Multiphase dolomitization of deeply buried Cambrian petroleum reservoirs,Tarim Basin,north‐west China

Cambrian dolostone reservoirs in the Tarim Basin, China, have significant potential for future discoveries of petroleum, although exploration and production planning is hampered by limited understanding of the occurrence and distribution of dolomite in such ancient rocks buried to nearly 8 km. The study herein accessed new drill core samples which provide an opportunity to understand the dolomitization process in deep basins and its impact on Cambrian carbonate reservoirs. This study documents the origin of the dolostone reservoirs using a combination of petrology, fluid‐inclusion microthermometry, and stable and radiogenic‐isotopes of outcrop and core samples. An initial microbial dolomitization event occurred in restricted lagoon environments and is characterized by depleted δ¹³C values. Dolomicrite from lagoonal and sabkha facies, some fabric‐retentive dolomite and fabric‐obliterative dolomite in the peloidal shoal and reef facies show the highest δ¹⁸O values. These dolomites represent relatively early reflux dolomitization. The local occurrence of K‐feldspar in dolomicrite indicates that some radiogenic strontium was contributed via terrigenous input. Most fabric‐retentive dolomite may have precipitated from seawater at slightly elevated temperatures, suggested by petrological and isotopic data. Most fabric‐obliterative dolomite, and medium to coarse dolomite cement, formed between 90°C and 130°C from marine evaporitic brine. Saddle dolomite formed by hydrothermal dolomitization at temperatures up to 170°C, and involved the mixing of connate brines with Sr‐ enriched hydrothermal fluids. Intercrystalline, moldic, and breccia porosities are due to the early stages of dolomitization. Macroscopic, intergranular, vuggy, fracture and dissolution porosity are due to burial‐related dissolution and regional hydrothermal events. This work has shown that old (for example, Cambrian or even Precambrian) sucrosic dolomite with associated anhydrite, buried to as much as 8000 m, can still have a high potential for hosting substantial hydrocarbon resources and should be globally targeted for future exploration.     

On the controls of preferential flow in soils of different hillslope position and lithological origin

Soils derived from different lithologies and their controls on preferential flow remain underexplored in forested landscapes. In the same lithology, the propensity for preferential flow occurrence at different hillslope positions also remains largely elusive. By utilizing a soil moisture response time method, we compared preferential flow occurrence between a shale site (Shale Hills, silt loam soils) and a sandstone site (Garner Run, sandy loam soils) at four hillslope positions: ridge-top, North- and South-facing mid-slopes and toe slope, for over 2 years. The catchments are neighbouring and covered by temperate forest. For the four hillslope positions, Shale Hills had higher preferential flow frequencies compared to Garner Run. Between these two catchments, the South-facing mid-slope sites showed the highest contrasts in preferential flow frequency (33.5% of events at Shale Hills vs. 8.8% at Garner Run) while the ridge-top sites showed the lowest contrasts (18.7 vs. 13.2%). Additionally, over the unfrozen period, for seven out of eight monitoring sites, drier antecedent conditions tended to be more favourable for preferential flows to occur, with significant (p < .01) relationships at two sites. Except for the South-facing mid-slope sites, both Shale Hills and Garner Run had two preferential flow pathways. The characteristic preferential flow pathways at Shale Hills were the B_w and C horizons, and for Garner Run, preferential flow moved from the E/AE horizon to the B_w horizon. This study shows that shale-derived soils tended to have higher preferential flow occurrence than sandstone soils, but hillslope positions exhibit different levels of contrasts. More effort should be paid to study the impact of lithology on preferential flows in the context of land surface modelling and biogeochemical reactions to improve ecosystem services of headwater catchments.     

Assessing urban rainfall-runoff response to stormwater management extent

We report an empirical analysis of the hydrologic response of three small, highly impervious urban watersheds to pulse rainfall events, to assess how traditional stormwater management (SWM) alters urban hydrographs. The watersheds vary in SWM coverage from 3% to 61% and in impervious cover from 45% to 67%. By selecting a set of storm events that involved a single rainfall pulse with >96% of total precipitation delivered in 60 min, we reduced the effect of differences between storms on hydrograph response to isolate characteristic responses attributable to watershed properties. Watershed-average radar rainfall data were used to generate local storm hyetographs for each event in each watershed, thus compensating for the extreme spatial and temporal heterogeneity of short-duration, intense rainfall events. By normalizing discharge values to the discharge peak and centring each hydrograph on the time of peak we were able to visualize the envelope of hydrographs for each group and to generate representative composite hydrographs for comparison across the three watersheds. Despite dramatic differences in the fraction of watershed area draining to SWM features across these three headwater tributaries, we did not find strong evidence that SWM causes significant attenuation of the hydrograph peak. Hydrograph response for the three watersheds is remarkably uniform despite contrasts in SWM, impervious cover and spatial patterns of land cover type. The primary difference in hydrograph response is observed on the recession limb of the hydrograph, and that change appears to be associated with higher storm-total runoff in the watersheds with more area draining to SWM. Our findings contribute more evidence to the work of previous authors suggesting that SWM is less effective at attenuating urban hydrographs than is commonly assumed. Our findings also are consistent with previous work concluding that percent impervious cover may have greater influence on runoff volume than percent SWM coverage.     

