Dives into outer Coronado Canyon System

Dives in Lockheed's submarine “Deep Quest” followed the floor of the fan valley and outer gorge of Coronado Canyon, southwest of the California—Baja California border. Both the fan valley and outer gorge have meandering courses. Basin depressions and intermittent steep descents characterize the outer gorge. No indications were found of recent activity of turbidity currents at either location, but a sand layer 30 cm below the surface is interpreted as related to a lower stand of sea level at the close of the last ice age. Abundant organisms were seen on the valley floor and in the overlying water.     

Deep tow studies of the Tamayo transform fault

The Tamayo transform fault occurs at the north end of the East Pacific Rise where it enters the Gulf of California. The two deep-tow surveys reported here show that the transform fault zone changes significantly as a function of distance from the spreading center intersections. At site 1, near the intersection, one side of the fault is young and the fault zone is narrow and well-defined. Strike slip occurs in a zone approximately 1-km wide suggesting a correspondingly narrow zone of decoupling between the Pacific and North American plates. On the young side of the strike-slip zone, normal faults occur along shear zones which are 45°–50° oblique to the transform strike. They occur parallel to the short axis of the strain ellipse for transform fault strain here, i.e., perpendicular to the least compressive stress. The transform walls are formed by normal faulting as has been pointed out in previous detailed surveys. Here, however, the age contrast of 2.5 m.y. across the transform valley is apparent in the morphology of the normal fault scarps. While the scarps are steep and well-defined on the young side, the scarps on the older side have gradual 10°–30° slopes and appear to be primarily talus ramps. Apparently, the scarps have been tectonically eroded by continued strike slip activity after the initial stages of normal faulting. Thus, transform valleys should be quite asymmetric in cross-section where there is a significant age contrast and one side is less than approximately 0.5 m.y. old. Also, along older sections of the transform valley walls, normal faulting may not be at all obvious due to degradation of the scarps by tectonic erosion. This phenomenon makes the likelihood of transform faults providing windows into the oceanic crust most unlikely except in special cases.The picture of transform deformation is more complex at site 2 in the central portion of the fault where both sides of the fault are greater than 1 m.y. old. Here the transform valley is wider (25–30 km as opposed to 2–5 km). There is no clear simple zone of strike slip tectonics. In fact, the only clear evidence for deformation is the intrusion of magmatic or serpentinite diapirs through the sediments of the transform valley floor. The diapirs have deformed the turbidite layers flooring the valley and in one carefully studied case the turbidite sequence has been uplifted, perched atop the diapir. The pattern of deformation on this outcropping diapir shows radial and concentric fractures which can be modeled by a vertical intrusion circular in plan view. Magnetic studies limit the possible composition to basalt or serpentinite. A 60-km-long median ridge is also likely to be the product of intrusion along the transform fault. The survey at site 2 pointed out the importance of vertical tectonics in the transform valley floor and in particular the importance of diapiric intrusions of either basaltic or serpentinite composition.Based on initial boundary conditions and present tectonic elements in the Tamayo fault zone, a possible history of the mouth of the Gulf of California is outlined. The median ridge was emplaced starting approximately 0.8 m.y. ago by regional extension across the transform fault, the result of leaky transform faulting. The diapirs occur along a possible relay zone of extension midway along the fault which began approximately 0.15 m.y. ago. The extension in this case is parallel to the trend of the transform fault, is still occurring at present, and may evolve into a true spreading center.Contribution of the Scripps Institution of Oceanography, new series.     

Comparison of three oxidation methods used for the analysis of the dissolved organic carbon in seawater

Three methods for the determination of dissolved organic carbon in seawater were compared. Samples were analysed using persulphate oxidation, high-temperature combustion, and ultraviolet photo-oxidation. The dissolved organic carbon content of the seawater samples ranged from 0.6 to 1.6 mg C/I. This study shows that results of high-temperature oxidation and photo-oxidation procedures differ by less than 5%, whereas results with persulphate oxidation are about 15% less than those obtained with the high-temperature oxidation. The relative merits of each of the oxidation techniques for the determination of organic matter in seawater are discussed.     

