光释光测年中石英样品提纯方法的改进

为了解决光释光前处理中遇到的传统方法无法获得满足纯度石英的问题,通过大量对比实验,结合玻璃工艺中石英分离研究成果,最后获得了新的石英提纯流程,与传统方法相比,新方法通过化学分离避免了密度变化对石英长石分离的影响,从而解决了斜长石和岩屑在传统的重液分离中无法剔除的问题,新方法能够获得满足纯度要求和量要求的石英,同时,新方法比传统方法实验室工作效率更高。     

渤海湾盆地垦东凸起北坡馆上段沉积相模式探讨

主要通过岩心观察、粒度分析、参数计算、录测井分析等手段,充分吸收国内外河流研究成果,结合研究区区域地质背景,揭示垦东凸起北坡馆上段沉积相模式。得到以下认识：研究区馆上段地层为河流相沉积,从沉积物特征和平面形态角度可以将研究区馆上段河流沉积理解为介于辫状河及曲流河之间的过渡河型。其平均河道弯曲度大于1.7,垂向层序表现为泥多砂少,具有曲流河的特征;但沉积层序顶部常直接覆盖河漫/洪泛平原沉积,特别是河道内砂坝发育造成河道分汊河,砂坝沉积物粒度特征反映受洪水控制的震荡性特点而与曲流河有重要差别。本文借用在水利学界和地貌学界广为使用的分汊河概念建立了研究区馆上段沉积相模式,包括河床、堤岸、河漫/洪泛平原、废弃河道等4个亚相,组成下粗上细的正旋回。其中,河道砂坝是其主要砂体,顶部常被洪泛平原直接覆盖;决口扇是仅次于河道砂坝的第二大砂体。     

长江中下游湖泊沉积物铅污染记录——以洪湖、固城湖和太湖为例

2002～2005年在长江中下游的洪湖、固城湖和太湖分别采集了沉积物柱样钻孔,测定了总有机碳（TOC）和金属元素包括Pb,Al,Fe,Ti等,并采用210Pb和137Cs进行了近代沉积物定年。研究结果表明,洪湖钻孔平均沉积速率为0.15cm/a,固城湖平均沉积速率在0.067cm/a,太湖平均沉积速率为0.35～0.41cm/a。根据湖泊沉积物中铅元素与参考元素（Al,Fe和Ti）浓度和TOC的相关关系建立了回归方程,线性关系极显著（p<0.001）。根据回归方程获取了钻孔中铅的背景值变化,研究表明近代沉积物中金属铅不仅仅来源于自然的作用,而人类活动导致铅的累积发生时间都在20世纪70年代,从一个侧面也说明利用沉积物铅含量变化进行断代存在可能性。对太湖钻孔而言,其污染程度要高于洪湖和固城湖。研究结果表明近30年来洪湖和固城湖人为造成湖泊沉积物铅累积量在不断增加,其沉积物铅污染有进一步加重的趋势,应受到科学家和管理部门的关注。     

准噶尔盆地液态烃分子碳同位素组成特征及其应用

文章报导了准噶尔盆地不同地区、不同产层原油和烃源岩样品中正构烷烃和类异成二烯烃碳同位素组成特征。在ｎＣ₁₁－ｎＣ₃₄之间，保罗系湖沼相成因的原油，正构烷烃δ13Ｃ值大部分分布在－２７．０‰──３２．４‰之间，比海相地层的原油重，具有富集13Ｃ的特征。ⅡＡ型烃源岩产出原油的单烃δ13Ｃ值比ⅡＢ型的轻，相对富集12Ｃ。碳源组成相同的原油在正构烷烃和类异成二烯烃碳同位素组成上，有相似的分布范围和较为一致的总体变化趋势，因此单烃碳同位素组成可用于油－油对比和油－源对比中。     

