The biogeochemical sulfur cycle in the marine boundary layer over the Northeast Pacific Ocean

The major components of the marine boundary layer biogeochemical sulfur cycle were measured simultaneously onshore and off the coast of Washington State, U.S.A. during May 1987. Seawater dimethylsulfide (DMS) concentrations on the continental shelf were strongly influenced by coastal upwelling. Concentration further offshore were typical of summer values (2.2 nmol/L) at this latitude. Although seawater DMS concentrations were high on the biologically productive continental shelf (2–12 nmol/L), this region had no measurable effect on atmospheric DMS concentrations. Atmospheric DMS concentrations (0.1–12 nmol/m³), however, were extremely dependent upon wind speed and boundary layer height. Although there appeared to be an appreciable input of non-sea-salt sulfate to the marine boundary layer from the free troposphere, the local flux of DMS from the ocean to the atmosphere was sufficient to balance the remainder of the sulfur budget.     

Faunal relationships between the New Zealand plateau and the New Zealand sector of Antarctica based on echinoderm distribution

The problem of New Zealand‐Antarctic faunal relationships is discussed on the basis of echinoderm distribution. The limitations of the data upon which past zoogeographical speculations have been based are pointed out.

Macquarie Island (occupying an intermediate geographical position between the New Zealand Plateau and the Antarctic) shows definite relationships with New Zealand, and the submarine Macquarie Ridge may have provided a connecting migration route. However, only four species of echinoderms are shared between the Ross Sea‐Balleny Islands area (the New Zealand sector of the Antarctic Region) and the New Zealand Pliateau‐Macquarie Island area (the New Zealand Region). Although the as yet unsampled part of the Macquarie‐Balleny Ridge may reveal other faunal similarities, the present systematic sampling has made possible a sounder understanding of the zoogeographical affinities of the two regions.     

A sedimentary record of the rise and fall of the metal industry in Bergslagen,south central Sweden

Detailed stratigraphic analyses of sediments deposited in Lake Botjärnen, a small boreal forest lake in the shield terrain of central Sweden, clearly reflect progressively increasing human impact on terrestrial and aquatic ecosystems following settlement and establishment of an iron industry in the 17th century. Rising frequencies of pollen and spores from light-demanding plants provide evidence of extensive forest clearance for charcoal and timber production, which peaked in the early 20th century. An associated increase in catchment erosion is reflected by changing carbon and nitrogen elemental content and carbon–isotope composition of sediment organic matter and by increased magnetic susceptibility of the sediments. Records of air-borne pollutants (lead, zinc and sulphur) can be correlated to the development of local and regional mining and metal industry as inferred from historical accounts. Rapid recession of the iron industry led to re-forestation and recovery of the aquatic nutrient status to pre-industrial conditions over the past 100 years. The chronology of the sediment succession, which is based on ²¹⁰Pb and ¹³⁷Cs radionuclide data in combination with radiocarbon dating, is confirmed by historical lead pollution trends established for the region.     

Formation of copper—iron sulfide minerals during corrosion of artifacts and possible implications for pseudogilding

Adherent films of the gold-colored metal sulfides pyrite (FeS₂), pyrrhotite (Fe_1−xS), and chalcopyrite (CuFeS₂) are known to exist on metallic and nonmetallic artifacts of Classic times. Consideration of the action of bacterial consortia containing sulfate reducing bacteria (SRB) during microbiologically influenced corrosion (MIC) and analyses of appropriate trajectories on Eh-pH stability diagrams indicate that these films can be understood either as a result of natural processes over archaeological times or of deliberate pseudogilding. Methods of discriminating natural sulfide deposition from pseudogilding are suggested. © 1993 John Wiley & Sons, Inc.     

Aging in Activity Spaces: How Does Individual Accessibility Compare across Age Cohorts?

The proportion of individuals age sixty-five and over is growing at an astronomical rate in the United States, and some estimate that this demographic age group will double by the year 2025. Older adults and adults nearing retirement age tend to reside in suburban neighborhoods and rely heavily on personal vehicles. This study uses travel diary data on automobile trips to construct activity spaces to explore whether or not travel patterns across age groups result in differential access to particular goods and services in the Orlando Metropolitan Statistical Area (MSA). Using an approach based on time geographic density estimation, this research identifies activity spaces across different age cohorts to identify differences in the automobility of different age groups. Results indicate that the geographic dispersion of activities with the Orlando MSA currently favors younger adults. Adults age fifty to sixty-four had the lowest accessibility scores compared to other age cohorts. If this preretirement group has poor access now, holding other effects constant, their access might only get worse as they get older and stop commuting. Transportation is an important consideration in planning for aging populations, and analyzing differences in how older adults travel compared to their younger counterparts can offer insight into the diverse needs of this group. Key Words: accessibility, aging populations, mobility, time geography, transportation.     