Forensic geology in serious crime investigation

CSI, Silent Witness , and a host of other recent television dramas have highlighted the role of science in serious crime investigation and detection. Although many 'real' forensic scientists wince at the media portrayal of their discipline, the programmes have led to a wider understanding of the role of different branches of science in criminal investigations. This is not always a good thing, as 'career' or 'professional' criminals will work very hard at being forensically aware to avoid detection, hence any credible forensic scientist might want to be at best a little reticent as to what they do and how they do it. However, in the UK court system evidence presented by the Prosecution team has to be disclosed to the defence and to be open to challenge in court. This article aims to show, in the broadest of terms, how geology is becoming used increasingly in the detection of serious crime.     

Modelling changes in suspended sediment from forest road surfaces in a coastal watershed of British Columbia

Erosion from logging road surfaces, cut slopes, banks, and ditches represents a chronic source of sediment input to streams that can degrade aquatic habitats. Road surface erosion is of particular concern because the magnitude of sediment generation when traffic levels are high can be large. Current models for predicting sediment production from roads require information on area‐specific sediment delivery, which is not often available. Here, we developed a model to quantify suspended sediment concentrations (SSC) generated by forest roads surfaces under different conditions of use and density. This model is designed for a typical medium‐size coastal watershed of British Columbia or the American Pacific Northwest, and was applied to the Chilliwack River watershed as a case study. The results illustrate that intensive use of forest roads combined with high road density can increase the number of extreme sedimentation events over a predetermined threshold. A comparison of the effects of road density and the level of road use suggests that the level of road use is more important than the road density for the generation of fine sediment from road surfaces. However, the model omits the impact of roads on mass movements in a watershed, which represent a major source of sediment in steep watersheds, so the effect of road density is likely more substantial than the model predicts. The model is an attempt to overcome field data limitations by using an empirical relation between SSC and traffic variables, and presents a starting point for more intensive field studies that could be used to validate it. Copyright © 2013 John Wiley & Sons, Ltd.     

Cosmogenic 10Be insights into the extent and chronology of the last deglaciation in Wester Ross,northwest Scotland

Cosmogenic ¹⁰Be surface exposure ages for bedrock sites around Torridon and the Applecross Peninsula in Wester Ross, northwest Scotland, provide new insights into the Lateglacial transition. Accounting for postglacial weathering, six statistically comparable exposure ages give a late Younger Dryas (G‐1) exposure age of 11.8 ± 1.1 ka. Two further outliers are tentative pre‐Younger Dryas exposure ages of 13.4 ± 0.5 ka in Torridon, and 17.5 ± 1.2 ka in Applecross. The Younger Dryas exposure ages have compelling implications for the deglaciation of marginal Loch Lomond Stadial ice fields in Torridon and Applecross. Firstly, they conflict with predictions of restricted ice cover and rapid retreat based on modelling experiments and climate proxies, instead fitting a model of vertically extensive and prolonged ice coverage in Wester Ross. Secondly, they indicate that >2 m of erosion took place in the upper valleys of Torridon and Applecross during the Younger Dryas, implying a dominantly warm‐based glacial regime. Finally, the exposure ages have clarified that corrie (cirque) glaciers did not readvance in Wester Ross, following final deglaciation. Copyright © 2011 John Wiley & Sons, Ltd.     

Forensic geology at the International School Science Fair 2013

In July 2013 the International School Science Fair (ISSF) was hosted by Camborne Science and International Academy, Cornwall, UK. This meeting brings young talented scientists together from around the world to participate in workshops and activities highlighting current scientific developments. As part of ISSF 2013, a workshop on forensic geology was delivered to some of the international participants. This included the preparation of a map to show the mineralogical composition of the soils of the participating schools. The soil mineralogy was determined using automated mineral analysis based on scanning electron microscopy. In addition there were workshops on the recovery of geological trace evidence in a forensic context and the theory and practice of carrying out a geophysical search for hidden items. Data generated as part of this workshop are available to download from the International Union of Geological Sciences, Initiative on Forensic Geology website ( http://www.forensicgeologyinternational.com ).     

Eliciting stakeholder preferences: An application of qualitative and quantitative methods to shrimp aquaculture in the Indian Sundarbans

The Sundarbans region of West Bengal in India is inhabited by small-scale farmers and traditional rice paddy-cum-prawn cultivators. Recent policy initiatives by the Government of India may facilitate expansion of commercial shrimp aquaculture in the future, setting the stage for potential conflicts between local stakeholders. We used qualitative and quantitative methods to analyse the preferences of local stakeholders for alternative management options related to shrimp aquaculture development in the region. We then derived management recommendations for the development of shrimp aquaculture in the region that would minimize the environmental impacts of shrimp aquaculture, distribute the economic benefits of shrimp aquaculture more equally and develop alternative opportunities for income generation, especially for shrimp Fry Collectors.     

