Occurrence and turnover of DMSP and DMS in deep waters of the Ross Sea,Antarctica

High concentrations of the phytoplankton metabolite dimethylsulfoniopropionate (DMSP) and its degradation product dimethylsulfide (DMS) are associated with blooms of Phaeocystis antarctica in the Ross Sea, Antarctica. Episodic and rapid vertical export of Phaeocystis biomass to deep water has been reported for the Ross Sea, therefore we examined the distribution and microbial consumption rates of DMSP and DMS throughout the sub-euphotic water column. Total DMSP (dissolved+particulate; DMSPt) was present at 0.5–22 nM at depths between 70 and 690 m during both the early bloom (November) and the late bloom (January). Sub-euphotic peaks of DMSP were sometimes associated with mid-water temperature maxima, and elevated DMSP below 70 m was found mainly in water masses characterized as Modified Circumpolar Deep Water or Antarctic Shelf Water. Overall, 50–94% of the integrated water-column DMSPt was found below the euphotic zone. At one station during the early bloom, local maxima of DMSPt (14 nM) and DMS (20 nM) were observed between 113 and 240 m and these maxima corresponded with high chlorophyll a concentrations, P. antarctica cell numbers, and Fv/Fm (the quantum yield of photosystem II). During the late bloom, a sub-euphotic maximum of DMSPt (15.8 nM) at 250 m cooccurred with peaks of chlorophyll a concentration, DMSP lyase activity, bacterial production and dissolved DMSP consumption rates. DMSP turnover contributed ～12% of the bacterial carbon demand between 200 and 400 m. DMS concentrations peaked at 286 m but the maximum concentration (0.42 nM) was far lower than observed during the early bloom, probably because of relatively rapid biological consumption of DMS (1–3 turnovers per day) which, in turn, contributed to elevated dissolved dimethylsulfoxide (DMSO) concentrations. Relatively stable DMSPt distributions at some sites suggest that rapid sinking of Phaeocystis biomass is probably not the major mechanism responsible for mesopelagic DMSP accumulations. Rather, subduction of near-surface water masses, lateral advective transport or trapping of slowly sinking P. antarctica biomass in intermediate water masses are more likely mechanisms. We found that a culture of P. antarctica maintained cellular integrity during 34 days of darkness, therefore the presence of intact cells (and DMSP) at depth can be explained even under a slow sinking/advection scenario. Whatever the mechanism, the large pools of DMSP and DMS below the euphotic zone suggest that export exerts a control on potential DMS emission from the surface waters of the Ross Sea.     

<Superscript>87</Superscript>Sr/<Superscript>86</Superscript>Sr anomalies in Late Cretaceous-Early Tertiary strata of the Cauvery basin,south India: Constraints on nature and rate of environmental changes across K-T boundary

The Ariyalur-Pondicherry sub-basin of the Cauvery basin comprises a near complete stratigraphic record of Upper Cretaceous-Lower Tertiary periods. Earlier studies have documented variations of clay mineral assemblages, change in microtexture of siliciclasts and many geochemical and stable isotopic anomalies far below the Cretaceous-Tertiary boundary (KTB) in these strata. This paper documents the occurrences of two positive ⁸⁷Sr/⁸⁶Sr anomalies preceding K-T boundary in this basin and discusses plausible causes. Analysis of trace elemental and stable isotopic profiles, sedimentation history, petrography and mineralogy of the rocks reveal that while both the anomalies may be due to increased detrital influx caused by sea level and climatic changes, the second anomaly might have been influenced by Deccan volcanism which in turn predated KTB. Record of such anomalies preceding K-T boundary supports the view of multi-causal step-wise extinction of biota across KTB.     

