Disequilibrium for Ca during growth of pelitic garnet

Compositional zoning in hundreds of almandine-rich garnets in amphibolite by facies micaceous quartzites from the Picuris Range, north-central New Mexico USA, indicates that although Mn, Mg and Fe achieve chemical equilibrium at hand-sample scale during garnet growth, Ca does not. Instead, Ca concentrations at the surface of growing garnets appear to depend strongly on kinetic factors that govern the local chemical environment, yielding disequilibrium for Ca at scales larger than the region immediately surrounding an individual porphyroblast. Detailed zoning profiles were obtained for 371 garnet crystals in a small volume of a single sample of garnetiferous quartzite, and core analyses were made of 97 additional crystals. Each analysis was made on a section that passed precisely through the morphological centre of the crystal, located by means of 3-D imagery from computed X-ray tomography. The data reveal strong correlations between crystal size and concentrations of Mn, Mg and Fe (but not Ca) in garnet cores; a relationship between crystal size and isolation; rigorous cross-correlations among concentrations of Mn, Mg and Fe (but not Ca); and systematic variations in Ca concentrations as a function of crystal size and core composition that are anomalous in comparison to the behaviour of the other divalent cations. We interpret these observations as the result of thermally accelerated diffusion-controlled garnet growth, in circumstances that promoted rapid intergranular diffusion and thus rock-wide equilibration of Mn, Mg and Fe, but that prevented equilibration at similar scale for Ca because of its more sluggish intergranular diffusion. The anomalous behaviour of Ca is made evident in these garnets by the presence of sharp spikes in Ca concentration, which are demonstrably not a consequence of any simultaneous rock-wide event, such as a change in pressure, temperature, or some other intensive parameter. Instead, Ca concentrations probably reflect the local extent of reaction in the immediate vicinity of each porphyroblast. To the degree that such kinetic factors introduce departures from chemical equilibrium for Ca, thermobarometric estimates that involve grossular contents of pelitic garnet will be in error.     

Timing and exhumation of eclogite facies shear zones, Musgrave Block, central Australia

Timing constraints on shear zones can provide an insight into the kinematic and exhumation evolution of metamorphic belts. In the Musgrave Block, central Australia, granulite facies gneisses have been affected, to varying degrees, by mylonitic deformation, some of which attained eclogite facies. The Davenport Shear Zone is a dominant strike-slip system that formed at eclogite facies conditions ( T  ≈650  °C and P ≈12.0  kbar). Sm–Nd mineral isochrons obtained from equilibrated high-pressure assemblages, as well as ⁴⁰Ar–³⁹Ar data, show that the eclogite and greenschist facies high-strain overprints were coeval, at c .  550  Ma. Mylonitic processes do not appear to have reset the U–Pb system in zircon, but may have partially disturbed it. The thermal gradient in the Musgrave Block crust at c .  550  Ma was c .  16  °C  km⁻¹ and at c .  535  Ma was c .  18  °C  km⁻¹, based on P – T  estimates of eclogite and greenschist facies shear zones, respectively. These estimates are similar to present-day geothermal gradients in many stable continental shield areas, suggesting that the region did not undergo a significant transient perturbation of the geotherm. Therefore, in the Musgrave Block, cooling subsequent to eclogite facies metamorphism appears to have been controlled by exhumation, rather than by the removal of a heat source. Estimated exhumation rates in the range 0.2 to ≥1.5  mm year⁻¹ are comparable with other orogenic belts, rather than cratonic areas elsewhere.     

UV Laser Ablation ICP-MS: Some Applications in the Earth Sciences

This study reports a series of applications of UV laser ablation ICP-MS in the geological sciences. The advantages and disadvantages of the PQ "S" option and the use of nitrogen in the carrier gas are discussed. A general problem common to all ablation techniques is the calibration technique and experiments involving synthetic calibration samples are covered. Zircon geochemistry and geochronology by LA-ICP-MS are discussed and data are presented for REE, Hf and U for a standard zircon (91500) as well as a series of zircons from Zimbabwe. The potential of using Ce and Eu anomalies in petrologic studies is illustrated by zircons from a fractionated gabbroic-granite in the Urals. The potential of the LA-ICP-MS method to utilise standard X-ray fluorescence glass discs is demonstrated as a useful semi-quantitative tool in determining REE patterns. LA-ICP-MS is a powerful tool in the analysis of the platinum group elements (and Re) and some examples are given in the successful application of the technique to partitioning in iron meteorites.     

Two stages of zircon and monazite growth in anatectic leucogneiss: SHRIMP constraints on the duration and intensity of Pan-African metamorphism in Prydz Bay, East Antarctica

SHRIMP U–Pb data from two samples of foliated anatectic leucogneiss bracket the high-grade metamorphic history of metasediments from southern Prydz Bay, East Antarctica. Magmatic zircons in these two samples have mean crystallization ages of 535 ± 13 and 536 ± 35 Myr, and provide a good estimate for the timing of peak metamorphism and partial melting. Low-Th monazite grains in the same samples have mean ages of 528 ± 4 and 527 ± 11 Myr, which are within error of the zircon ages but may reflect a lower blocking temperature. High-Th monazite rims with younger mean ages of 518 ± 3 and 512 ± 13 Myr occur around low-Th cores in both samples, and were precipitated from hydrous fluids released during the crystallization of residual melts. These magmatic fluids were channelled along the retrograde foliation present in both samples. All mineral assemblages and fabrics preserved in the metasediments reflect intense Pan-African metamorphism and deformation, associated with high degrees of partial melting and significant vertical displacements of the crust. Continental reconstructions assuming limited Pan-African tectonism in East Antarctica should be reassessed in the light of these new data.     

