Production of a molybdophore during metal-targeted dissolution of silicates by soil bacteria

Although many bioessential metals are scarce in natural water and rock systems, microbial secretion of high-affinity ligands for metal extraction from solid phases has only been documented for Fe. However, we have discovered that Mo is extracted from a silicate by a high-affinity ligand (a possible “molybdophore”) secreted by an N₂-fixing soil bacterium. The putative molybdophore, aminochelin, is secreted as a siderophore under Fe-depleted conditions, but is also secreted under Fe-sufficient, Mo-depleted conditions. Presumably, molybdophore production facilitates uptake of Mo for use in Mo enzymes. In contrast, an Fe-requiring soil bacterium without a special Mo requirement only enhances the release of Fe from the silicate. Fractionation of Mo stable isotopes during uptake to cells may provide a “fingerprint” for the importance of chelating ligands in such systems. Many such metal-specific ligands secreted by prokaryotes for extraction of bioessential metals, their effects on Earth materials, and their possible utility in the recovery of economic metals remain to be discovered.     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

金塔绿洲风场与温湿场特征的数值模拟

使用美国NCAR新版MM5V3.6非静力平衡模式,采用三重嵌套的降尺度方法,模拟研究了甘肃河西走廊金塔绿洲风场与温湿场特征。结果表明:由于绿洲的存在,绿洲沙漠系统产生的次级环流对局地环流有一定影响;平流作用将沙漠中的干热空气送向绿洲,绿洲近地层会出现逆温,感热向地表输送;沙漠上由于临近绿洲的水汽平流作用,上层大气湿度比低层更大,这就是逆湿现象。     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...     

Geology and activity around volcanoes on Io from the analysis of NIMS spectral images

The last two successful flybys of Io by Galileo in 2001 (orbits I31, I32) allowed the Near Infrared Mapping Spectrometer to enrich its collection of IR spectral image cubes of the satellite. These data cover hemispheric portions of Io, several volcanic centers as well as their surroundings with a spatial resolution ranging from 2 to 93 km pixel⁻¹. They map thermal emission from the hot-spots and the distribution of solid SO₂ in the 1.0-4.7 μm spectral range. We obtain maps of SO₂ abundance and granularity from the NIMS data using the method of Douté et al. (2002, Icarus 158, 460-482). The maps are correlated to distinguish four different physical units that indicate zones of SO₂ condensation, metamorphism and sublimation. We relate these information with visible images from Galileo's Solid State Imaging System and with detailed mapping of the thermal emission produced by Io's surface. Our principal goal is to understand the mechanisms controlling how lava, pyroclastics and gas are emitted by different types of volcanoes and how these products evolve. The 800 km diameter white ring of fallout created by a violent “Pillanian” eruption during summer of 2001 is at least partly composed of solid SO₂ and has enriched preexisting regional deposits. Orange materials have been recently or are currently emplaced 240 km south from the main eruption site, possibly as sulfur flows. A similar event may have taken place in the past at Ababinili Patera (12.5° N, 142° W). Carefull study of SO₂ maps covering the Emakong region also suggests that sulfur forms the bright channel-fed flow emerging from the south eastern side of the caldera. Within the main caldera of Tvashtar Catena completely cooled patches of crust exist. Elsewhere, the caldera is still cooling from previous episodes of flooding. We confirm that Amirani emits constantly large amount of SO₂ gas by interaction of fresh lava with the volatiles of the underlying plains. Nevertheless SO₂ frost is not the major component of the bright white ring seen in the SSI images. Over the whole Gish Bar region, SO₂ frost seems barely stable and is constantly regenerated. The stability increases along gray filamentary structures which could be faults filled with materials having peculiar thermal properties. Northwest of Gish Bar Patera, a localized bright deposit shows an unusual spectral signature potentially indicative of H₂O molecules forming ice crystals or being trapped in a nonidentified matrix. The Chaac region may present a thickened old crust reducing the geothermal flux to levels lower than 0.5 W m⁻² and thus creating a cold trap for SO₂. Looking at the abundance and degree of metamorphose of SO₂, we establish the relative age of different flows and ejecta for the Sobo Fluctus. Finally the assumption that the white patches in visible images indicate SO₂ rich deposits is once again challenged. In the Camaxtli region we identify a topographically controlled compact white deposit showing only moderate SO₂ abundance. In contrast, we detect two spots of quite pure SO₂ ice on the gray flanks of Emakong. Furthermore, the close association of fumarolic SO₂ and red S₂ already noted for several volcanic centers is observed at Tupan.     

Penetrative convection in rotating fluids: A model for the base of stellar convection zones

Abstract

To model penetrative convection at the base of a stellar convection zone we consider two plane parallel, co-rotating Boussinesq layers coupled at their fluid interface. The system is such that the upper layer is unstable to convection while the lower is stable. Following the method of Kondo and Unno (1982, 1983) we calculate critical Rayleigh numbers R_c for a wide class of parameters. Here, R_c is typically much less than in the case of a single layer, although the scaling R_c～T^2/3 as T → ∞ still holds, where T is the usual Taylor number. With parameters relevant to the Sun the helicity profile is discontinuous at the interface, and dominated by a large peak in a thin boundary layer beneath the convecting region. In reality the distribution is continuous, but the sharp transition associated with a rapid decline in the effective viscosity in the overshoot region is approximated by a discontinuity here. This source of helicity and its relation to an alpha effect in a mean-field dynamo is especially relevant since it is a generally held view that the overshoot region is the location of magnetic field generation in the Sun.     

Climatic response of thick leaf spruce (Picea crassifolia) tree-ring width at different elevations over Qilian Mountains, northwestern China

Tree-ring cores of thick leaf spruce (Picea crassifolia) taken from four sites at different elevations, in the middle of the Qilian Mountains, in the arid and semi-arid region of northwestern China, were used to develop four tree-ring width chronologies using standard dendrochronological methods. Results indicate that with increasing altitude the chronologies’ year-to-year variations decreased. Hence, the sensitivity of the tree-ring chronologies to climate decreases with altitude. Further analysis showed that the significant limiting factor on tree growth is spring precipitation. Measurements of stomata density and leaf dry weight suggest the species’ ecological adaptation strategy changes with elevation. At high elevation the metabolic rate of thick leaf spruce decreases, thus showing the effect of the climate.     

Possible representation for discovery observations of stellar flares

It is shown that the chronology of flare star discoveries in the Pleiades cluster and the Orion association can be described satisfactorily by various distribution functions (gamma, binomial, decreasing exponential, and delta) for the mean frequencies of stellar flares. However, it has been found that this is due to the uncertainty in the observationally derived distribution function for the mean frequency of stellar flares. The most likely function is that derived by Ambartsumian, which has a physical basis.Translated fromAstrofizika, Vol. 38, No. 1, pp. 25–32, January–March, 1995.