Derivation of the chalk superficial deposits of the North Downs, England: an application of discriminant analysis

Stepwise discriminant analysis was used on particle size and heavy mineral data from 276 sediment samples, including 39 from published sources, to distinguish between Palaeocene and Plio–Pleistocene deposits, found above the Cretaceous Chalk in southeast England, and to determine parent materials of the soils and superficial deposits of the central North Downs. Of 71 known cases (in situ deposits), 85.9% were correctly classified using textural data (sig. 99.9%), and 89.7% of 29 known cases (sig. 99.9%), using heavy mineral data. The best textural discriminating variables were %sand, graphic mean, %clay and graphic skewness, and the best heavy mineral discriminants were %kyanite plus staurolite, %andalusite and %garnet. Discriminant analysis has achieved good differentiation between marine Plio–Pleistocene sands, Clay-with-flints, loess and Palaeocene groups, and allowed objective classification of sediments of unknown origin. The distribution of parent materials revealed, strongly upholds the earlier interpretation [Z. Geomorphol. 39 (1995) 433] that in the central North Downs, except where Palaeocene residuals survive, the superficial cover above the Chalk consists of in situ Clay-with-flints sensu stricto, beneath Plateau Drift and loess. Clay-with-flints is seen as residual, and Plateau Drift as a Pleistocene soliflucted deposit. Textural affinities of Reading Beds Clay and Clay-with-flints elicited by a third discriminant analysis, using additional published data from 22 samples, suggest their common derivation from Chalk residua.     

Thermal and transport properties of mantle rock at high pressure: Applications to super-Earths

In the present study, the temperature- and pressure-dependent transport and thermal properties, i.e., viscosity, phonon thermal conductivity, thermal expansivity and heat capacities, as well as electronic and radiative thermal conductivities, have been derived for the mantles of super-Earths. These properties are necessary to understand the interior dynamics and the thermal evolution of those planets. We assume that the mantles consist of MgSiO₃ perovskite (pv), but we discuss the effects of the post-perovskite transition, and we elaborate on an addition of periclase MgO and incorporated Fe. However, MgO is found to only significantly influence the phonon thermal conductivity – the viscosities, heat capacities and thermal expansivities of pv and MgO remain comparable. We use the Keane theory of solids, which takes into account the behavior of solid matter at the infinite pressure limit, adopt the Keane equations of state, and adjust for pv and MgO by comparison with experimental high-pressure and high-temperature data. We find the theory of the infinite pressure limit of Keane to be in excellent agreement with recent ab initio studies and experiments. To calculate the melting curve, we further use the Lindemann–Stacey scaling law and fit it to available experimental data. The best data fitting melting temperature for pv reaches 5700 K at 135 GPa and increases to 20,000 K at 1.1 TPa, corresponding to the core-mantle boundary of a 10 Earth mass super-Earth (10M_Earth). We find the pv adiabatic temperature (with a potential temperature of 1700 K) to reach 2570 K at 135 GPa and 5000 K at 1.1 TPa. To calculate the pressure-and temperature-dependent viscosity, we use the semi-empirical homologous temperature scaling to relate enthalpy change, and hence viscosity, to the melting temperature. We find that the resulting activation volume of pv decreases from 2.8 cm³/mol at 25 GPa to 1.4 cm³/mol at 1.1 TPa-resulting in a viscosity increase by ～15 orders of magnitude through the adiabatic mantle of a 10M_Earth planet. Furthermore, the thermal expansivity (of pv and MgO) decreases by a factor of eight, and the total thermal conductivity (phonon, radiative and electronic) of an Earth-like pv/MgO composite increases by a factor of seven through an adiabatic mantle of a 10M_Earth super-Earth. At higher temperatures, i.e., for super-adiabatic temperature profiles, the electronic and radiative thermal conductivities strongly increase and dominate the conductive heat transport. All findings indicate an increase of heat transfer solely by conduction in the lower mantles of super-Earths. Thus our results disagree with Earth-biased full-mantle convection assumptions made by previous models for super-Earths, and additionally raise questions about the differentiation of massive rocky exoplanets and their ability to generate magnetic fields or sustain plate tectonics.     