湖北寒武系牛蹄塘组页岩气成藏条件与综合评价

牛蹄塘组是湖北省重要的海相页岩气层系之一,对其深入研究有助于预测资源潜力并指明勘探方向.利用露头及探井资料对区内牛蹄塘组的储层特征、资源潜力等进行了研究.结果表明,牛蹄塘组依据岩性组合可以分为一段和二段,鄂西宜昌?恩施、神农架西侧深水陆棚相以及鄂东南盆地边缘相富有机质页岩厚度大,TOC含量高,以硅质类页岩为主,页岩气成藏物质基础良好.气显较好的地区集中分布在鄂西黄陵背斜东南缘,分析认为较弱的变形、有效的顶底板和适中的热演化是牛蹄塘组页岩气富集成藏的关键.除宜昌局部地区具有勘探开发前景外,秭归、鹤峰等地区仍值得探索,鄂东南及鄂西北地区由于构造变形和岩浆活动强烈,保存条件极差,基本无页岩气勘探前景.      

基于面积-高程积分的叶尔羌河山区流域地貌发育特征及其控制因素研究

以叶尔羌河山区流域为研究对象, 利用ArcGIS中的水文分析工具获得1357个集水区的面积-高程积分(HI)值, 定量化研究帕米尔弧形构造带东缘叶尔羌河山区流域的地貌发育特征及其控制因素。结果表明: 1)叶尔羌河山区流域的1357个集水区面积与HI均值的相关性较差(R²=0.0936), 表明集水区面积对HI均值的影响较小; 2)HI值介于0.0717~0.6485, 均值为0.4056, 整体处于地貌发展的壮年期, 是构造、岩性和气候等因素共同作用的结果; 3)HI均值排序为断裂带区域(0.4148)>整个流域(0.4056)>非断裂带区域(0.4004), 表明构造活动是地貌发育的影响因素, 其影响主要表现在断裂带的规模和活动性; 4)非断裂带区域不同岩性的HI均值排序为: 变质岩(0.491353)>冰、雪及现代冰川(0.491351)>花岗岩(0.4426)>海相沉积岩(0.4098)>陆相沉积岩(0.3890)>海陆交互相沉积岩(0.3813)>第四系沉积物(0.3598), 表明岩性是地貌发育的重要影响因素, 且岩石的抗侵蚀能力差异是影响岩性与地貌的关系的重要因素; 5)气候主要通过降水和气温控制河流径流量来影响河流的侵蚀作用和搬运作用进而影响流域内地貌发育, 多年平均年降水对流域的地貌发育的影响较小, 多年平均年气温对流域的地貌发育有特别重要的影响, 是气候对地貌发育的主要控制因素。

     

北半球72 ka BP气候突变事件及其与Toba火山的关系

72 ka BP左右的强降温事件是末次冰期最大的气候突变事件,且同时期发生了第四纪以来最强的火山喷发——Toba火山喷发,后者在此次强降温事件中扮演着什么角色一直是古气候学界研究的热点。对此进行深入的研究,有助于全面评价火山喷发的环境效应,进一步完善末次冰期突变事件的成因机制。系统回顾深海岩芯、极地冰芯、洞穴石笋、黄土、湖泊等古气候载体的研究成果,这些记录对72 ka BP左右的强降温事件和/或Toba火山喷发进行了不同程度的描述,并从不同的角度分析二者的关系。从72 ka BP左右的强降温事件和Toba火山喷发的时间上,以及火山喷发对气候变化影响的机理上看,Toba火山喷发确实对这次强降温事件产生了实质性影响。这个影响在格陵兰冰芯记录中表现得尤为明显,并得到了气候模拟的进一步支持。然而,部分低纬海洋记录研究表明,Toba火山喷发前后气候没有发生显著变化,至少低纬地区的气候不如高纬地区变化明显。古生物研究同时显示出Toba火山喷发并未对其生存环境产生灾难性的影响,由此可见,72 ka BP左右的强降温事件驱动机制及其对Toba火山喷发的响应程度尚存争议。今后的研究应重视提高气候记录分辨率和探测Toba火山喷发证据的研究,从解剖事件的内部结构特征入手,进而建立气候模式与火山效应之间的联系,以此来明确“72 ka事件”驱动机制及其对Toba火山喷发的响应关系。     

