Experimental constraints on degassing and permeability in volcanic conduit flow

This study assesses the effect of decompression rate on two processes that directly influence the behavior of volcanic eruptions: degassing and permeability in magmas. We studied the degassing of magma with experiments on hydrated natural rhyolitic glass at high pressure and temperature. From the data collected, we defined and characterized one degassing regime in equilibrium and two regimes in disequilibrium. Equilibrium bubble growth occurs when the decompression rate is slower than 0.1 MPa s^–1, while higher rates cause porosity to deviate rapidly from equilibrium, defining the first disequilibrium regime of degassing. If the deviation is large enough, a critical threshold of super-saturation is reached and bubble growth accelerates, defining the second disequilibrium regime. We studied permeability and bubble coalescence in magma with experiments using the same rhyolitic melt in open degassing conditions. Under these open conditions, we observed that bubbles start to coalesce at ~43 vol% porosity, regardless of decompression rate. Coalescence profoundly affects bubble texture and size distributions, and induces the melt to become permeable. We determined coalescence to occur on a time scale (~180 s) independent of decompression rate. We parameterized and incorporated our experimental results into a 1D conduit flow model to explore the implications of our findings on eruptive behavior of rhyolitic melts with low crystal contents stored in the upper crust. Compared to previous models that assume equilibrium degassing of the melt during ascent, the introduction of disequilibrium degassing reduces the deviation from lithostatic pressure by ~25%, the acceleration at high porosities (>50 vol%) by a factor 5, and the associated decompression rate by an order of magnitude. The integration of the time scale of coalescence to the model shows that the transition between explosive and effusive eruptive regimes is sensitive to small variations of the initial magma ascent speed, and that flow conditions near fragmentation may significantly be affected by bubble coalescence and gas escape.Editorial responsibility: D. Dingwell     

DIET AWSUM: a fluctuation-based deconvolution technique forenhancing signal-to-noise ratio and resolution

A technique for simultaneously improving resolution and signal-to-noise ratio gain, the directivity improved estimation technique (DIET) combined with the advanced WISPR summation (AWSUM), or DIET AWSUM, is introduced. The DIET AWSUM method combines a straightforward deconvolution technique with the highly fluctuation-sensitive AWSUM filter. DIET AWSUM results generated for ocean acoustic data are compared with estimates produced using the maximum entropy method (MEM), a well-tested standard. The DIET AWSUM method achieved superior results in both increased resolution and improved gain for stable signal identification chiefly because of its greater ability to discriminate between stable signals and fluctuating signals and noise     

Long-term photographic,current, and nephelometer observations of manganese nodule environments in the Pacific

Long-term measurements on and near the seafloor were made at five locations in the Pacific as part of the Manganese Nodule Project (MANOP). Bottom Ocean Monitor (BOM) tripods deployed at each site contained a time-lapse camera, nephelometer, and current meter. From nearly three years of photographs of the seafloor, there was no evidence that benthic organisms turned over, rotated, or moved nodules. There were indications, however, that benthic organims cleaned sediment from the tops of nodules and in some cases deposited sediment underneath nodules. Currents never exceeded the expected threshold for sediment resuspension of nodule movement. Particle concentrations in the water remained uniformly low throughout the deployments. Degredation of fecal pellets and organic matter proceeded more rapidly than expected. All changes of the seafloor morphology were attributable to the activity of organisms as opposed to currents. The occurrence in one photo sequence of dark, fluffy globs may be related to phytoplankton blooms in the region of equatorial upwelling.     

Threshold response of small streams to surface coal mining,bituminous coal fields,central Pennsylvania

Stream response to surface coal mining and reclamation was studied in 29 small (0·13 to 5·72 km²) watersheds located in the bituminous coal fields of Central Pennsylvania. These basins, up to 82 per cent mined, were selected from 176 first-order tributaries of Beech Creek with similar vegetation, soil, lithology, and basin characteristics. Measurements were made at 262 cross-sections (an average of nine cross-sections per stream) of channel cross-section area, bankfull width, mean bankfull depth, dimensions of the largest moving blocks, stream slope, valley-side slope, basin area, and mined area. Observed differences in channel morphology were related to differences in extent of mining by means of scatter plots, correlation, cluster analysis, and bivariate regression. Stream response to increased peak discharge and channel shear stress produced by increased surface runoff from regraded mine spoil takes the form of enlarged channels and increases in the size of moving blocks. Large basin areas appear to dampen the effect of mining, resulting in limited channel enlargement with greater extent of mining. In contrast, where peak discharges and associated shear stresses exceed the combined erosional resistance of floodplain vegetation, colluvial blocks, and channel banks, streams adjust extensively to higher levels of mining, causing an abrupt increase in the size of transported blocks and eroded channels. In the first-order basins studied, this stepped response occurs at approximately 0·45 km² mined area and 50 per cent of the total basin area mined. For streams that have exceeded both threshold levels, disequilibrium is demonstrated by a strong, positive correlation between local stream slope and basin area. Where both threshold levels of mining are exceeded, steep channel slopes reinforce the tendency of stream cross-sections to increase with greater disturbance by mining, necessitating that these streams rapidly adjust their morphology in order to attain a new equilibrium which is compatible with the conditions imposed by mining and reclamation.     

