The stable aryl hydrocarbon receptor agonist potency of United Kingdom Continental Shelf (UKCS) offshore produced water effluents

The in vitro aryl hydrocarbon receptor (AhR) agonist potency of offshore produced water effluents, collected from the United Kingdom Continental Shelf, was determined using the dioxin responsive (DR)-chemically activated luciferase expression (CALUX) assay. Octadecylsilane (C18) solid phase extraction (SPE) extracts of produced water were exposed to DR-CALUX cells for 24 h in order to investigate the contribution in potency from compounds that are stable to metabolism by the CALUX cells during exposure. The stable AhR agonist potency determined over 24 h was highly variable and ranged from 1 to 430 ng TCDD TEQ_CALUX l⁻¹. These data reflect the highly variable composition of produced water discharges from different production fields. It is recommended that further work be performed to characterise the full range of stable dioxin like AhR agonists present in offshore produced water discharges using techniques such as bioassay-directed analysis.     

A probabilistic performance‐based approach for mitigating the seismic pounding risk between adjacent buildings

Existing design procedures for determining the separation distance between adjacent buildings subjected to seismic pounding risk are based on approximations of the buildings' peak relative displacement. These procedures are characterized by unknown safety levels and thus are not suitable for use within a performance‐based earthquake engineering framework. This paper introduces an innovative reliability‐based methodology for the design of the separation distance between adjacent buildings. The proposed methodology, which is naturally integrated into modern performance‐based design procedures, provides the value of the separation distance corresponding to a target probability of pounding during the design life of the buildings. It recasts the inverse reliability problem of the determination of the design separation distance as a zero‐finding problem and involves the use of analytical techniques in order to evaluate the statistics of the dynamic response of the buildings. Both uncertainty in the seismic intensity and record‐to‐record variability are taken into account. The proposed methodology is applied to several different buildings modeled as linear elastic single‐degree‐of‐freedom (SDOF) and multi‐degree‐of‐freedom (MDOF) systems, as well as SDOF nonlinear hysteretic systems. The design separation distances obtained are compared with the corresponding estimates that are based on several response combination rules suggested in the seismic design codes and in the literature. In contrast to current seismic code design procedures, the newly proposed methodology provides consistent safety levels for different building properties and different seismic hazard conditions. Copyright © 2012 John Wiley & Sons, Ltd.     

Analysis of the geomagnetic induction tensor

The geomagnetic induction tensor is a means of summarizing the response of the earth at a given observing site to a geomagnetic variation source field. In this paper the characteristics of the tensor elements are examined, both generally and for the special cases of one-dimensional and two-dimensional geologic structure. The first-order model is taken of uniform source fields originating external to a semi-infinite half-space. Graphical ways of presenting the information contained in an induction tensor are explored, including ellipses of rotation, polar diagrams, and diagrams analogous to the Mohr circles of elasticity theory. Criteria to distinguish “two-dimensional” data from “three-dimensional” data are established. The advantages of simultaneously recording “normal” and “anomalous” variations are demonstrated in terms of the extra tensor elements which may then be estimated. The most practical way of presenting information from many stations on a map may be by drawing, for each site, arrows which summarize the response in the vertical field and quadrics which summarize the response in the horizontal field.     

Assessing groundwater storage changes in the Nubian aquifer using GRACE data

Gravity Recovery and Climate Experiment (GRACE) level two (L2) data is used in estimating the groundwater storage changes (GWSC) in the Nubian Sandstone Aquifer System (NSAS). This set of data consists of spherical harmonics coefficients with specific degree and order. The GRACE data is de-correlated using a sixth degree polynomial in order to reduce the effect of the noise error resulting from the correlation between the spherical harmonics coefficients with the same degree parity. The GRACE estimates of GWSC are smoothed using Gaussian filter with half width of 1000 km. This half width is chosen in order to maximize the correlation between the GRACE estimates of GWSC and previous modeling results of the NSAS. The loss in groundwater storage occurring in each of the four countries sharing the NSAS is calculated to assess the sustainability of using the NSAS as a water resource in each country. The overarching finding in this study is that NSAS is losing its groundwater storage at a very high rate. Also, it is found that Egypt is the fastest in losing its groundwater storage from the NSAS. This loss of groundwater storage in Egypt may not necessarily be resulting from in-country extractions because of the trans-boundary nature of this aquifer. The GRACE-based estimates are found to be close to available data and previous modeling results of the NSAS.     

