A Statistical Study of Microwave Flare Morphologies

This study has been motivated by the detection of a small number of optically thin microwave bursts with maximum emission near the loop top, which is contrary to the prediction of isotropic gyrosynchrotron models. Using Nobeyama Radioheliograph (NoRH) high-spatial-resolution images at 17 and 34 GHz, we study the morphology at the radio peak of 104 flares that occurred relatively close to the limb. Using data from the Nobeyama Polarimeter we were able to determine whether the 17- and 34-GHz emissions came from optically thin or thick sources. We identified single-loop events, taking into account supplementary information from EUV and soft X-ray (SXR) images. We found optically thin emission from the top of the loop in 36% of single-loop events. In agreement with standard models, in this sample 46% and 18% of the events showed optically thin emission from the footpoints and optically thick emission from the entire loop, respectively. The derived percentage of events with gyrosynchrotron emission from isotropic populations of energetic electrons is possibly an upper limit. This point is illustrated by the analysis of an optically thin event that shows footpoint emission during the rise phase and loop-top emission during the decay phase. A model that takes into account both anisotropies in the distribution function of nonthermal electrons and time evolution can reproduce the observed transition from footpoint to loop-top morphology, if electrons with pitch-angle anisotropy are injected near one of the footpoints.     

Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

Interpretation of aeromagnetic data across the central crystalline shield area of Nigeria

Summary. A residual map of the total magnetic field (above 25 000 nT base) is presented for a portion of the central crystalline shield area of Nigeria and overlapping small portions of the Chad basin and the Benue rift (8°30'−12° 00'lat, and 7°−10°30' long). The map (based on a dataset digitized from recently released aeromagnetic sheets of Nigeria) leads to four results. (1) A magnetic boundary, evident on the map, separates the Younger Granite complexes into two groups. The groups are petrologically different, and the boundary may be a fault line with uplift to the south. (2) South of the boundary the map is dominated by a system of sub-parallel anomalies striking NE–SW, possibly representing major tectonic trends, and a set of fractures through which the Younger Granite complexes were intruded. The trend of the system parallels the Benue rift and lineaments in the oceanic crust off West Africa. (3) Negative magnetic anomalies lie over most of the known ring complexes, and over some suspected buried ring complexes and other intrusions. (4) 2½-and 3-D modelling shows that the larger complexes extend to 12 km depth, and the smaller ones to 6 km. They have nearly vertical sides, and magnetization contrasts range from 0.3 to 0.5 A m⁻¹.     

Lead and copper in the waters of Raritan and Lower New York Bays

A survey of waters adjacent to this heavily urbanized and industrialized region showed concentrations of copper, 65 μg l.^?1 to be the highest reported to date for estuarine waters, and lead up to 13.9 μg l.^?1 Correlations between distributions of dissolved and total metal concentration in the water column, hydrography, and metal in the sediment were related to benthic studies in this area. Laboratory studies are cited which show the potential for adverse effects on marine animals at these metal concentrations.     

Analysis of some aromatic hydrocarbons in a benzene-soluble bitumen from Green River shale

The hydrocarbon content of an aromatic fraction, isolated from the bitumen of Green River shale, was studied by mass spectrometry, infra-red spectrometry, gas chromatography and a dehydrogenation technique. The hydrocarbon types and their distribution in this aromatic fraction, as determined by mass spectrometry, include the following: C_nH_2n?6(10%), C_nH_{2n?8 (31 %)}, C_nH_2n?10(18%), C_nH_2n?12(12%), C_nH_2n?14(8%) and a series of alkenylbenzenes (20%). The carbon-number range, empirical formulae and quantity of each compound in the major types are reported. Mass spectra of several compounds and homologous mixtures of compounds isolated from the aromatic fraction are also given.     

The Catoca kimberlite pipe, Republic of Angola: A paleovolcanological model

The Catoca kimberlite pipe is among the world’s largest primary diamond deposits. The Catoca volcanic edifice is only slightly eroded. Kimberlitic rocks of various facies compose a crater of about 1 km in diameter and a diatreme. The structure of the pipe and mining conditions of the deposit are complicated by intense intrapipe tectonic processes related to large-amplitude subsidence. Based on geological data, we propose a structural model of the deposit and a paleovolcanological model of the Catoca pipe formed during a full cycle beginning with a stage of active volcanism and completed by stages of gradually waning volcanic activity and sedimentation. It is suggested that the banded tuffisitic kimberlite of the crater zone was deposited at the stage of active volcanic eruption from specific pyroclastic suspension as a low-viscosity mixture of crystals and aqueous sol rich in serpentine.     

Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.     

A contribution to the theory of the equatorial noise generation in the Earth’s magnetosphere

This work is devoted to the study of the generation of the equatorial noise—electromagnetic emission below the LHR frequency observed near the equatorial plane of the magnetosphere at distances of ~4R_E. According to accepted views, the generation of the equatorial noise is related to the instability of ring current protons. In this work, a logarithmic distribution of energetic protons over the magnetic moment with an empty loss cone is proposed, and arguments for the formation of such a distribution are presented. The main result of the work is the calculation and analysis of the instability growth rate of waves forming the equatorial noise. The growth rate obtained in this work significantly differs from that encountered in the literature.