecreasing staircase-like release policies withm unit increments,m>1, and to seasonal inflows. The analysis is conducted in terms of an alternative to the Moran inflow-outflow sequencing scheme, with the release during a working interval controlled by the water level at the beginning of that interval.In addition to the storage, the equilibrium distributions of yield and spillage are obtained. Illustrative examples are provided.     

Petrology of the Rainy Lake area,Minnesota, USA-implications for petrotectonic setting of the archean southern Wabigoon subprovince of the Canadian Shield

The Rainy Lake area in northern Minnesota and southwestern, Ontario is a Late Archean (2.7 Ga) granite-greenstone belt within the Wabigoon subprovince of the Canadian Shield. In Minnesota the rocks include mafic and felsic volcanic rocks, volcaniclastic, chemical sedimentary rocks, and graywacke that are intrucded by coeval gabbro, tonalite, and granodiorite. New data presented here focus on the geochemistry and petrology of the Minnesota part of the Rainy Lake area. Igneous rocks in the area are bimodal. The mafic rocks are made up of three distinct suites: (1) low-TiO₂ tholeiite and gabbro that have slightly evolved Mg-numbers (63–49) and relatively flat rare-earth element (REE) patterns that range from 20–8 x chondrites (Ce/Yb_N=0.8–1.5); (2) high-TiO₂ tholeiite with evolved Mg-numbers (46–29) and high total REE abundances that range from 70–40 x chondrites (Ce/Yb_N=1.8–3.3), and (3) calc-alkaline basaltic andesite and geochemically similar monzodiorite and lamprophyre with primitive Mg-numbers (79–63), enriched light rare-earth elements (LREE) and depleted heavy rare-earth elements (HREE). These three suites are not related by partial melting of a similar source or by fractional crystallization of a common parental magma; they resulted from melting of heterogeneous Archean mantle. The felsic rocks are made up of two distinct suites: (1)low-Al₂O₃ tholeiitic rhyolite, and (2) high-Al₂O₃ calc-alkaline dacite and rhyolite and consanguineous tonalite. The tholeiitic felsic rocks are high in Y, Zr, Nb, and total REE that are unfractionated and have pronounced negative Eu anomalies. The calcalkaline felsic rocks are depleted in Y, Zr, and Nb, and the REE that are highly fractionated with high LREE and depleted HREE, and display moderate negative Eu anomalies. Both suites of felsic rocks were generated by partial melting of crustal material. The most reasonable modern analog for the paleotectonic setting is an immature island arc. The bimodal volcanic rocks are intercalated with sedimentary rocks and have been intruded by pre- and syntectonic granitoid rocks. However, the geochemistry of the mafic rocks does not correlate fully with that of mafic rocks in modern are evvironments. The low-TiO₂ tholeiite is similar to both N-type mid-ocean-ridge basalt (MORB) and low-K tholeiite from immature marginal basins. The calc-alkaline basaltic andesite is like that of low-K calc-alkaline mafic volcanic rocks from oceanic volcanic arcs; however, the high-TiO₂ tholeiite is most similar to modern E-type MORB, which occurs in oceanic rifts. The conundrum may be explained by: (1) rifting of a pre-existing immature arc system to produce the bimodal volcanic rocks and high-TiO₂ tholeiite; (2) variable enrichment of a previously depleted Archean mantle, to produce both the low- and high-TiO₂ tholeiite and the calc-alkaline basaltic andesite, and/or (3) enrichment of the parental rocks of the high-TiO₂ tholeiite by crustal contamination.     

Restoration of an impounded salt marsh in New England

The restoration of a 20 ha tidal marsh, impounded for 32, yr, in Stonington, Connecticut was studied to document vegetation change 10 yr after the reintroduction of tidal flushing. These data were then compared to a 1976 survey of the same marsh when it was in its freshest state and dominanted byTypha angustifolia. Currently,T. angustifolia remains vigorous only along the upland borders and in the upper reaches of the valley marsh. Live coverage ofT. angustifolia has declined from 74% to 16% and surviving stands are mostly stunted and depauperate. Other brackish species have also been adversely effected, except forPhragmites australis which has increased. In contrast, the salt marsh speciesSpartina alterniflora has dramatically expanded, from <1% to 45% cover over the last decade. Locally, high marsh species have also become established, covering another 20% of the marsh.