Discriminating characters of ore-forming intrusions in the super-large Chalukou porphyry Mo deposit,NE China

The Chalukou porphyry Mo deposit, located in the Great Hinggan Range, is the largest Mo deposit in northeast China, although the age and genesis of the associated magmatic intrusions remain debated.Here we report zircon U-Pb ages and trace elements, whole rock geochemistry and Sre Nd isotope data with a view to understand the relationship between the magmatism and molybdenum mineralization.Zircon U-Pb analysis yield an age of 475 Ma for rhyolite in the older strata, 168 Ma for the premineralization monzogranite, and 154 Ma for the syn-mineralization granite porphyry. The granite porphyry and quartz porphyry are considered as the ore-forming intrusions. These rocks are peraluminous, alkali-calcic, and belong to high-K to shoshonitic series with a strong depletion of Eu. They also display characteristics of I-type granites. The rocks exhibit wide variations of(87 Sr/86 Sr)iin the range of 0.705426 -0.707363, and ε_(Nd)(t) of -3.7 to 0.93. Zircon REE distribution patterns show characteristics between crust and the mantle, implying magma genesis through crust-mantle interaction. The Fe_2O_3/FeO values(average 1) for the whole rock and EuN/Eu*Nvalues(average 0.45), Ce~(4+)/Ce~(3+) values(average 301)for zircon grains from the granite porphyry are higher than those from other lithologies. These features suggest that the ore-forming intrusions(syn-mineralization porphyry) had higher oxygen fugacity conditions than those of the pre-mineralization and post-mineralization rocks. The Chalukou Mo deposit formed in relation to the southward subduction of the Mongol-Okhotsk Ocean. Our study suggests that the subduction-related setting, crust-mantle interaction, and the large-scale magmatic intrusion were favorable factors to generate the super-large Mo deposits in this area.     

Study of late-Mesozoic magmatic rocks and their related copper-gold-polymetallic deposits in the Guichi ore-cluster district,Lower Yangtze River Metallogenic Belt,East China

ABSTRACT

The Guichi ore-cluster district in the Lower Yangtze River Metallogenic Belt hosts extensive Cu–Au–Mo polymetallic deposits including the Tongshan Cu–Mo, Paodaoling Au, Matou Cu–Mo, Anzishan Cu–Mo, Guilinzheng Mo and Zhaceqiao Au deposits, mostly associated with the late Mesozoic magmatic rocks, which has been drawn to attention of study and exploration. However, the metallogenic relationship between magmatic rocks and the Cu–Au-polymetallic deposits is not well constrained. In this study, we report new zircon U–Pb ages, Hf isotopic, and geochemical data for the ore-bearing intrusions of Guichi region. LA-ICP-MS U–Pb ages for the Anzishan quartz diorite porphyrite is 143.9 ± 1.0 Ma. Integrated with previous geochronological data, these late Mesozoic magmatic rocks can be subdivided into two stages of magmatic activities. The first stage (150–132 Ma) is characterized by high-K calc-alkaline intrusions closely associated with Cu–Au polymetallic ore deposits. Whereas, the second stage (130–125 Ma) produced granites and syenites and is mainly characterized by shoshonite series that are related to Mo–Cu mineralization. The first stage of magmatic rocks is considered to be formed by partial melting of subducted Palaeo-Pacific Plate, assimilated with Yangtze lower crust and remelting Meso-Neoproterozoic crust/sediments. The second stage of magmatism is originated from partial melting of Mesoproterozoic-Neoproterozoic crust, mixed with juvenile crustal materials. The depression cross to the uplift zone of the Jiangnan Ancient Continent forms a gradual transition relation, and the hydrothermal mineralization composite with two stages have certain characteristics along the regional fault (Gaotan Fault). Guichi region results from two episodes of magmatism probably related to tectonic transition from subduction of Palaeo-Pacific Plate to back-arc extensional setting between 150 and 125 Ma, which lead to the Mesozoic large-scale polymetallic mineralization events in southeast China.