Improved Petrological Modal Analyses from X-ray Powder Diffraction Data by use of the Rietveld Method I. Selected Igneous, Volcanic, and Metamorphic Rocks

Mineral modes have been determined for specimens of eight rocktypes from CuK X-ray powder diffraction data using the Rietveldmethod. The samples include two granites, a granodiorite, adamellite,gabbro, basalt, trachyte, and two granulite-facies metamorphicrocks. Up to eight individual mineral components have been measuredin each sample (no glassy phases were observed), with a detectionlimit of {small tilde}1 wt.%, depending on the mineral assemblage.Marked variations in grain size (i.e., granite vs. trachyte)provide no difficulties for the X-ray method. The X-ray resultscompare very favourably with (1) optical modes determined forthe medium–coarse-grained samples by point counting, (2)normative calculations obtained using locally enhanced catanormand mesonorm software, and (3) corresponding Rietveld modesdetermined, for two samples, from neutron powder data. Wheredifferences occur, these are discussed in relation to the limitationsof each of the methods. The improved accuracy of the X-ray method is due primarily tothe incorporation of the full diffraction profile in the Rietveldanalysis calculations, and the elimination of preferred orientationby collecting the data from samples packed in glass capillaries(i.e., Debye–Scherrer mode). The good agreement of theX-ray and neutron modes shows that the usual problems encounteredwith microabsorption, extinction, and sampling are of littleconcern in these rocks. The results highlight one of the majoradvantages provided by Rietveld modal analysis over the moretraditional ‘reference intensity’ X-ray methods,namely, that the crystal chemistry (and thus the calibrationconstants) of the individual phases can be adjusted dynamicallyduring each individual analysis. This not only provides moreaccurate phase abundances, but also gives important supplementaryinformation about the mineralogy of the major components.     

Prediction of influence of global warming on biological cycle and carbon balance in forest ecosystems of the Volga River Basin

The gradient (ordination) analysis was used to find the tendencies and the rate of changes in discrete parameters of the cycle of forest phytomasses accompanying a growing thermoarid climatic trend. The prognostic estimates of biotic regulation of the carbon cycle by forest biogeocenoses according to the HadCM3 (version A2) climatic scenarios, describing the most powerful coming global warming, are presented.     

Diurnal variation of deep cloud systems over the Indian region using INSAT-1B pixel data

Summary Among the various time scales of deep clouds, diurnal variation is found to be prominent over the tropics. The present study examines the diurnal variation in the number and area cover associated with the cloud systems over the tropical Indian region using INSAT-1B pixel data. Three periods, namely, April–May 1988, July–August 1988, and January–February 1989 are considered. The dependence of diurnal characteristics on the temperature threshold, life duration and size of cloud systems, and land-sea contrast has been explored. The diurnal characteristics of cloud systems living for more than a day have been studied for the first time. It is shown that cloud systems exhibit strong diurnal dependence at the coldest temperature threshold used (201 K). Also, the diurnal variation is more for larger cloud systems and for longer living systems. In general, more deep cloud activity is found from the satellite data during the pre-dawn and early morning hours. Precipitation is enhanced during morning to early noon hours. Further, using data from a recent field experiment, clear evidence of diurnal variation in precipitation over the Bay of Bengal is also presented. Received March 20, 2000/Revised October 3, 2000     

Fe3+ in shocked olivine crystals of the ALHA 77005 meteorite

ALHA 77005, a shocked achondrite of the shergottite group, is unique in containing cumulus olivine crystals which display a brownish color in thin section. Mössbauer, EPR, and optical spectroscopic studies show the presence of Fe³⁺ in the olivine. Approximately 4.5 wt.% of the total iron in the olivine (24 wt.% as FeO) is in the trivalent state. The Fe³⁺ ions preferentially occupy M2 lattice positions. Charge transfer between Fe³⁺ and Fe²⁺ as well as between Fe³⁺ and oxygen ligands causes a broad absorption band in the optical spectrum at high energies which is the reason for the olivine color. It is concluded that the color of the ALHA 77005 olivine is preterrestrial and may be the result of shock-induced oxidation of the olivine crystals on the meteorite parent body.     

Peculiarities of Dynamic Slip Nucleation in a Thin Granular Layer

Izvestiya, Physics of the Solid Earth - Abstract—Granular media determine the dynamics of many natural systems including faults in the Earth’s crust. The paper addresses the laboratory...     

State of stress in the northern Tabas block, east-central Iran, as inferred from focal mechanisms of the 1978 Tabas earthquake sequence

In this paper, the state of stress in the northern Tabas block in east-central Iran is analyzed based on the systematic inversion of aftershock focal mechanisms from the 1978.09.16 Tabas earthquake, to characterise the stress regime that controls most earthquakes in this area. Here, stress inversions of double-couple focal mechanisms of earthquakes recorded during the 30 days following the main shock have been carried out. The calculated average stress regime indicates dominant major 226° to 237° trending compression for the Tabas region. The dominating regime in east-central Iran is thrusting with a minimum stress axis, σ ₃, close to vertical. The reconstruction of the main seismotectonic stress in east-central Iran with a NE-SW compression is consistent with independent information of the active plate convergence related to Arabia-Eurasia convergence. Most earthquakes in the mentioned area occur near or around concealed Quaternary thrust faults with their activity being controlled by the NE-SW compression. Where ?, the ratio of principal stress differences, is 0.5, a small difference between σ ₂; σ ₃ and σ ₁ and small amounts of deviatoric stress is indicated. Therefore, for small deviatoric horizontal σ ₁ it is not possible to increase and reactivate small sections of basement thrust faults and create secondary basement aftershocks. Reconstructed stress regimes in this study for sedimentary cover (237) and basement (226) of Tabas are similar. Therefore, it seems that the basement and cover were coupled together, possibly along the 2–4 km of upper Precambrian low-grade metamorphic rocks. Then these segments of the fold-and-thrust belt were involved in similar seismic activity under a similar stress regime.     

The interpretation of body trace metal concentrations in neogastropods from Hong Kong.

Three species of neogastropods, i.e., Thais clavigera, Thais luteostoma and Morula musiva, were collected from 12 sites in the coastal waters of Hong Kong, including clean and known metal-enriched ones. Accordingly, body trace metal concentrations varied greatly. Copper and zinc body concentrations compared poorly with those of accepted biomonitors and presumed metal contamination profiles. Much is known about the feeding ecology of neogastropods on local shores and where direct observational data were not available, their diets could, nevertheless, be estimated reliably. Accumulated metal concentrations can be interpreted with regard to dietary history. T. luteostoma, for example, had body copper concentrations of 51.8 microg g(-1) on an exposed shore and a diet of mainly barnacles. In contrast, on a sheltered shore (but only some 250 m distant) where the diet consisted mainly of oysters, body copper concentrations were approximately 15 times greater at 833 microg g(-1). Similar results were obtained for T. clavigera. The results of this analysis suggest that neogastropods can play a significant role in trace metal trophic transfer studies, especially as their representatives are intertidally and subtidally ubiquitous and can be spatially separated into tropical specialists and temperate generalists.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.