Pressure-temperature and evolution of fluid compositions of Al2SiO5-bearing rocks,Mica Creek,B.C., in light of fluid inclusion data and mineral equilibria

Metamorphosed pelitic rocks from Mica Creek, British Columbia contain sillimanite, kyanite with minor fibrolite and andalusite-bearing quartz pods. Mineral equilibria were used to infer peak P-T conditions and fluid compositions in equilibrium with the solid phases. Fluid inclusions in three schist samples appear to be good indicators of conditions affecting those rocks during and after peak metamorphic conditions. In samples from two localities, fluid inclusions from schist and quartz-rich segregations have densities appropriate to the peak metamorphic conditions. The observed compositions for these fluids (low salinity with 12 mole % dissolved CO₂) agree with calculated values of 0.84 to 0.85, based upon paragonite-quartz-albite-Al₂SiO₅ equilibria. The fluids unmixed as the schists were uplifted and cooled; fluid inclusions trapped during this stage outline a solvus in the CO₂-H₂O-NaCl system. A later influx of fluids containing CH₄ and N₂ accompanied formation of andalusite-bearing plagioclaserich segregations. The restricted association of andalusite-bearing pods and low density fluids suggest a localized but pervasive fluid influx during uplift. Preservation of high density fluid inclusions during uplift and erosion, coupled with evidence for unmixing of H₂O- and CO₂-rich fluids on the solvus, provide constraints on the P-T uplift path.     

Polarization in spectral lines

The general formalism, presented in a previous paper of this series (Landi Degl'Innocenti, 1983a), is particularized to deduce the radiative transfer equations for polarized radiation and the statistical equilibrium equations for a multi-level atom in the zero-magnetic field, collisionless regime. The formulae are developed both in the standard representation and in the representation of the statistical tensors. For resonance scattering in a two-level atom, in the limiting case of complete depolarization of the ground level, we recover the classical results for Rayleigh scattering and we derive the expression of the phase matrix in terms of ordinary rotation matrices. The law of scattering is then generalized to take properly into account the influence of the anisotropy of the radiation field on the atomic polarization of the ground level (depopulation pumping).     

Seismic model of the lithosphere of the East European Platform beneath the Baltic Sea-Black Sea profile

This paper presents the results of seismic measurements along the Baltic Sea-Black Sea profile. The basic wave groups recorded up to distances of 900 km are characterized. The main elements of a lithospheric model of the southwestern part of the Precambrian East European Platform are given. The thickness of the Earth's crust is about 45 km and the mean velocity of the crust is about 6.3 km/s. At a depth of 65 km, the velocity increases from 8.2 to 8.5 km/s. In the depth interval 110 to 135 km, there is a series of layers with low and high velocities. The lower boundary of the lithosphere is probably defined by the boundary at a depth of 110 km.     

Evaluation of the spatial changes in seagrass cover in the lagoons of Lakshadweep islands,India, using IRS LISS III satellite images

A study was conducted in Lakshadweep islands to determine the feasibility of using Indian Remote Sensing (IRS) satellites for detecting changes in the seagrass from other coastal features. IRS ID and IRS P6 LISS III having spatial resolution of 23.5 m with lower cost compared to all other contemporary satellites with the same spatial resolution have not been widely used for monitoring the changes in seagrass cover. In this context, the present study attempted to explore the effectiveness of LISS III data for mapping seagrasses and to inform the international community about the usefulness of these low-cost imageries for coastal resource monitoring. Supervised classification and change detection studies found a significant decrease in seagrass cover of 73.03 ha in the Lakshadweep group of islands. An overall accuracy of 67.5% was obtained for the change maps, and seagrass cover and its changes vary at different islands.