Seasonal variation of zinc in the barnacle, Balanus balanoides (L.) maintained on a raft in the Menai Strait

A population of the intertidal barnacle, Balanus balanoides (L.) maintained on a raft in the Menai Strait was sampled regularly over a two-year period and pooled fractions analysed for zinc and other trace metals. The seasonal variation of zinc in three fractions (body, other soft tissues and shell) has been followed and related to physiological condition. The body accumulates zinc almost continuously whilst this trace metal accumulates in the ovary only as it develops and is lost in the gametes when these are laid. The newly formed egg-masses therefore may be the more useful sample for indicating zinc pollution.     

Enhanced geochemical gradients in a marine shallow-water hydrothermal system: Unusual arsenic speciation in horizontal and vertical pore water profiles

The shallow marine hydrothermal vents near Ambitle Island in eastern Papua New Guinea discharge hot, slightly acidic, As-rich, chemically reduced fluid into cool, slightly alkaline, oxygenated seawater. Gradients in temperature, pH, and total As (As^T), among others, are established as the two aqueous phases mix. The hydrothermal fluid contained 900 μg/L As^T, almost exclusively present as the reduced As^III, while local seawater measured between 1.2 and 2.4 μg/L As, with approximately equal levels of As^III and As^V. Of particular interest in this study was As speciation and abundance in pore waters as a function of sediment depth and as a function of distance from the area of focused venting. With increasing distance, As^T concentration in the pore water decreased rapidly, but remained elevated up to 300 m from the area of focused venting when compared to a non-hydrothermal control site. As a function of depth (to 100 cm) As^T concentration in the pore water profiles was elevated and generally increased with depth. Surprisingly, aqueous As^V far exceeded aqueous As^III at almost all distances and depths investigated, while at the control site the As^III concentration exceeded that of As^V. In the Tutum Bay hydrothermal system, chemical disequilibria among As species provide potential metabolic energy for arsenite oxidizing microorganisms where hydrothermal fluid mixes with seawater near the vent orifice, and for arsenate reducing microorganisms with increasing distance and depth from the hydrothermal point source.     

Geochemical processes controlling the spatial distribution of selenium in soil and water,west central South Dakota,USA

Selenium (Se) is essential in the human diet, but has a low threshold for toxic concentration. It is recommended that nutrients such as Se should be consumed through foods as part of a normal diet. Se concentrations in crops and meat depend on the amount of labile Se in the soil where crops and forage are grown. Therefore, managing agriculture for optimal Se in grain crops and forage requires an understanding of the distribution and mobility of Se. Elevated concentrations of Se occur in waters, soils, and forage 120 km west of Pierre in west central South Dakota, USA. The research site lies in an elevated, dissected plain where soils developed on gently dipping Pierre Shale. Soils were sampled along catena transects and waters collected from soil, ponds, and shallow borings in areas of known elevated forage and crop Se. Soil extracts from saturated-paste extraction and acid (aqua regia and hydrofluoric acid) extraction were analyzed. Selenate was the dominant Se species in both acid and saturated-paste extracts; selenite and organic Se were below detection (<0.2 ppb) in the same soil extracts. On average, 98% of soil Se was not water-soluble. The distribution of total Se shows much less spatial variation than water-soluble Se in the areas sampled. Se shows correlation with organic carbon in soils and waters, suggesting its association with organic carbon. Ca shows some correlation to Se in acid extracts, but not in saturated-paste extracts or in waters. Total Se shows no significant correlation to Na, Mg, and total S in the soils. Se in saturated-paste extracts and water samples shows good correlations with Na, Mg, and SO₄, suggesting that evaporitic Na–Mg–sulfate minerals may temporarily concentrate water-soluble Se in shallow soils. The dissolution and precipitation of these Na–Mg–sulfate salts together with pH and oxidation–reduction conditions apparently control water-soluble Se distribution and mobilization in shallow subsurface environments.     

Way forward to achieve sustainable and cost-effective biofuel production from microalgae: a review

Driven by policies aimed at enhancing energy security and mitigating greenhouse gas emissions, the production and use of biofuels have significantly increased in recent years. Microalgae owing to its multiple advantages which include high lipid content, sustainable biomass production, effective land and water utilization are the most potential biofuel feedstock that can provide drop-in fossil fuel replacements without stimulating competition for agricultural resources and are considered to be more environmentally benign than the first- and second-generation biofuel feedstocks. However, there are many existing technical and scientific impediments that are yet to be resolved. Keeping this in view, the present review provides a concise account of the microalgal species known to accumulate high levels of lipid and describes the main factors that should be taken into consideration while selecting suitable algal strains for mass cultivation. The underlining advantages and limitations of raceway pond and photobioreactor cultivation systems are also examined. The recent advances in genetic engineering of microalgae to improve biomass and lipid productivity are then highlighted, which include the ongoing debate over the biosafety issues pertinent to the use of genetically modified algae. Furthermore, a wide range of high-value products that can be co-produced from microalgae have been discussed. The review concludes with a comprehensive summary of the major techno-economic constraints to commercialization of algal-derived biofuels along with promising methods for overcoming these challenges in order to produce cost-competitive and environmentally sustainable biofuel.     

