Arsenic anomalies in shallow Venetian Plain (Northeast Italy) groundwater

A pilot area within the Venetian Plain was selected to assess the arsenic (As) contamination of groundwater. The area represents a typical residential, industrial and agricultural organization representative of most western countries, and is also devoid of lithologies with high or anomalous As content. Hydrogeological and chemical data have been collected, the latter spatialized by a geostatistical approach. The unconfined aquifer reservoir varies from a predominantly gravel composition in the north to a sandy and silt–clay composition further south, including peat layers. The hydrochemical features of the waters are rather homogeneous, featuring low mineral content and a Ca-bicarbonate signature. In contrast, the redox state is highly variable; oxidizing conditions are predominant in the northern and coarse parts of the aquifer, whereas reducing potentials prevail in the southern and silt–clay parts. Several well waters contain arsenic in excess of drinkable limits (=10 ppb), and most of these wells are located in the southern area. A large portion of the studied area has a high probability of containing non-potable water (up to 150 ppb As). Remarkably, As “hot spots” (As > 300 ppb, up to 431 ppb) were identified at the transition from gravel to silt–clay sediments. No industrial or agricultural source of As has been found.     

Laboratory study of deep-water breaking waves

In an attempt to elucidate the mechanics of deep-water wave breaking, a variety of breaking waves, including spilling and plunging waves, of different length scales and geometries was studied. The waves were generated through wave-wave interactions using wave packets with constant-steepness components, constant-amplitude components, and also components following the Pierson-Moskowitz distribution. Wave steepening prior to breaking were found to cause an increase in the high frequency spectral slope of the wave spectrum. The slopes were correlated to the type of breaking and the intensity of the breaking. The energy loss through breaking varied with the spectral characteristics of the wave packet. On the other hand, it was also noted that, irrespective of the wave packet, the losses were from the higher frequency end of the first harmonics.     

Models of travel demand with endogenous preference change and heterogeneous agents

In the literatures of regional science, urban economics, and urban development planning, a working assumption is that individuals respond to incentives and regulations, given their preferences. Models for planning and policy analyses are used to consider what might occur if the incentives or regulations were different. In these models, however, preferences are usually assumed to be given and stable, and agents are usually assumed to be homogeneous. This paper focuses on the implications of making preferences in models of policy implementation endogenously determined and time varying heterogeneous agents. We consider first the recent literature on intertemporal choice and preference change, which cuts across many disciplines, and more briefly the literature on norm-regarding behavior. We then elaborate a simple model of transportation demand—from a static to a dynamic orientation, from fixed and exogenously given preferences of strictly self-regarding agents to endogenously determined and policy-induced preferences of heterogeneous agents—and illustrate its characteristics with simple numerical examples.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

Guided wave propagation in laterally varying media - II. Lg-waves in north-western Europe

Summary. Lg -wave observations at NORSAR from a sequence of explosions straddling the Central Graben in the North Sea, show that the phase is almost extinguished by passing through this structure. For models of the graben structure, based on seismic refraction experiments, with crustal thinning beneath a zone of thickened sediments, numerical modelling of Lg propagation shows very poor transmission. The inclusion of attenuation simulating the effects of scattering from faults and other complex structures further diminishes the transmittivity. The theoretical effect of a crustal pinch is to redistribute S energy over a wide range of groups velocities, a pattern that fits well with the observations.
Three components recordings at NORSAR of explosive charges fired in water covering a wide range of azimuths, show significant transverse components to the seismograms. The transverse energy builds up with travel time and for Lg is of the same order as the vertical component. These results are consistent with the theoretical prediction of progressive net transfer of energy from Rayleigh to Love modes as the wavetrain propagates through a three-dimensionally heterogeneous medium.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

The neotectonics and geodynamics of the Lower Oka Region (East European Craton)

The neotectonic structures of the Lower Oka (Nizhneokskii) Region formed under different geodynamic conditions. This is attested by the morphology, orientation, internal structure, and jointing of the structures. The Oka-Tsna arc formed under the effect of tension from an inner source on the one hand and stress from the Alpian belt on the other hand. The latitudinally-oriented structures of the northwestern slope of the Tokmovo arc emerged as a result of uplift and widening. Both types of structure are combined within the limits of the Oka-Murom trough, which is a geodynamically active zone.