Organochlorine contaminants in sea turtles from the Eastern Pacific

We measured organochlorine residues in three species of sea turtles from the Baja California peninsula, Mexico. Seventeen of 21 organochlorine pesticides analyzed were detected, with heptachlor epoxide and gamma-hexachlorocyclohexane the most prevalent (14 (40%) and 11 (31%) of the 35 tissue samples, respectively). PCBs were detected in all but one of the 9 turtles studied, with congener 18 the most commonly detected (8 (23%) of the samples). The dioxin-like congeners 118 and 180 were detected in 4 (11%) and 3 (9%) of the samples, respectively. Percent contribution of congeners was negatively correlated to their octanol-water partition coefficients, with kidney and muscle containing more lower-chlorinated congeners than liver or adipose samples. Levels of organochlorines detected in the present study were low, potentially attributable to the feeding habits of the predominant species collected in this study (herbivorous) and/or the samples obtained in an unindustrialized region.     

Transport and deposition of pyroclastic material from the ∼1000 A.D. caldera-forming eruption of Volcán Ceboruco, Nayarit, Mexico

The complex eruption sequence from the ∼1000 A.D. caldera-forming eruption of Volcán Ceboruco, known as the Jala Pumice, offers an exceptional opportunity to examine how pyroclastic material is transported and deposited from pyroclastic density currents over variable topography. Three main pyroclastic surge deposits (S1, S2, and S3) and two pyroclastic flow deposits (Marquesado and North-Flank PFDs) were emplaced during this eruption. Pyroclastic surge deposits are massive, planar, or cross-bedded, poor-to-well sorted, and display fluctuations in thickness, median diameter, sorting, and lithology as a function of distance, topography, and flow dynamics. Marquesado pyroclastic flow deposits reveal lateral variations from massive, poorly sorted deposits located within 5 km of Ceboruco to planar bedded, moderately well sorted deposits located >15 km away over the nearly horizontal topography to the south of Ceboruco. North-Flank pyroclastic flow deposits also reveal lateral variations from massive, poorly sorted deposits located within 4 km of Ceboruco to planar bedded, moderately well sorted deposits located 8 km away atop an escarpment that steeply rises 230 m from the northern valley floor. Field observations, granulometric analyses, component analyses, and crystal sedimentation calculations along flow-parallel sampling transects all suggest that both surges and flows were density stratified currents, where deposition occurred from a basal region of higher particle concentration that was supplied from an overlying dilute layer that transports particles in suspension. This supports the idea of a transition between “flow” and “surge” end members with variations in particle concentration. Topography greatly affects the transport and depositional capacity of the pyroclastic density currents as a result of “blocking”, either by topographic obstacles or by abrupt breaks at the base of volcano slopes, whereas the origin of Jala Pumice surge deposits (phreatomagmatic versus magmatic) appears to have little impact on their flow dynamics. Editorial responsibility: A.W. Woods This revised version was published in February 2005 with corrections to the title. An erratum to this article is available at .     

Storage and interaction of compositionally heterogeneous magmas from the 1986 eruption of Augustine Volcano, Alaska

Compositional heterogeneity (56–64 wt% SiO₂ whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO₂) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.     

Evaluation of two direct immunoassays for rapid detection of petroleum products on marine birds

To reduce rehabilitation time and improve survival, a practical, objective test is needed to determine if marine birds are contaminated with oil before they enter captivity. The RaPID Assays and EnviroGard immunoassays for detection of polycyclic aromatic hydrocarbons (PAHs) in soil were evaluated for their ability to detect petroleum on feather samples from 30 intermediate fuel oil contaminated and 30 uncontaminated common murres (Uria aalge). Sensitivity, specificity, positive and negative predictive value, precision, and time required to run each assay were determined. The RaPID Assays was 96.7% sensitive and specific, while the EnviroGard assay was 93.3% sensitive, and 90.0% specific. Sensitivity decreased at higher dilutions for both assays. Intra-replicate variation was less than 20%. Our evaluation showed that these immunoassays are rapid and cost-effective methods for detecting oil-contamination on the plumage of seabirds, with the EnviroGard assay being more practical in most oil spill response situations due to ease of use and rapidity of results.     

Sources and transport of dissolved and particulate organic carbon in the Mississippi River estuary and adjacent coastal waters of the northern Gulf of Mexico

Dissolved organic carbon (DOC), stable carbon isotopic (δ¹³C) compositions of DOC and particulate organic carbon (POC), and elemental C/N ratios of POC were measured for samples collected from the lower Mississippi and Atchafalaya rivers and adjacent coastal waters in the northern Gulf of Mexico during the low flow season in June 2000 and high flow season in April 2001. These isotopic and C/N results combined with DOC measurements were used to assess the sources and transport of terrestrial organic matter from the Mississippi and Atchafalaya rivers to the coastal region in the northern Gulf of Mexico. δ¹³C values of both POC (−23.8‰ to −26.8‰) and DOC (−25.0‰ to −29.0‰) carried by the two rivers were more depleted than the values measured for the samples collected in the offshore waters. Strong seasonal variations in δ¹³C distributions were observed for both POC and DOC in the surface waters of the region. Fresh water discharge and horizontal mixing played important roles in the distribution and transport of terrestrial POC and DOC offshore. Our results indicate that both POC and DOC exhibited non-conservative behavior during the mixing especially in the mid-salinity range. Based on a simple two end-member mixing model, the comparison of the measured DOC-δ¹³C with the calculated conservative isotopic mixing curve indicated that there was a significant in situ production of marine-derived DOC in the mid- to high-salinity waters consistent with our in situ chlorophyll-a measurements. Our DOC-δ¹³C data suggest that a removal of terrestrial DOC mainly occurred in the high-salinity (>25) waters during the mixing. Our study indicates that the mid- to high- (10–30) salinity range was the most dynamic zone for organic carbon transport and cycling in the Mississippi River estuary. Variability in isotopic and elemental compositions along with variability in DOC and POC concentrations suggest that autochthonous production, bacterial utilization, and photo-oxidation could all play important roles in regulating and removing terrestrial DOC in the northern Gulf of Mexico and further study of these individual processes is warranted.     

