Geochemistry of Suspended Matter from Waters of the Amazon Basin

The geochemical study of the suspended matter in the waters of the Amazon River and its tributaries revealed that the chemical composition of this material ranges widely; however, generally, it is similar to the average composition of the suspended matter in the rivers and clayey sedimentary rocks around the world. Against this background, an essential regional Hg enrichment due to the anthropogenic factor is distinguished. The suspensions from the so-called clear waters from the tributaries of the Amazon River—Xingu and Trombetas—demonstrate the local enrichment in Pb, Sn, Zn, and organic carbon indicating the ore mineralization of the drainage basin, and points to the presence of metal-organic complexes.     

Observations of the structure and evolution of solar flares with a soft X-ray telescope

132 soft X-ray flare events have been observed with The Aerospace Corporation/Marshall Space Flight Center S-056 X-ray telescope that was part of the ATM complement of instruments aboard Skylab. Analyses of these data are reported in this paper. The observations are summarized and a detailed discussion of the X-ray flare structures is presented. The data indicated that soft X-rays emitted by a flare come primarily from an intense well-defined core surrounded by a region of fainter, more diffuse emission. Loop structures are found to constitute a fundamental characteristic of flare cores and arcades of loops are found to play a more important role in the flare phenomena than previously thought. Size distributions of these core features are presented and a classification scheme describing the brightest flare X-ray features is proposed. The data show no correlations between the size of core features and: (1) the peak X-ray intensity, as indicated by detectors on the SOLRAD satellite; (2) the rise time of the X-ray flare event, or (3) the presence of a nonthermal X-ray component. An analysis of flare evolution indicates evidence for preliminary heating and energy release prior to the main phase of the flare. Core features are found to be remarkably stable and retain their shape throughout a flare. Most changes in the overall configuration seem to be the result of the appearance, disappearance or change in brightness of individual features, rather than the restructuring or re-orientation of these features. Brief comparisons with several theories are presented.     

Invariant manifolds, phase correlations of chaotic orbits and the spiral structure of galaxies

In the presence of a strong   m = 2  component in a rotating galaxy, the phase-space structure near corotation is shaped to a large extent by the invariant manifolds of the short-period family of unstable periodic orbits terminating at L ₁ or L ₂. The main effect of these manifolds is to create robust phase correlations among a number of chaotic orbits large enough to support a spiral density wave outside corotation. The phenomenon is described theoretically by soliton-like solutions of a Sine–Gordon equation. Numerical examples are given in an N -body simulation of a barred spiral galaxy. In these examples, we demonstrate how the projection of unstable manifolds in configuration space reproduces essentially the entire observed bar–spiral pattern.     

Simulating the moderating effect of a lake on downwind temperatures

A steady-state, two-dimensional numerical model is used to simulate air temperatures and humidity downwind of a lake at night. Thermal effects of the lake were modelled for the case of moderate and low surface winds under the cold-air advective conditions that occur following the passage of a cold front. Surface temperatures were found to be in good agreement with observations. A comparison of model results with thermal imagery indicated the model successfully predicts the downwind distance for which thermal effects due to the lake are significant.     

The measurement and extraction of the <nu>6 atmospheric emission band of CFC-12 from interfering emission features

Ground-based thermal emission measurements of the zenith sky have been made at Peterborough, Ontario since January 1993. In this paper, the measurement of the ₆ band of atmospheric CFC-12, an important greenhouse gas, is presented for a cold, clear day in January 1994. A spectrum of the non-CFC-12 emission features has been simulated using the FASCD3P radiation code and measured radiosonde profiles of temperature, pressure and humidity. This has enabled a satisfactory subtraction of the interfering emission features from the CFC-12 emission spectrum. A comparison of the observed and simulated ₆-bands of CFC-12 shows good agreement at all frequencies of emission. From these spectra the total downward greenhouse radiative flux from the CFC-12 ₆ emission based for a very cold day has been estimated to be 0.27 W m⁻²±10%.     

Seismic hazard monitoring in Kamchatka and its applications to the M = 6.6 earthquake of 6 October 1987

The earthquake of 6 October 1987 (M = 6.6), which occurred near the Shipunsky Cape, Kamchatka, was the largest crustal event in the vicinity of the main city of Kamchatka — Petropavlovsk-Kamchatsky — during the last three decades. It was followed by numerous aftershocks. This earthquake allowed us to test the effectiveness of the seismic hazard monitoring in Kamchatka, including the seismological, geodetic and hydrogeochemical surveys. The seismic survey provided the location and source nature of the main shock and aftershocks and the seismic environment of the main shock. The geodetic and hydrogeochemical surveys have yielded data on the response to earthquakes of the Earth's surface deformations, water level, and chemical elements concentration in the underground water. As a result, the following data were obtained:

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The earthquake of 6 October had a seismic moment 4–10 E18 Nm, thrust type of faulting and the source volume of 20 × 20 × 10 km³. The maximum intensity was VI–VII (MSK-64 scale) and maximum acceleration 88 cm/s².

