Prime controls on Archaean–Palaeoproterozoic sedimentation: Change over time

Although the principle of uniformitarianism may be applied to the Precambrian sedimentary record as a whole, certain periods of the Archaean and Palaeoproterozoic witnessed a changing pattern of prime influences controlling the depositional systems. This paper examines the major controls on sedimentation systems and environments during the Archaean and Palaeoproterozoic within the broader perspective of Earth evolution. Earth's earliest sedimentary system (4.4?-3.7 Ga) was presumably comprised of deep oceanic realms and probably influenced primarily by bolide impacts, major tsunamis, localized traction and global contour current patterns, and bathymetry. As continental crust began to form, the impact-dominated, tsunami type sedimentation gave way to wider varieties of sedimentary environments, known from the oldest sedimentary records. During early continental crustal evolution (c. 3.7–2.7 Ga), sedimentation was essentially of greenstone-type. Volcanic and volcaniclastic rocks were the major components of the greenstone belts, associated with thin carbonates, stromatolitic evaporites, BIF, pelites and quartzites and lesser synorogenic turbidites, conglomerates and sandstones. Volcanism and active tectonism (reflecting dynamic depositional settings during island arc and proto-continental nucleus formation) were the predominant factors influencing sedimentation during this phase of Earth evolution. Transgressions and regressions under the combined influence of tectonics and eustasy are reflected in fining- and coarsening-upwards successions from the proto-cratonic settings; low freeboard enabled the transgression to affect large areas of the proto-cratons. As the earliest, relatively stable craton formed, through a combination of plate tectonic and mantle-thermal processes, continents and supercontinents with the potential for supercontinental cycles started to influence sedimentation strongly. Major controls on Neoarchaean–Palaeoproterozoic sedimentation systems (2.7–1.6 Ga) were provided by a combination of superplume events and plate tectonics. Two global-scale ‘superevents’ at c. 2.7 Ga and c. 2.2–1.8 Ga were accompanied by eustatic rise concomitant with peaks in crustal growth rates, and large epeiric seas developed. The operation of first-order controls leading to development of vast chemical sedimentary platforms in these epeiric seas and concomitant palaeo-atmospheric and palaeo-oceanic evolution combined to provide a second-order control on global sedimentary systems in the Neoarchaean–Palaeoproterozoic period. The supercontinental cycle had become well established by the end of the Palaeoproterozoic, with the existence of large cratons across broad spectrums of palaeolatitude enabling erg development. The entire spectrum of sedimentary systems and environments came into existence by c. 1.8 Ga, prime influences on sedimentation and depositional system possibly remaining essentially uniform thereafter.     

Glacial conglomerates of the Appalachian Plateau,New York

Three generations of Quaternary conglomerates formed by cementation of glacial gravels are found in drift of the Appalachian Plateau in south-central New York. Postglacial conglomerates have been locally cemented by carbonate minerals within limestone-bearing (erratic-rich) gravels of Late Wisconsin (Woodfordian) age. Conglomerates cemented during the Mid-Wisconsin interstade occur as numerous fragments in erratic-rich Late Wisconsin drift, and as a single in situ mound near Syracuse. Mid-Wisconsin conglomerate contains fragments of a still older conglomerate believed to be of possible pre-Wisconsin (Sangamon) age. Both postglacial and Mid-Wisconsin conglomerates were cemented in the same manner, as a result of diagenetic processes in the vadose zones of limestone-bearing terraces. Information gleaned from conglomerate fragments indicates that Early Wisconsin drift was similar to Late Wisconsin drift; the Early and Late Wisconsin glaciations and deglaciations of the plateau probably proceeded in much the same fashion.     