Organic pollutants associated with macromolecular soil organic matter: Mode of binding

A study of ether-linked moieties in macromolecular bound residues of polycyclic aromatic hydrocarbons (PAH) generated in bioremediation experiments was performed using high temperature hydrolysis degradation with subsequent analysis of the products by GC-MS. This hydrolysis reaction was specifically designed to cleave ether bonds including relatively stable diarylether structures. Among the reaction products, aromatic alcohols representing typical microbiologically derived metabolites of PAH were found in addition to natural compounds. Thus, parts of the bound residues appeared to be linked within the macromolecular material by ether bonds. Model experiments with an oxidoreductase enzyme and aromatic alcohols indicate the formation of these ether bonds to be an enzyme-catalysed process.     

中国汽车工业──改革开放后的重整与国际化

大规模的重整和广泛的国际化是改革开放后中国汽车工业发展的两个主要特征。作者首先从企业组织结构、生产能力与品种结构、规模经济和空间分布等四个方面分析了近二十年来中国汽车工业重整的效果及所形成的行业特征;其次根据利用的外资和技术的来源以及涉及的技术形态分析了其国际化的程度及在世界汽车工业中的位置;最后总结了中国汽车工业面临的若干问题,并提出在散乱的格局和跨国公司竞争的双重压力下,中国汽车工业正处于成长的关键时期。     

Hydrologic and climatic implications of a multidisciplinary study of late Holocene sediment from Kenosee Lake, southeastern Saskatchewan, Canada

Sediment lithology and mineralogy, as well as ostracode, plant macrofossil and stable isotope stratigraphies of lake sediment cores, are used to reconstruct late Holocene hydrologic changes at Kenosee Lake, a relatively large, hyposaline lake in southeastern Saskatchewan. Chronological control is provided by AMS radiocarbon ages of upland and shoreline plant macrofossils. All indicators outline an early, low-water, saline phase of lake history (4100–3000 BP), when the basin was occupied by a series of small, interconnected, sulfate-rich brine pools, as opposed to the single, topographically-closed lake that exists today. A rapid rise in lake-level (3000–2300 BP) led to the establishment of carbonate-rich, hyposaline lake conditions like those today. Lithostratigraphic data and ostracode assemblages indicate peak salinities were attained early in this period of lake infilling, suggesting that the lake-level rise was initially driven by an influx of saline groundwater. Lake-level and water chemistry have remained relatively stable over the last 2000 years, compared to earlier events. Because of a lack of datable organic material in sediments deposited during the last 2000 years, the chronology of recent events is not well resolved. Plant macrofossil, lithostratigraphic and ostracode evidence suggests that lake draw-down, accompanied by slightly higher than present salinites, occurred sometime prior to 600 BP, followed by peak lake-level and freshwater conditions. This most recent high lake stand, indicative of a high water table on the surrounding upland, may also have led to the establishment of an extensive cover of Betula in the watershed, possibly in response to paludification. Ostracode assemblages indicate that peak freshwater conditions occurred within the last 100 years. Since historically documented lake-level fluctuations correlate with decadal scale climatic fluctuations in the meteorological record, and late-Holocene hydrologic dynamics correspond to well documented climatic excursions of the Neoglacial and Little Ice Age, Kenosee Lake dynamics offer insight into the susceptibility of the region's water resources to climate change.     

Recovering magnetic susceptibility from electromagnetic data over a one-dimensional earth

While the inversion of electromagnetic data to recover electrical conductivity has received much attention, the inversion of those data to recover magnetic susceptibility has not been fully studied. In this paper we invert frequency-domain electromagnetic (EM) data from a horizontal coplanar system to recover a 1-D distribution of magnetic susceptibility under the assumption that the electrical conductivity is known. The inversion is carried out by dividing the earth into layers of constant susceptibility and minimizing an objective function of the susceptibility subject to fitting the data. An adjoint Green's function solution is used in the calculation of sensitivities, and it is apparent that the sensitivity problem is driven by three sources. One of the sources is the scaled electric field in the layer of interest, and the other two, related to effective magnetic charges, are located at the upper and lower boundaries of the layer. These charges give rise to a frequency-independent term in the sensitivities. Because different frequencies penetrate to different depths in the earth, the EM data contain inherent information about the depth distribution of susceptibility. This contrasts with static field measurements, which can be reproduced by a surface layer of magnetization. We illustrate the effectiveness of the inversion algorithm on synthetic and field data and show also the importance of knowing the background conductivity. In practical circumstances, where there is no a priori information about conductivity distribution, a simultaneous inversion of EM data to recover both electrical conductivity and susceptibility will be required.