Compositional heterogeneity of crude oil and its origin in the Linnan subsag, Linyi County, Shandong Province

The Linnan subsag is the main oil producer of the Linpan oil zone. Based on the oil group composition, gas chromatography data and biomarker analysis, it was indicated that crude oils from different oilfields varied greatly in group composition and showed obvious heterogeneities in the aspects of precursor type, crude oil maturity and hydrocarbon depositional environment. According to the characteristics of source rocks, three oil populations can be distinguished, i.e., the southern, northern and transitional oil populations. Furthermore, on the basis of post-reservoir reworking processes, the medium conditions of hydrocarbon-generating environment and differences in maturity, six oil families and twelve sub-families were distinquished. An integrated study suggested that the factors leading to such heterogeneities in crude oil composition mainly include different source rocks, multi-stage oil/gas charging, geo-chromatographic effects during oil/gas migration, reservoir heterogeneities and various post-reservoir secondary alterations.     

湘南铜山岭铜多金属矿床成矿物质来源的 S、Pb、C同位素约束

铜山岭铜多金属矿床是湘南W、Sn、Pb、Zn、Cu多金属矿集区的代表性矿床,本文对其不同类型岩石和矿石矿物进行了S、Pb、C同位素组成对比研究。矿石硫化物的δ34 S值变化范围为-1.9‰~5.7‰,平均值为2.6‰,硫主要来源于硫同位素组成均一化的岩浆。硫化物硫同位素平衡温度表明,矿床主要成矿温度为134~339℃。矿石铅的206 Pb/204 Pb、207 Pb/204 Pb、208 Pb/204 Pb比值分别为18.256~18.856、15.726~15.877、38.352~39.430;岩体岩石铅的206Pb/204Pb、207Pb/204Pb、208Pb/204Pb比值分别为18.617~18.805、15.721~15.786、38.923~39.073;两者铅同位素组成相同,都主要为上地壳铅,是由同一岩浆体系分异形成,可能来源于古老基底岩石。不同类型岩石、方解石矿物的δ13 CPDB值为-9.88‰~1.32‰,δ18 OSMOW值为11.67‰~17.68‰,从矽卡岩矿体到距岩体稍远的围岩地层,方解石矿物的δ13 CPDB、δ18 OSMOW值逐渐增大,成矿流体中的碳早期可能主要来源于岩浆,在成矿过程中有部分碳酸盐岩地层碳的加入。铜山岭矿床成矿物质主要来源于岩浆,赋矿地层对矿床成矿物质来源作用不显著,仅提供了少量成矿物质。     

Changes in soil quality in the critical area of desertification surrounding the Ejina Oasis,Northern China

The critical area around an oasis where desertification occurs determines the ecological security and stability of the oasis. In this study, the soil quality in the critical area of desertification surrounding the Ejina Oasis was evaluated by using a soil quality index (SQI). The soil surface moisture content was related to vegetation cover; it remained high to a distance of 600 m from the oasis, decreased at distances of 600 to 1,700 m, and then gradually increased to a distance of 1,900 m. The sand content and soil bulk density gradually decreased to a distance of 300 m from the oasis; however, the silt and clay contents, soil pH, soil organic matter (SOM), and total and available nutrients increased away from the oasis. From 300 to 1,900 m, the sand content and soil bulk density increased; however, values of other soil properties decreased. Thus, a distance of 300 m from the edge of the oasis represents an obvious demarcation point for soil properties. SOM and the clay content were the key factors that determined soil quality. SQI increased from 0.284 at the edge of the oasis to 0.793 at 300 m, decreased to 0.262 at 1,400 m, and then decreased further to 0.142 at 1,900 m. SQI was lowest at distances of 1,400–1,900 m. The area beyond 300 m from the oasis was most vulnerable to desertification, and is thus the area where desertification control measures should be strengthened.     

库车坳陷中生代海侵事件对有机质的影响

对库车河剖面三叠侏罗系重要生烃组段进行了有机质生物标志化合物及单体烃同位素研究,研究结果表明,海侵层位与非海侵层位在生物组成和生标特征等方面明显不同,海侵带来了不同的生物体,使有机质类型发生了改变。在生物标志化合物参数方面表现为Ｐｒ／Ｐｈ小于１,甾烷含量丰富,甾烷中Ｃ_２７化合物丰度与Ｃ_２９相当,三环萜烷有Ｃ_２１＜Ｃ_２３＞Ｃ_２４的分布特点,单体烃同位素表现出富集轻碳同位素的特点。中生代海侵事件对塔北隆起区及库车拗陷油气资源具有重要的意义。     