A SIMPLE SOIL MOISTURE INDEX TO FORECAST CROP YIELDS

Neutron probe soil moisture measurements obtained biweekly during the growing season between 1982 and 1991 from multiple depths under grass-covered plots at 17 Illinois Climate Network sites are used to forecast crop yields. A Soil Moisture Index (SMIX) that combines the effect of intensity, duration, and timing of drought or excessively wet conditions was computed by integrating the quantity of available soil moisture throughout the rooting zone over the growing season. Relationships between the SMIX values and crop yields are evaluated at county, regional, and statewide scales. Coefficients of determination (r ²) for relationships between the SMIX values and maize, soybeans, and hay yields at the statewide level are 0.88, 0.74, and 0.81, respectively, when the period of integration is terminated at the end of the growing season. This new soil index can be employed to forecast yields as early as 12 weeks before harvest for the state of Illinois. However, predictions with RMSE ≤ 10% of the mean yield can be achieved only for SMIX integration periods ending 5, 9, and 6 weeks before harvest for maize, soybeans, and hay, respectively. Nomograms are presented for using the relationships between the SMIX values and crop yields to forecast Illinois's major crops well before harvest.     

Hydrogen ionization and n=2 population for model spicules and prominences

Using slab model atmospheres that are irradiated from both sides by photospheric, chromospheric, and coronal radiation fields we have determined the ionization and excitation equilibrium for hydrogen.The model atom consists of two bound levels (n = 1 and n = 2) and a continuum. Ly- was assumed to be optically thick with the transition in detailed radiative balance. The Balmer continuum was assumed to be optically thin with the associated radiative ionization dominated by the photospheric radiation field (T _rad = 5940 K). The ionization equilibrium was determined from an exact treatment of the radiative transfer problem for the internally generated Ly-c field and the impressed chromospheric and coronal field (characterized by T _rad = 6500K).Our calculations corroborate the hypothesis that N₂, the n = 2 population density, is uniquely determined by the electron density N _e. We also present ionization curves for 6000K, 7500K, and 10000K models ranging in total hydrogen density from 1 × 10¹⁰/cm³ to 3 × 10¹²/cm³. Using these curves it is possible to obtain the total hydrogen density from the n = 2 population density in prominences and spicules.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Self-similar magnetogasdynamic cylindrical shock waves,I

Similarity solutions describing the flow of a perfect gas behind a cylindrical shock wave with transverse magnetic field are investigated in an inhomogeneous medium. The total energy of the shock wave is assumed to be constant. A comparative study has been made between the results with and without magnetic field.     

Assessing groundwater storage changes in the Nubian aquifer using GRACE data

Gravity Recovery and Climate Experiment (GRACE) level two (L2) data is used in estimating the groundwater storage changes (GWSC) in the Nubian Sandstone Aquifer System (NSAS). This set of data consists of spherical harmonics coefficients with specific degree and order. The GRACE data is de-correlated using a sixth degree polynomial in order to reduce the effect of the noise error resulting from the correlation between the spherical harmonics coefficients with the same degree parity. The GRACE estimates of GWSC are smoothed using Gaussian filter with half width of 1000 km. This half width is chosen in order to maximize the correlation between the GRACE estimates of GWSC and previous modeling results of the NSAS. The loss in groundwater storage occurring in each of the four countries sharing the NSAS is calculated to assess the sustainability of using the NSAS as a water resource in each country. The overarching finding in this study is that NSAS is losing its groundwater storage at a very high rate. Also, it is found that Egypt is the fastest in losing its groundwater storage from the NSAS. This loss of groundwater storage in Egypt may not necessarily be resulting from in-country extractions because of the trans-boundary nature of this aquifer. The GRACE-based estimates are found to be close to available data and previous modeling results of the NSAS.     

Application of Deuterium Excess for Identification of Freshwater Sources in the Bays of Novaya Zemlya Archipelago

Doklady Earth Sciences - An isotopic–geochemical study was carried out for waters of Tsivolkii and Sedov bays (southeastern coast of the Novaya Zemlya Archipelago). The waters of these bays...     

Unravelling the effects of melt depletion and secondary infiltration on mantle Re-Os isotopes beneath the French Massif Central

Spinel lherzolite xenoliths from Mont Briançon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (¹⁸⁷Os/¹⁸⁸Os = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25% of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic sulfide with low [Os] and radiogenic ¹⁸⁷Os/¹⁸⁸Os, and (ii) primary sulfides with high [Os] and unradiogenic ¹⁸⁷Os/¹⁸⁸Os, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s).     