A climate-related oxidizing event in deep-sea sediment from the Bering Sea

Many cores from the deep basins of the Bering Sea have a thin oxidized zone within otherwise reduced sediment. This oxidized zone began to form about 6000 yr ago and represents an interval of about 3200 yr. Mineralogically, the oxidized and reduced sediments are similar, but chemically they differ. Concentrations of Fe and C are lower, and concentrations of Mn, Ba, Co, Mo, and Ni are higher in the oxidized than in the reduced sediment. Mn is enriched about 10-fold in the oxidized zone relative to its concentration in the reduced sediment, Mo about threefold, and Ba, Co, and Ni about twofold. These data suggest that the oxidized zone developed diagenetically as the result of the balance between the flux of organic matter and the available dissolved oxygen in bottom and interstitial waters.We propose that the Bering Sea was substantially ice covered when global glacial conditions prevailed. during the transition to global interglacial conditions, seasonal meltwater from thawing sea ice formed a lens of fresh water that decreased organic productivity. During the winter seasons, however, sea ice reformed and caused downwelling of dense, oxygen-rich waters to recharge bottom waters. The combination of lower organic productivity and more oxygen-rich bottom water allowed oxidized sediment to accumulate. Once full interglacial conditions were established, the volume of sea ice produced was insufficient to affect either productivity or the supply of dissolved oxygen and so bottom conditions again became reducing.Similar events probably occurred during the onset of global glacial conditions, and similar oxidized layers probably formed at these times. Such oxidized zones are highly unstable, however, in a reducing environment and, once buried beyond the influence of bacterial and infaunal activities, are depleted of their available oxygen and converted to reduced sediment.     

Ecosystem modelling in the southern Benguela: comparisons of Atlantis,Ecopath with Ecosim,and OSMOSE under fishing scenarios

Ecosystem-based management of marine fisheries requires the use of simulation modelling to investigate the system-level impact of candidate fisheries management strategies. However, testing of fundamental assumptions such as system structure or process formulations is rarely done. In this study, we compare the output of three different ecosystem models (Atlantis, Ecopath with Ecosim, and OSMOSE) applied to the same ecosystem (the southern Benguela), to explore which ecosystem effects of fishing are most sensitive to model uncertainty. We subjected the models to two contrasting fishing pressure scenarios, applying high fishing pressure to either small pelagic fish or to adult hake. We compared the resulting model behaviour at a system level, and also at the level of model groups. We analysed the outputs in terms of various commonly used ecosystem indicators, and found some similarities in the overall behaviour of the models, despite major differences in model formulation and assumptions. Direction of change in system-level indicators was consistent for all models under the hake pressure scenario, although discrepancies emerged under the small-pelagic-fish scenario. Studying biomass response of individual model groups was key to understanding more integrated system-level metrics. All three models are based on existing knowledge of the system, and the convergence of model results increases confidence in the robustness of the model outputs. Points of divergence in the model results suggest important areas of future study. The use of feeding guilds to provide indicators for fish species at an aggregated level was explored, and proved to be an interesting alternative to aggregation by trophic level.     

Estimating the hydraulic properties of an aquitard from in situ pore pressure measurements

A workflow is described to estimate specific storage (S _s) and hydraulic conductivity (K) from a profile of vibrating wire piezometers embedded into a regional aquitard in Australia. The loading efficiency, compressibility and S _s were estimated from pore pressure response to atmospheric pressure changes, and K was estimated from the earliest part of the measurement record following grouting. Results indicate that S _s and K were, respectively, 8.8?×?10^?6 to 1.2?×?10^?5 m^?1 and 2?×?10^?12 m s^?1 for a claystone/siltstone, and 4.3?×?10^?6 to 9.6?×?10^?6 m^?1 and 1?×?10^?12 to 5?×?10^?12 m s^?1 for a thick mudstone. K estimates from the pore pressure response are within one order of magnitude when compared to direct measurement in a laboratory and inverse modelled flux rates determined from natural tracer profiles. Further analysis of the evolution and longevity of the properties of borehole grout (e.g. thermal and chemical effects) may help refine the estimation of formation hydraulic properties using this workflow. However, the convergence of K values illustrates the benefit of multiple lines of evidence to support aquitard characterization. An additional benefit of in situ pore pressure measurement is the generation of long-term data to constrain groundwater flow models, which provides a link between laboratory scale data and the formation scale.