Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Wrench faults,pull-apart basins,and volcanism in central Oregon: A new tectonic model based on image interpretation

A tectonic study of the Newberry Crater region of central Oregon has been based on the interpretation of Landsat Thematic Mapper imagery. Two major faults, the Brothers-Tumalo and Eugene-Denio Faults, pass NW-SE through the region and step to the right at the eastern margin of the Cascades Range. Dextral wrench faulting on these structures during the Tertiary controlled the formation of the La Pine Basin, a pull-apart structure containing Tertiary and Quaternary sediments and volcanics. Tertiary wrench faulting appears to have been associated with rotations of crustal blocks at a plate margin, but was superseded in the Quaternary by extensional faulting of the Basin and Range province. Newberry Crater and other major bimodal volcanic centres in the NW Cordillera (Crater Lake, Medicine Lake, Mt. St. Helens) seem to have a similar tectonic setting in crustal pull-aparts. A relationship between magma type and fault trend at Newberry and Medicine Lake is suggested.     

A deep seismic profile of 800 km length recorded in southern Queensland, Australia

Summary. In 1984, the Australian Bureau of Mineral Resources and the Geological Survey of Queensland recorded a regional seismic reflection profile of over 800 km length from the eastern part of the Eromanga Basin to the Beenleigh Block east of the Clarence Moreton Basin. A relatively transparent upper crustal basement with an underlying, more reflective lower crust is characteristic of much of the region. Prominent westerly dipping reflectors occur well below the sediments of the eastern margin of the Clarence Moreton Basin and the adjacent Beenleigh Block, and provide some of the most interesting features of the entire survey. A wide angle reflection/refraction survey of 192 km length and an expanding reflection spread of 25 km length were recorded across the Nebine Ridge. The only clear deep reflectors are interpreted as P-to-SV or SV-to-P converted reflections from a mid-crustal boundary at a depth of about 17 km. The combined Nebine Ridge data provide well-constrained P and S wave velocity models of the upper crust, and suggest a crustal structure quite different from that beneath the adjacent Mesozoic basins.     

Morphodynamics of a 1000‐year flood in the Kamp River,Austria, and impacts on floodplain morphology

This paper investigates the impact of a 1000‐year flood in August 2002 on floodplains and valley morphology of an Austrian mixed alluvial bed rock river. Discharges with a recurrence interval between 500 and 2000 years caused distinctive overbank scouring and material deposition in the floodplains. After the 1000‐year flood, those morphologically affected areas were at random intervals documented over the whole longitudinal profile. In addition to overbank erosion in curved sections (cut‐offs), the river bed locally widened, floodplain stripping occurred and local overbank scours were documented along straight parts of the river. A hydrodynamic‐numerical model, combined with field measurements, was used to analyse the cause of these erosional landforms. Based on the modelled hydraulic conditions for a one‐year flood (30–78 m³ s^–1) and the catastrophic 2002 event (700–800 m³ s^–1), the numerical results allowed a cause‐effect study with 19 parameters. Deterministic and statistical analysis (ANOVA, discriminant analysis) showed that the morphodynamic effects of the 2002 flood were influenced by the variability of valley morphology of the Kamp River, which led partially to supercritical flow during flood constriction. These processes were in some cases also anthropogenically influenced. Lateral constriction and expansion of the valley geometry over short distances led to scouring and aggradation within the inundated areas during the event. These morphological features were therefore responsible for the elongated scour holes in the floodplains. Copyright © 2009 John Wiley & Sons, Ltd.     

Old, Low-Mass, Metal-Rich (SMR) Stars

The authors of this paper try to disentangle the many problems arisen from a new enlarged sample of nearby low-mass,metal-rich-stars. These stars have reliable absolute magnitudes, deduced from Hipparcos parallaxes, precise bolometric corrections, effective temperatures and metal abundances from high resolution detailed spectroscopic analyses. Their ages have been derived from a grid of isochrones calculated with up to date physics. The main goal of this paper is to determine the ages of the slightly evolved SMR stars. Among those with well determinated ages about 80% of them have intermediate ages of (2 to 5 Gyr), but only 20% have ages of 8 Gyr or more. Nevertheless, the existence of very old metal-rich stars is confirmed. This revised version was published online in July 2006 with corrections to the Cover Date.