Mineralogy and geochemistry of lateritic soil profiles in Kerala, India

Lateritic soils near Calicut, Kerala, contain halloysite of intermediate hydration, kaolinite, goethite, gibbsite and quartz. The presence of halloysite is responsible for relatively high plasticity and cation-exchange capacity. Fe-hydroxide colloids along with halloysite contribute to significant phosphate uptake by this soil. Composition of local groundwater is consistent with weathering of sodic plagioclase to gibbsite, kaolinite and metastable halloysite.     

Platinum-group minerals in quaternary gold placers in the upper Chindwin area of northern Burma

In the Chindwin Basin in northern Burma, there is a system of five Pleistocene terraces in which gold placers with low concentrations of platinum-group minerals (PGM) occur. Samples were taken from four sites in the Chindwin Basin and one from near an ophiolite occurrence on the northeast side of the Chindwin Basin; they were studied under the microscope, with a scanning electron microscope, and an electron microprobe. The main minerals were Pt-Fe and Os-Ir-Ru alloys, usually in a ratio between 2 and 5. In most cases, the shape of the grains allowed a quick distinction between the two types. Sperrylite, laurite, irarsite, cooperite, tulameenite, and isomertieite occur infrequently as individual mineral grains and sometimes as inclusions in the alloy grains. Braggite, platarsite, hollingworthite, bowieite, keithconnite, cuproiridsite, malanite, stibiopalladinite, geversite, kashinite, several unnamed PGM, and Fe, Ni, and Cu sulfides were observed as inclusions, mainly in the Pt-Fe alloys and also to a lesser extent in the Os-Ir-Ru alloys. Lamellar and myrmekite-like intergrowths, oriented exsolution lamellae, and idiomorphic inclusions of sulfides in the alloys indicate a magmatic origin of the PGM. The origin of the PGM is assumed to be ophiolites in northern Burma. A continual decrease in mean grain size occurred during transport.

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Platingruppenminerale in quartären Goldseifen im oberen Chindwingebiet in Nord-Burma

Zusammenfassung Im Gebiet des Chindwin Basin in Nordburma ist ein System von fünf pleistozänen Terrassen ausgebildet, in denen Goldseifen mit geringen Anteilen an PGM auftreten.PGM-Konzentrate von vier Vorkommen des Chindwin Basin und eine weitere Probe aus der Nähe eines Ophiolithvorkommens im Nordosten des Chindwin Basin wurden mit optischer Mikroskopie, Rasterelektronenmikroskopie und Mikrosonde untersucht.Hauptmineralien sind Pt-Fe-Legierungen und Os-Ir-Ru-Legierungen in einem Verhältnis von 2: 1 bis 5: 1. Ihre Morphologie kugeliger oder plattiger, teilweise idiomorpher Körner erlaubt in den meisten Fällen eine rasche Identifizierung der beiden Typen. Sehr selten treten als Einzelminerale, aber auch als Einschlüsse in Legierungen, Sperrylith, Laurit, Irarsit, Cooperit, Tulameenit und Isomertieit auf. Braggit, Platarsit, Hollingworthit, Bowieit, Keithconnit, Cuproiridsit, Malanit, Stibiopalladinit, Geversit, Kaschinit, einige unbekannte PGM und Fe-, Ni- und Cu-Sulfide wurden nr als Einschlüsse, hauptsächlich in Pt-Fe-Legierungen, weniger in Os-Ir-Ru-Legierungen, beobachtet.Lamellare und myrmekitische Verwachsungen, orientierte Entmischungen und idiomorphe Einschlüsse von Sulfiden in Legierungen weisen auf eine magmatische Entstehung der PGM hin. Die Herkunft der PGM wird in Ophiolithen Nordburmas vermutet. Beim Transport hat eine kontinuierliche Abnahme der mittleren Korngrösse stattgefunden.

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With 8 Figures