Before this event, a relative increase in the number of the upper mantle (depth more than 100 km) moderate magnitude earthquakes during 5 years and a one-year period of seismic quiescence for small shallow earthquakes, were recognized. Significant anomalies in HCO₃ and H₃BO₃ concentrations in the underground waters were observed in the wells a week before the main shock.

     

Resolving mechanisms of toxicity while pursuing ecotoxicological relevance?

In this age of modern biology, aquatic toxicological research has pursued mechanisms of action of toxicants. This has provided potential tools for ecotoxicologic investigations. However, problems of biocomplexity and issues at higher levels of biological organization remain a challenge. In the 1980s and 1990s and continuing to a lesser extent today, organisms residing in highly contaminated field sites or exposed in the laboratory to calibrated concentrations of individual compounds were carefully analyzed for their responses to priority pollutants. Correlation of biochemical and structural analyses in cultured cells and tissues, as well as the in vivo exposures led to the production and application of biomarkers of exposure and effect and to our awareness of genotoxicity and its chronic manifestations, such as neoplasms, in wild fishes. To gain acceptance of these findings in the greater environmental toxicology community, “validation of the model” versus other, better-established often rodent models, was necessary and became a major focus. Resultant biomarkers were applied to heavily contaminated and reference field sites as part of effects assessment and with investigations following large-scale disasters such as oil spills or industrial accidents.

Over the past 15 years, in the laboratory, small aquarium fish models such as medaka (Oryzias latipes), zebrafish (Danio rerio), platyfish (Xiphophorus species), fathead minnow (Pimephales promelas), and sheepshead minnow (Cyprinodon variegatus) were increasingly used establishing mechanisms of toxicants. Today, the same organisms provide reliable information at higher levels of biological organization relevant to ecotoxicology. We review studies resolving mechanisms of toxicity and discuss ways to address biocomplexity, mixtures of contaminants, and the need to relate individual level responses to populations and communities.     

A comparative study of geothermal and meteorological records of climate change in Kamchatka

To reconstruct the recent climate history in Kamchatka, a series of repeated precise temperature logs were performed in a number of boreholes located in a broad east-west strip (between 52 and 54°N) in the central part of Kamchatka west of Petropavlovsk-Kamchatski. Within three years more than 30 temperature logs were performed in 10 holes (one up to six logs per hole) to the depth of up to 400 metres. Measured temperature gradients varied in a broad interval 0 to 60 mK/m and in some holes a sizeable variation in the subsurface temperatures due to advective heat transport by underground water was observed. Measured data were compared with older temperature profiles obtained in the early eighties by Sugrobov and Yanovsky (1993). Even when older data are of poorer precision (accuracy of about 0.1 K), they presented valuable information of the subsurface temperature conditions existing 20–25 years ago. Borehole observations and the inverted ground surface temperature histories (GSTHs) used for the paleoclimate reconstruction were complemented with a detailed survey of meteorological data. Namely, the long-term surface air temperature (SAT) and precipitation records from Petropavlovsk station (in operation since 1890) were used together with similar data from a number of local subsidiary meteo-stations operating in Central Kamchatka since 1950. Regardless of extreme complexity of the local meteorological/climate conditions, diversity of borehole sites and calibration of measuring devices used during the whole campaign, the results of the climate reconstruction supported a general warming of about 1 K characteristic for the 20th century, which followed an inexpressive cooler period typical for the most of the 19th century. In the last three to four decades the warming rate has been locally increasing up to 0.02 K/year. It was also shown that the snow cover played a dominant role in the penetration of the climate “signal” to depth and could considerably smooth down the subsurface response to the changes occurred on the surface.     

Gamma-Hadron Separation using Čerenkov Photon Density Fluctuations

In the atmospheric Čerenkov technique γ-rays are detected against the abundant background produced by hadronic showers. In order to improve the signal to noise ratio of theexperiment, it is necessary to reject a significant fraction of hadronic showers. Traditional background rejection methods based on image shape parameters have been extensively used for the data from imaging telescopes. However, non-imaging Čerenkov telescopes have to develop very different means of statistically identifying and removing cosmic ray events. Some of the parameters, which could be potentially important for non-imaging arrays, are the temporal and spectral differences, the lateral distributions and density fluctuations of Čerenkov photons generated by γ-ray and hadron primaries. Here we study the differences in fluctuations of Čerenkov photon density in the light pool at the observation level from showers initiated by photons and those initiated by protons or heavier nuclei. The database of simulated events for the PACT array has been used to evaluate the efficiency of the new technique. Various types of density fluctuations like the short range and medium range fluctuations as well as flatness parameter are studied. The estimated quality factors reflect the efficiencies with which the hadrons can be rejected from the data. Since some of these parameters are independent, the cuts may be applied in tandem and we demonstrate that the proton rejection efficiency of ∼90% can be achieved. Use of density fluctuations is particularly suited for wavefront sampling observations and it seems to be a good technique to improve the signal to noise ratio. This revised version was published online in July 2006 with corrections to the Cover Date.