Groundwater quality assessment using WQI and GIS techniques, Dindigul district, Tamil Nadu, India

The quality of groundwater was assessed by determining the physicochemical parameters (pH, EC, TDS and TH) and major ions concentration (HCO₃, Cl, FSO₄, Ca, Mg, Na and K) around Dindigul district, Tamil Nadu, India. The groundwater samples were collected from 59 bore wells covering the entire study area and analyzed using standard methods. The GIS mapping technique were adopted to highlight the spatial distribution pattern of physicochemical parameters and major ion concentration in the groundwater. Gibbs diagram reveals that the source of major ions is predominantly derived from rock–water interaction and evaporation dominance process. The salt combinations of the aquifers are dominated by CaHCO₃, mixed CaMgCl, mixed CaMgHCO₃ and CaCl facies type due to leaching and dissolution process of weathered rocks. The Canadian Council of Ministers of Environment Water Quality Index (CCMEWQI) suggests that most of the groundwater quality falls under good to marginal category. The statistical analysis indicates that the presence of major ions and physicochemical parameters are chiefly controlled by rock–water interaction and residence time of the groundwater. However, the major nutrient like nitrite in the groundwater probably comes from anthropogenic process. Based on the groundwater quality standards, majority of the samples are suitable for drinking purposes except few in the study area.     

Effects of diffusional modification of garnet growth zoning on P-T path calculations

The effect of intragranular diffusion on chemical zoning in garnet and on P-T paths calculated from that zoning was evaluated using a numerical model of multicomponent diffusion in combination with simulations of garnet growth. Syn-and post-growth diffusion of Mg–Fe–Mn–Ca species in garnet was calculated for a model pelitic assemblage over a range of temperatures from 485 to 635°C. Compositions from zoned garnet, as modified by diffusion, hypothetical inclusions of plagioclase within garnet and matrix phases were used to reconstruct pressure-temperature (P-T) paths from isobaric and polybaric model histories. P-T path calculations, based on numerical simulations conducted over an input isobaric heating path that reached peak temperatures between 585 and 635°C, show that relaxation of garnet compositional gradients by diffusion can induce modest to appreciable curvature in the inferred paths. Retrieved paths also indicated somewhat smaller overall temperature changes relative to the actual temperature difference of the input path. The magnitude of these distortions is shown to depend upon the heating and cooling rate and garnet crystal size as well as the actual peak temperature condition. The effect of diffusion on path trajectories in simulations with thermal histories that also included cooling were comparable to heating-only models that reached peak temperatures approximately 15–30°C higher. Compositions of garnets with radii less than 1 mm, that reached actual peak temperatures of 605°C along temperature-time histories characteristic of regional metamorphism, experienced sufficient diffusional relaxation to introduce errors of hundreds of bars to in excess of one kilobar in path trajectories. Path distortions were significant at heating/cooling rates less than 10°C/Ma, but rapidly diminished for rates faster than this. In polybaric simulations diffusion effects were least noticeable when the actual pressure-temperature conditions changed in a clockwise sense (i.e., convex to higher P and higher T), but apprecciable modification was seen in path models that underwent counterclockwise changes in P and T. Reequilibration of garnet rim compositions occurred during cooling on all paths, and temperature maxima obtained from garnet-biotite geothermometry underestimated actual peak conditions by 40 to 70°C. Calculations suggest that P-T path trajectories calculated from garnets of at least 1 mm size, and that experienced actual thermal maxima below 585°C, are not likely to be distorted by diffusional effects during regional metamorphism. However, P-T path reconstructions based on garnet zonation with smaller grains or higher temperatures may lead to misinterpretation of crystallization history. The partitioning record of peak metamorphic temperatures may be destroyed by diffusional reequilibration of garnet rim compositions during cooling, seriously complicating the task of quantitatively estimating diffusion effects on path calculations.