The gravitational field of topographic-isostatic masses and the hypothesis of mass condensation II-the topographic-isostatic geoid

In Part I we focussed on a convergent representation of the gravitational potential generated bytopographic masses on top of the equipotential surface atMean Sea Level, thegeoid, and by those masses which compensate topography. Topographic masses have also been condensated, namely represented by a single layer. Part II extends the computation of the gravitational field of topographic-isostatic masses by a detailed analysis of itsforce field in terms ofvector-spherical harmonic functions. In addition, the discontinuous mass-condensated topographic gravitational force vector (head force) is given. Once we identify theMoho discontinuity asone interface of isostatically compensated topographical masses, we have computed the topographic potential and the gravitational potential which is generated by isostatically compensated masses atMean Sea Level, the geoid, and illustrated by various figures of geoidal undulations. In comparison to a data oriented global geoid computation ofJ. Engels (1991) the conclusion can be made that the assumption of aconstant crustal mass density, the basic condition for isostatic modeling, does not apply. Insteaddensity variations in the crust, e.g. betweenoceanic and continental crust densities, have to be introduced in order to match the global real geoid and its topographic-isostatic model. The performed analysis documents that thestandard isostatic models based upon aconstant crustal density areunreal.     

Infrasonic detection of a Leonid bolide: 1998 November 17

Abstract— During the early morning hours of the night of the peak of the annual Leonid meteor shower on 1998 November 17, a bright fireball (approximately ?12 to ?14 visual magnitude at 100 km in the zenith) was observed over northern New Mexico with visual sightings as far away from Los Alamos as Albuquerque (～150 km to the south of Los Alamos), including direct persistent trail observations at the U. S. A. F. Starfire Optical Range (SOR), which is also near Albuqerque. This event did not produce any sonic boom reports, presumably because of its high altitude. It was also detected locally by an infrared radiometer at Sandia National Laboratory and by an intensified charge-coupled device (CCD) camera located in Placitas, New Mexico. Subsequent investigations of the data from the six infrasound arrays used by Los Alamos National Laboratory (LANL) and operated for the Department of Energy as a part of the Comprehensive Test Ban Treaty (CTBT) Research and Development program for the International Monitoring System (IMS) showed the presence of an infrasonic signal from the proper direction at the correct time for this bolide from two of our six arrays (both located in Los Alamos). The infrasound recordings (i.e., the wave amplitude and period data) indicated that an explosion occurred in the atmosphere at a source height of ～93.5 km (with respect to sea level) or ～90 km with respect to the altitude of Los Alamos, having its origins slightly to the north and west of Los Alamos. Purely geometric solutions from the ground observers reports combined with direct measurements from the CCD camera at Placitas produced a source height of 91 ± 7 km. The signal characteristics analyzed from 0.5 to 3.0 Hz include a total duration of about 3–4 s for a source directed from Los Alamos toward 353.6 ± 0.4° measured from true north at a maximum elevation arrival angle of ～72.7°. The latter was deduced on the basis of the observed signal trace velocities (for the part of the recording with the highest cross-correlation) and ranged from a constant value of about 920–1150 m/s (depending on the window length used in the analysis) for a ray trajectory along a direct refractive path between the source and the Los Alamos arrays. The dominant signal frequency at maximum amplitude at Los Alamos was ～0.71 Hz. These highly correlated signals had a peak to peak, maximum amplitude of ～2.1 microbars (0.21 Pa). Using several methods that incorporate various observed signal characteristics, total distance traveled, etc., our analysis indicates that the bolide probably had a source energy of ～1.14 t (TNT equivalent) or 4.77 × 10⁹ J. This is ～14.1× smaller than the source energy estimate made using the infrasonic, empirical source energy relationship for low-altitude stationary point sources developed in the 1960s by the Air Force Technical Applications Center (AFTAC), Patrick Air Force Base, Florida. This relation was originally developed, however, for much larger source energies and at much longer ranges.     

The polarization of starlight in NGC 654 and IC 5146

Two very young star clusters, NGC 654 and IC 5146 are studied using photographic polarization measures with limiting magnitudeB=15m,with a view to determining the nature of magnetic fields in the vicinities of these clusters.Starlight from NGC 654 is found to be polarized in a direction parallel to the galactic plane, the fainter members being more strongly polarized than the brighter ones.Polarization of starlight in IC 5146 is found to be very variable in both magnitude and direction, indicating the presence of complex magnetic fields within the cluster.