The typing of Au and base-metal occurrences by plasma/mass spectrometry: initial results

This paper discusses the application of the newly developed ELAN 250 I.C.P./mass spectrometer to exploration geochemistry. This instrument combines an inductively coupled plasma with a quadrupole mass spectrometer. The combination of these two existing technologies makes it possible for the first time to perform stable-isotope and elemental analysis rapidly and concurrently.Particular attention is paid to the use of lead isotopes to type Au and base-metal occurrences. Data are presented on galena samples obtained from the Geological Survey of Canada and the Royal Ontario Museum. Consideration is also given to the potential usefulness of Pb isotopes and trace-element data to type mineral occurrences and to identify new ones.     

Strontium-calcium ratios in Cenozoic planktonic foraminifera

The $\text{Sr}\text{Ca}$ ratio and other parameters have been measured in fossil planktonic foraminifera from the Atlantic and Pacific Ocean basins in order to evaluate the $\text{Sr}\text{Ca}$ ratio of seawater during the last 75 million years. Results on well-preserved samples indicate that the ratio has increased to its present value by 10–15% during the Cenozoic, and that minima occurred between 55-45 Ma and 10-5 Ma, when the ratio was 15–25% less than at present. The long-term increase may reflect either decreasing deposition of aragonite with a high $\text{Sr}\text{Ca}$ ratio in shallow seas, or decreasing seafloor spreading rates and consequently decreasing hydrothermal supply of Ca during the Cenozoic. Other geologic evidence suggests that the Eocene minimum (near 50 Ma) may have resulted from increased aragonite sedimentation, while the Late Miocene minimum (between 10-5 Ma) may have been caused by an increased rate of seawater-basalt exchange when seafloor spreading rates increased on the East Pacific Rise near 10 Ma.     

Long-term monitoring of the behavior of a talus-colluvium deposit

Landslides - This article describes the behavior of a talus-colluvium deposit up to 70-m thick located in the Serra dos Orgaos, Rio de Janeiro/RJ, Brazil. The monitoring dataset of 13 years...     

The influence of minerals on the pyrolysis of kerogens

The effect of mineral matter on the laboratory pyrolysis of sediments, kerogens and coals, and of coal macerals mixed with either alumina, bentonite, kaolinite, or calcium carbonate has been investigated. Some minerals are more active than others in effecting changes in the composition of the pyrolysate. The relative content of low molecular weight pyrolysis products is higher for kerogens pyrolyzed in a mineral matrix than for isolated kerogens. Our limited data suggests that this is due to both condensation and gasification of higher molecular weight constituents in the ‘primary’ pyrolysate. Differences in the content of aromatic versus aliphatic compounds have been noted when pyrograms from coal macerals are compared with pyrograms from coal maceral-mineral mixtures. We conclude that mineralogy is important in controlling the composition of kerogen pyrolysis products.     

Occurrence of a regular C25 isoprenoid hydrocarbon in tertiary sediments representing a lagoonal-type,saline environment

A regular C₂₅ isoprenoid alkane (2,6,10,14,18-pentamethyleicosane) has been isolated from highly saline Tertiary sediments. The isolation utilized elution chromatography, urea adduction and gas chromatography; identification was based on the mass spectrum. This C₂₅ isoprenoid may represent a biological marker, possibly typical for a lagoonal-type, saline environment.     

Reliability of inexpensive charcoal and alpha-track radon monitors

A comparison between single short-term radon measurements and annual radon measurements in basements shows that significant uncertainties should be associated with the short-term measurements. Activated charcoal radon monitors which measure radon over a 3 to 7 day interval yield measurements that should carry a ± 90% uncertainty in terms of estimating annual radon concentration. Alpha-track radon monitors which measure radon over a 3 month interval should carry a ± 30% uncertainty. Decisions about home purchases, home remediation and the development of risk characterizations may often be incorrect if currently popular but unrealistically low estimates of uncertainty are applied to short-term radon measurements. Optimal results are obtained from year-long alpha-track measurements.     