Hydrological field data from a modeller's perspective: Part 1. Diagnostic tests for model structure

Hydrological scientists develop perceptual models of the catchments they study, using field measurements and observations to build an understanding of the dominant processes controlling the hydrological response. However, conceptual and numerical models used to simulate catchment behaviour often fail to take advantage of this knowledge. It is common instead to use a pre‐defined model structure which can only be fitted to the catchment via parameter calibration. In this article, we suggest an alternative approach where different sources of field data are used to build a synthesis of dominant hydrological processes and hence provide recommendations for representing those processes in a time‐stepping simulation model. Using analysis of precipitation, flow and soil moisture data, recommendations are made for a comprehensive set of modelling decisions, including Evapotranspiration (ET) parameterization, vertical drainage threshold and behaviour, depth and water holding capacity of the active soil zone, unsaturated and saturated zone model architecture and deep groundwater flow behaviour. The second article in this two‐part series implements those recommendations and tests the capability of different model sub‐components to represent the observed hydrological processes. Copyright © 2010 John Wiley & Sons, Ltd.     

Quaternary bimodal volcanism in the Niğde Volcanic Complex (Cappadocia,central Anatolia,Turkey): age,petrogenesis and geodynamic implications

The late Neogene to Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia is one of the most impressive volcanic fields of Turkey because of its extent and spectacular erosionally sculptured landscape. The late Neogene evolution of the CVP started with the eruption of extensive andesitic-dacitic lavas and ignimbrites with minor basaltic lavas. This stage was followed by Quaternary bimodal volcanism. Here, we present geochemical, isotopic (Sr–Nd–Pb and δ¹⁸O isotopes) and geochronological (U–Pb zircon and Ar–Ar amphibole and whole-rock ages) data for bimodal volcanic rocks of the Ni?de Volcanic Complex (NVC) in the western part of the CVP to determine mantle melting dynamics and magmatic processes within the overlying continental crust during the Quaternary. Geochronological data suggest that the bimodal volcanic activity in the study area occurred between ca. 1.1 and ca. 0.2 Ma (Pleistocene) and comprises (1) mafic lavas consisting of basalts, trachybasalts, basaltic andesites and scoria lapilli fallout deposits with mainly basaltic composition, (2) felsic lavas consisting of mostly rhyolites and pumice lapilli fall-out and surge deposits with dacitic to rhyolitic composition. The most mafic sample is basalt from a monogenetic cone, which is characterized by ⁸⁷Sr/⁸⁶Sr = 0.7038, ¹⁴³Nd/¹⁴⁴Nd = 0.5128, ²⁰⁶Pb/²⁰⁴Pb = 18.80, ²⁰⁷Pb/²⁰⁴Pb = 15.60 and ²⁰⁸Pb/²⁰⁴Pb = 38.68, suggesting a moderately depleted signature of the mantle source. Felsic volcanic rocks define a narrow range of ¹⁴³Nd/¹⁴⁴Nd isotope ratios (0.5126–0.5128) and are homogeneous in Pb isotope composition (²⁰⁶Pb/²⁰⁴Pb = 18.84–18.87, ²⁰⁷Pb/²⁰⁴Pb = 15.64–15.67 and ²⁰⁸Pb/²⁰⁴Pb = 38.93–38.99). ⁸⁷Sr/⁸⁶Sr isotopic compositions of mafic (0.7038–0.7053) and felsic (0.7040–0.7052) samples are similar, reflecting a common mantle source. The felsic rocks have relatively low zircon δ¹⁸O values (5.6 ± 0.6 ‰) overlapping mantle values (5.3 ± 0.3 %), consistent with an origin by fractional crystallization from a mafic melt with very minor continental crustal contamination. The geochronological and geochemical data suggest that mafic and felsic volcanic rocks of the NVC are genetically closely related to each other. Mafic rocks show a positive trend between ⁸⁷Sr/⁸⁶Sr and Th, suggesting simultaneous assimilation and fractional crystallization, whereas the felsic rocks are characterized by a flat or slightly negative variation. High ⁸⁷Sr/⁸⁶Sr gneisses are a potential crustal contaminant of the mafic magmas, but the comparatively low and invariant ⁸⁷Sr/⁸⁶Sr in the felsic volcanics suggests that these evolved dominantly by fractional crystallization. Mantle-derived basaltic melts, which experienced low degree of crustal assimilation, are proposed to be the parent melt of the felsic volcanics. Geochronological and geochemical results combined with regional geological and geophysical data suggest that bimodal volcanism of the NVC and the CVP, in general, developed in a post-collisional extensional tectonic regime that is caused by ascending asthenosphere, which played a key role during magma genesis.