Drowned shelf-edge deltas, barrier islands and related features along the outer continental shelf north of the head of De Soto Canyon, NE Gulf of Mexico

Four drowned shelf-edge delta complexes, two drowned shelf deltas, three drowned barrier islands, large areas of “hardground”, and fields of bedforms on the mid and outer continental shelf and uppermost slope north of the head of De Soto Canyon, NE Gulf of Mexico were mapped with high-resolution multibeam echosounder. Deltas formed not during the last eustatic low stand, but during one or more interstadials when eustatic sea levels were only 60 to 80 m below present sea level. The barrier islands and deltas must have been cemented prior to rapid falls of eustatic sea level that occurred during global glaciations. Cementation is necessary to have preserved the barrier islands from erosion and subsequent destruction by the rapid sea-level rise during the last deglaciation. The preservation of the relict bathymetry is so good that features that superficially resemble trough blowouts are found in association with one of the relict barrier islands. Asymmetric bedforms on the midshelf in water depths of 50 to 60 m indicate transport directions to the SW but asymmetric bedforms in water depths of the upper slope between 100 and 120 m on the S and SE flanks of the drowned shelf-edge deltas indicate a different current direction, a separate flow that is a continuation of a SW-flowing current that was previously found on the upper slope off NW Florida.     

Seismotectonic implications of sand blows in the southern Mississippi Embayment

We explore seismically-induced sand blows from the southern Mississippi Embayment and their implications in resolving the question of near or distal epicentral source region. This was accomplished using aerial photography, field excavations, and cone penetration tests. Our analysis shows that three sand blow fields exhibit a distinct chronology of strong ground motion for the southern embayment: (1) The Ashley County, Arkansas sand blow field, near the Arkansas/Louisiana state border, experienced four Holocene sand venting episodes; (2) to the north, the Desha County field experienced at least three episodes of liquefaction; and (3) the Lincoln–Jefferson Counties field experienced at least one episode. Cone penetration tests (CPT) conducted in and between the sand blow fields suggest that the fields may not be distal liquefaction associated with New Madrid seismic zone earthquakes but rather are likely associated with strong earthquakes on local faults. This conclusion is consistent with the differences in timing of the southern embayment sand venting episodes and those in the New Madrid seismic zone. These results suggest that active tectonism and strong seismicity in intraplate North America may not be localized at isolated weak spots, but rather widespread on fault systems that are favorably oriented for slip in the contemporary stress field.     

Mountain hazards and the resilience of social–ecological systems: lessons learned in India and Canada

Mountain regions are subject to a variety of hazardous processes. Earthquakes, landslides, snow avalanches, floods, debris flows, epidemics and fires, among other processes, have caused injury, death, damage and destruction. They also face challenges from increased populations, and expansion and intensification of␣activities, land uses and infrastructure. The combination of a dynamic bio- geophysical environment and intensified human use has increased the vulnerability of mountain social–ecological systems to risk from hazards. The ability of social–ecological systems to build resilience in the context of hazards is an important factor in their long-term sustainability. The role of resilience building in understanding the impact of hazards in mountain areas is examined and illustrated, in part, through examples from Canada and India. Resilient social–ecological systems have the ability to learn and adjust, use all forms of knowledge, to self-organize and to develop positive institutional linkages with other social–ecological systems in the face of hazards. The analysis suggests that traditional social–ecological systems built resilience through avoidance, which was effective for localized hazards. The more recent development and implementation of cross-scale institutional linkages is shown to be a particularly effective means of resilience building in mountain social–ecological systems in the face of all hazards.     

A review of water column processes influencing hypoxia in the northern Gulf of Mexico

In this review, we use data from field measurements of biogeochemical processes and cycles in the Mississippi River plume and in other shelf regions of the northern Gulf of Mexico to determine plume contributions to coastal hypoxia. We briefly review pertinent findings from these process studies, review recent mechanistic models that synthesize these processes to address hypoxia-related issues, and reinterpret current understanding in the context of these mechanistic models. Some of our conclusions are that both nitrogen and phosphorus are sometimes limiting to phytoplankton growth; respiration is the main fate of fixed carbon in the plume, implying that recycling is the main fate of nitrogen; decreasing the river nitrate loading results in less than a 1:1 decrease in organic matter sinking from the plume; and sedimenting organic matter from the Mississippi River plume can only fuel about 23% of observed coastal hypoxia, suggesting significant contributions from the Atchafalaya River and, possibly, coastal wetlands. We also identify gaps in our knowledge about controls on hypoxia, and indicate that some reinterpretation of our basic assumptions about this system is required. There are clear needs for improved information on the sources, rates, and locations of organic matter sedimentation; for further investigation of internal biogeochemical processes and cycling; for improved understanding of the rates of oxygen diffusion across the pycnocline; for identification and quantification of other sources of organic matter fueling hypoxia or other mechanisms by which Mississippi River derived organic matter fuels hypoxia; and for the development of a fully coupled physical-biogeochemical model.