Limnological studies of Amarga Lagoon,Chile: A saline lake in Patagonian South America

Amarga Lagoon, lat. 50°29 S and long. 73°45 S, it is located at the Torres del Paine National Park, Chile. The physical, chemical, and biological features of the lake were studied. According to salinity, the lake is mesosaline. Sodium and chloride were the dominant ions. Nitrogen was potentially limiting for phytoplankton growth. One Cyanophyceae species andArtemia were the predominant species in the plankton.Artemia provided abundant food for flamingoes.     

Removal of arsenic from aqueous solution by natural siderite and hematite

Batch and column experiments were conducted to examine the capability of naturally formed hematite and siderite to remove As from drinking water. Results show that both minerals were able to remove As from aqueous solutions, but with different efficiencies. In general, each material removed arsenate much more efficiently than As–DMA (dimethylarsinic acid), with the lowest adsorption efficiency for arsenite. The best removal efficiency for As species was obtained using a hematite, with a grain size range between 0.25 and 0.50 mm. The adsorption capacity for inorganic As(V) reached 202 μg/g. The pH generally had a great impact on the arsenate removal by the Fe minerals studied, while arsenite removal was slightly dependent on the initial pH of between 3 and 10. The presence of phosphate always had a negative effect on arsenate adsorption, due to competitive adsorption between them. A column packed with hematite in the upper half and siderite in the lower half with a grain size range of 0.25–0.5 mm proved to be an efficient reactive filter for the removal of all As species, causing a decrease in As concentration from 500 μg/L (including 200 μg/L As(V) as arsenate, 200 μg/L As(III) as arsenite and 100 μg/L As(V) as DMA) to less than 10 μg/L after 1055 pore volumes of water were filtered at a flow rate of 0.51 mL/min. After 2340 pore volumes passed through the column filter, the total inorganic As in the effluent was less than 5 μg/L. The total As load in the column filter was estimated to be 0.164 mg/g. Results of μ-synchrotron X-ray fluorescence analysis (μ-XRFA) suggest that coatings of fresh Fe(III) oxides, formed on the surface of the siderite grains after two weeks of operation, greatly increased the adsorption capacity of the filling material towards As.     

Untersuchungen zum Vorkommen von R+-Bakterien im Flußwasser

With colony numbers of 2 · 10⁴… 3 · 10⁵ and coliform contents of 2 · 10³… 1 · 1 · 10⁴ per ml, in the investigated river section 2.1% of colonies were resistant to tetracycline, 0.3% to chloramphenicol, 7.5% to kanamycin, 5.4% to trimethoprim, 12.7% to ampicillin and 0.14% to gentamycin. For the coliforms the resistances were 5.1% to tetracycline, 2.1% to chloramphenicol, 2.7% to kanamycin and 0.15% to gentamycin. There were isolated 63 different resistance types. Of the resistant Klebsiella strains 75% were resistant to three or more antibiotics. Of the coliform bacteria (Escherichia coli, Klebsiella, Enterobacter, Citrobacter) 31.6… 51.9% of the strains transferred their antibiotics-resistance to Escherichia coli K-12, for the antibiotics-resistant strains of Pseudomonas and Aeromonas a transfer of resistance was not observed at all.     

Geochemistry of the Rare Earth elements in spilites from the oceanic and continental crust

Analytical data including major elements, the Rare Earths, Ni, Cu, Zn, Rb, and Sr are presented for twenty-three spilites from the Mid-Atlantic Ridge, the Hercynian part of the Variscan geosyncline in Germany, and several localities in Switzerland. Low grade metamorphism (up to approximately 400° C) and spilitization of basaltic rocks apparently do not alter the original Rare Earth element (REE) distributions. This fact permits comparison of the spilites and unaltered tholeiitic basalts from the Mid-Atlantic Ridge. The relative REE distributions thus appear suitable for delineating the original basalt types of spilites formed by metamorphism. The spilites from the Hercynian part of the Variscan geosyncline have a REE distribution pattern which is characteristic of continental tholeiites. It is thus probable that during the formation of this geosyncline the principal magma extruded was of tholeiitic composition and that these rocks were later converted to spilites by metamorphism.