MM5数值预报引入GRAPES三维变分同化技术在上海地区的预报和检验

该文简要介绍GRAPES三维变分同化技术在MM5数值预报中的应用；利用2003年3月至2003年5月华东地区138个台站实况资料与其预报结果，评价了该模式系统对华东地区降水的预报结果，分析了三维变分同化对MM5数值预报结果的可能影响。结果表明，GRAPES三维变分同化方案是比较合理的，同化后模式对华东大部分地区的降水24 h预报比没有使用同化的总体情况要好；同样，同化后模式对华东大部分地区的晴雨预报准确率较高。     

冬春亚洲大气环流与华北中部夏季降水的相关分析

利用1957~2002年的NCEP/NCAR 500 hPa再分析资料以及同期华北地区夏季降水资料,分析了华北中部夏季降水与前期环流的关系。结果表明:夏季华北中部降水的多少与冬季东亚槽强弱、春季巴尔喀什湖到贝加尔湖的蒙古高原地区高度场呈显著相关。20世纪80年代中期以前冬季东亚槽偏强、春季蒙古高原地区高度值偏低;80年代中期之后冬季东亚槽开始转弱、春季蒙古高原地区高度值偏高。这与华北夏季降水的演变趋势相对应。说明冬季东亚槽的减弱以及春季蒙古高原地区高度值偏高是近年来华北夏季降水减少的原因之一。冬季东亚槽强对应夏季西太平洋副高在日本海地区高度呈偏强趋势,有利华北中部夏季降水偏多;春季蒙古高原地区高度值偏高有利于华北夏季出现西高东低形势,华北中部夏季降水易偏少。     

在简化的简单生物圈模式中结合新的雪盖模型

本文提出了将一个新的雪盖模型（ＳＡＳＴ）与简化的简单生物圈模型（ＳＳＩ）相结合后的ＳＳＩＢ模型的改进形式，并利用俄罗斯及法国的观测数据对改进后的模型进行了检验。文中描述了改进后的ＳＳＩＢ模型中空气－植被－雪盖－土壤复杂系统之间有关能量和质量交换的过程，并给出为求解这一组非线性方程组所发展的有效计算方法。利用俄罗斯及法国的观测结果对这一新的改进模型功能进行了验证。结果表明改进后ＳＳＩＢ的数值模拟结果能较好地重现现场观测数据，说明这个新的改进形式可以推广用于气候研究。     

The separation mechanism and application of a tapered diameter separation bed

Research on recycling waste printed circuit boards is at the forefront of preventing environmental pollution and finding ways to recycle resources. A wet process for reclaiming metals from printed circuit boards applying a tapered diameter separation bed is described, and the separation mechanism of the device is proposed. The motion of a particle in the tapered diameter fluid flow field and particle separation within this field were studied. As the material passes through the fluid field, along with the water, differences in particle density, granularity, and shape cause particles to follow at different trajectories. A tapered diameter separation bed was used to process 1?C0.074?mm-sized crushed material from discarded printed circuit boards. The separation efficiency of 91.77?% and the recovery rate of 95.79?% for recovered metal were achieved with a discharge water flow rate of 4.5m³/h, a material feed rate of 300?g/min, and an obliquity of 30°. For ?0.074?mm printed circuit boards, the metal recovery is 93.42?% and the separation efficiency is 77.63?% when the water discharge is 2?m³/h, the obliquity is 35o, and the material feed rate is 450?g/min. The superfine products in a size range of ?0.074?mm can be recovered effectively under suitable operating condition using the tapered diameter separation bed. It indicates that the lower separation limit of the tapered diameter separation bed can be close to zero. The technique will prevent environmental pollution from waste printed circuit boards and allow efficient recovery.     

兰州市大气飘尘的有机地球化学研究--Ⅱ.酮和醇脂类化合物的组成和分布特征

首次对兰州市大气飘尘中酮和醇脂类化合物进行了分析和研究。结果表明,兰州市大气飘尘中正烷基２酮和直链烷基醇的浓度分别为２０～２７０ｎｇｍ－３和５２０～９１０ｎｇｍ－３,并表现为３月份高于７月和８月份,这与兰州市特殊的地形和气候条件有关;其分布特征指示了它们来自人为活动、微生物和现代高等植物,而且它们在这３种来源中所占的比例分别为２．８％～１９．７％、１５．４％～３４．６％和５０．３％～８１．８％。甾醇化合物的浓度很低,它们由现代生物所提供。丰富的Ｃ１８类异戊二烯酮化合物的存在,反映了大气飘尘中有机质在大气氧化过程中已经被改造。     

含氟初始风化水化学组成的模型研究

在我国“三北”地区，浅层地下水中高氟苏打水分布广泛。本文利用和简化了Ｈｅｌｇｅｓｏｎ风化模型，以吉林省乾安地区为例，对含氟初始风化水化学组成作了研究和计算：探讨了二氧化碳滴定作用对风化过程的影响，从而定量确定了高氟水的成因模型。