Archean high-Mg monzodiorite–syenite,epidote skarn,and biotite–sericite gold lodes in the Granny Smith–Wallaby district,Australia: U–Pb and Re–Os chronometry of two intrusion-related hydrothermal systems

The Granny Smith (37 t Au production) and Wallaby deposits (38 t out of a 180 t Au resource) are located northeast of Kalgoorlie, in 2.7 Ga greenstones of the Eastern Goldfields Province, the youngest orogenic belt of the Yilgarn craton, Western Australia. At Granny Smith, a zoned monzodiorite–granodiorite stock, dated by a concordant titanite–zircon U–Pb age of 2,665 ± 3 Ma, cuts across east-dipping thrust faults. The stock is fractured but not displaced and sets a minimum age for large-scale (1 km) thrust faulting (D2), regional folding (D1), and dynamothermal metamorphism in the mining district. The local gold–pyrite mineralization, controlled by fractured fault zones, is younger than 2,665 ± 3 Ma. In augite–hornblende monzodiorite, alteration progressed from a hematite-stained alkali feldspar–quartz–calcite assemblage and quartz–molybdenite–pyrite veins to a late reduced sericite–dolomite–albite assemblage. Gold-related monazite and xenotime define a U–Pb age of 2,660 ± 5 Ma, and molybdenite from veins a Re–Os isochron age of 2,661 ± 6 Ma, indicating that mineralization took place shortly after the emplacement of the main stock, perhaps coincident with the intrusion of late alkali granite dikes. At Wallaby, a NE-trending swarm of porphyry dikes comprising augite monzonite, monzodiorite, and minor kersantite intrudes folded and thrust-faulted molasse. The conglomerate and the dikes are overprinted by barren (<0.01 g/t Au) anhydrite-bearing epidote–actinolite–calcite skarn, forming a 600-m-wide and >1,600-m-long replacement pipe, which is intruded by a younger ring dike of syenite porphyry pervasively altered to muscovite + calcite + pyrite. Skarn and syenite are cut by pink biotite–calcite veins, containing magnetite + pyrite and subeconomic gold–silver mineralization (Au/Ag = 0.2). The veins are associated with red biotite–sericite–calcite–albite alteration in adjacent monzonite dikes. Structural relations and the concordant titanite U–Pb age of the skarn constrain intrusion-related mineralization to 2,662 ± 3 Ma. The main-stage gold–pyrite ore (Au/Ag >10) forms hematite-stained sericite–dolomite–albite lodes in stacked D2 reverse faults, which offset skarn, syenite, and the biotite–calcite veins by up to 25 m. The molybdenite Re–Os age (2,661 ± 10 Ma) of the ore suggests a genetic link to intrusive activity but is in apparent conflict with a monazite–xenotime U–Pb age (2,651 ± 6 Ma), which differs from that of the skarn at the 95% confidence level. The time relationships at both gold deposits are inconsistent with orogenic models invoking a principal role for metamorphic fluids released during the main phase of compression in the fold belt. Instead, mineralization is related in space and time to late-orogenic, magnetite-series, high-Mg monzodiorite–syenite intrusions of mantle origin, characterized by Mg/(Mg + Fe_TOTAL) = 0.31–0.57, high Cr (34–96 ppm), Ni (22–63 ppm), Ba (1,056–2,321 ppm), Sr (1,268–2,457 ppm), Th (15–36 ppm), and rare earth elements (total REE: 343–523 ppm). At Wallaby, shared Ca–K–CO₂ metasomatism and Th-REE enrichment (in allanite) link Au–Ag mineralization in biotite–calcite veins to the formation of the giant epidote skarn, implicating a Th + REE-rich syenite pluton at depth as the source of the oxidized hydrothermal fluid. At Granny Smith, lead isotope data and the Rb–Th–U signature of early hematite-bearing wall-rock alteration point to fluid released by the source pluton of the differentiated alkali granite dikes.     

Hydrogeologic studies for nuclear-waste disposal in Sweden

Safety Report 1997 (SR 97) of the Swedish Nuclear Fuel and Waste Management Company is a comprehensive performance assessment of three hypothetical radioactive waste repositories in Sweden. It includes hydrogeologic studies (data compilation, parameter synthesis, and groundwater flow modeling) to determine groundwater flow and the associated uncertainties for the three sites. This report reviews and compares the hydrogeologic characterization programs, the site characteristics, and the groundwater flow models used in the SR 97 performance assessment. Although differences in site-characterization programs tend to mask differences in site characteristics, the sites do have notable differences that affect the results of the performance assessment. The effects of model uncertainties evaluated by the variant cases appear to be smaller than the variability of results for the base case (best estimate of site conditions) of each site. Electronic Publication